Development of Composite Adsorbent for Waste Water Treatment Using Adsorption and Electrochemical Regeneration
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33090
Development of Composite Adsorbent for Waste Water Treatment Using Adsorption and Electrochemical Regeneration

Authors: H. M. A. Asghar, S. N. Hussain, E. P. L. Roberts, N. W. Brown, H. Sattar

Abstract:

A unique combination of adsorption and electrochemical regeneration with a proprietary adsorbent material called Nyex 100 was introduced at the University of Manchester for waste water treatment applications. Nyex 100 is based on graphite intercalation compound. It is non porous and electrically conducing adsorbent material. This material exhibited very small BET surface area i.e. 2.75 m2g-1, in consequence, small adsorptive capacities for the adsorption of various organic pollutants were obtained. This work aims to develop composite adsorbent material essentially capable of electrochemical regeneration coupled with improved adsorption characteristics. An organic dye, acid violet 17 was used as standard organic pollutant. The developed composite material was successfully electrochemically regenerated using a DC current of 1 A for 60 minutes. Regeneration efficiency was maintained at around 100% for five adsorption-regeneration cycles.

Keywords: Adsorption, electrically conducting adsorbent material, electrochemical regeneration, waste water.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1070117

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 3215

References:


[1] H Y.C. Sharma, U.S.N. Upadhyay & F. Gode (2009) Adsorptive removal of a basic dye from water and waste water by activated carbon. Journal of Applied Sciences and Environmental Sanitation, Vol. 4 pp. 21-28.
[2] G.M. Walker & L.R. Weatherley (1997) Fixed bed adsorption of acid dyes onto activated carbon. Environmental Pollution, Vol. 99 pp. 133- 136.
[3] G.S. Miguel, S.D. Lambert & N.J.D. Graham, (2001) The regeneration of spent granular activated carbon. Water Research, Vol. 3 (11) pp. 2740-2748.
[4] N.W. Brown & E.P.L. Roberts (2007) Electrochemical pre-treatment of effluents containing chlorinated compounds using an adsorbent. Journal of Applied Electrochemistry, Vol. 37 (11) pp. 1329 - 1335.
[5] E. Sabio, E.J.F. Gonzalez, A. Ramiro & J. Ganan (2004) Thermal regeneration of activated carbon saturated with p-nitrophenol. Carbon Vol. 42 pp. 2285-2293.
[6] C.C. Leng, & N.G. Pinto (1996) Effects of surface properties of activated carbons on adsorption behaviour of selected aromatics. Carbon, Vol. 35 (9) pp. 1375-1385.
[7] D. Mohan, K.P. Singh & K. Kumar. (2002) Removal of dyes from wastewater using fly ash, a low-cost adsorbent. Industrial and Engineering Chemical Research, Vol. 41 pp.3688-3695.
[8] N.W. Brown, E.P.L. Roberts, A..A. Garforth & R.A.W. Dryfe (2004 a). Treatment of dye house effluents with carbon based adsorbent using anodic oxidation regeneration. Water Science and Technology, Vol. 49 (4) pp. 219-225.
[9] N.W. Brown, E.P.L. Roberts, A. Chasiotis, T. Cherdron & N. Sanghrajaka (2004 b). Atrazine removal using adsorption and electrochemical regeneration.Water Research, Vol. 38 pp. 3067-3074.
[10] N.W. Brown, E.P.L. Roberts, A.A. Garforth & R.A.W. Dryfe (2004 c) Electrochemical regeneration of a carbon based adsorbent loaded with crystal violet dye. Electrochimica Acta, Vol. 49 pp. 3269-3281.
[11] H.M.A. Asghar (2011). Development of graphitic adsorbents for water treatment using adsorption and electrochemical regeneration. Ph.D thesis submitted to the University of Manchester, UK.
[12] R.M. Narbaitz & J. Cen (1994). Electrochemical regeneration of granular activated carbon. Water Research, Vol. 28 (8) pp. 1771-1778.
[13] M. Streat & D.J. Horner (2000). Adsorption of highly soluble herbicide from water using activated carbon and hypercrosslinked polymers. Process Safety and Environmental Protection, Vol. 78 (5) pp. 363-382