Annealing of the Contact between Graphene and Metal: Electrical and Raman Study
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Annealing of the Contact between Graphene and Metal: Electrical and Raman Study

Authors: A. Sakavičius, A. Lukša, V. Nargelienė, V. Bukauskas, G. Astromskas, A. Šetkus

Abstract:

We investigate the influence of annealing on the properties of a contact between graphene and metal (Au and Ni), using circular transmission line model (CTLM) contact geometry. Kelvin probe force microscopy (KPFM) and Raman spectroscopy are applied for characterization of the surface and interface properties. Annealing causes a decrease of the metal-graphene contact resistance for both Ni and Au.

Keywords: Graphene, Kelvin force probe microscopy, Raman spectroscopy.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1130225

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References:


[1] Novoselov, Kostya S., et al. "Electric field effect in atomically thin carbon films." Science 306.5696 (2004): 666-669.
[2] Novoselov, Kostya S., et al. "Two-dimensional gas of massless Dirac fermions in graphene." Nature 438.7065 (2005): 197-200.
[3] Novoselov, K. S., et al. "Two-dimensional atomic crystals." Proceedings of the National Academy of Sciences of the United States of America 102.30 (2005): 10451-10453.
[4] Geim, Andre K., and Konstantin S. Novoselov. "The rise of graphene." Nature materials 6.3 (2007): 183-191.
[5] Stankovich, Sasha, et al. "Graphene-based composite materials." Nature 442.7100 (2006): 282-286.
[6] Ferrari, A. C., et al. "Raman spectrum of graphene and graphene layers." Physical review letters 97.18 (2006): 187401.
[7] Kang, Junmo, et al. "Graphene transfer: key for applications." Nanoscale 4.18 (2012): 5527-5537.
[8] Neto, AH Castro, et al. "The electronic properties of graphene." Reviews of modern physics 81.1 (2009): 109.
[9] Venugopal, A., L. Colombo, and E. M. Vogel. "Contact resistance in few and multilayer graphene devices." Applied Physics Letters 96.1 (2010): 013512.
[10] Li, Wei, et al. "Ultraviolet/ozone treatment to reduce metal-graphene contact resistance." Applied Physics Letters 102.18 (2013): 183110.
[11] Leong, Wei Sun, Chang Tai Nai, and John TL Thong. "What does annealing do to metal–graphene contacts?." Nano letters 14.7 (2014): 3840-3847.
[12] Liang, Xuelei, et al. "Toward clean and crackless transfer of graphene." ACS nano 5.11 (2011): 9144-9153.
[13] Politou, Maria, et al. "Transition metal contacts to graphene." Applied Physics Letters 107.15 (2015): 153104.
[14] Matsuda, Yuki, Wei-Qiao Deng, and William A. Goddard III. "Contact Resistance for “End-Contacted” Metal− Graphene and Metal− Nanotube Interfaces from Quantum Mechanics." The Journal of Physical Chemistry C 114.41 (2010): 17845-17850.
[15] Das, Anindya, et al. "Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor." Nature Nanotechnology 3.4 (2008): 210-215.
[16] Ferrari, Andrea C., and Denis M. Basko. "Raman spectroscopy as a versatile tool for studying the properties of graphene." Nature Nanotechnology 8.4 (2013): 235-246.
[17] Cheng, Zengguang, et al. "Toward intrinsic graphene surfaces: a systematic study on thermal annealing and wet-chemical treatment of SiO2-supported graphene devices." Nano letters 11.2 (2011): 767-771.
[18] Ni, Zhen Hua, et al. "Uniaxial strain on graphene: Raman spectroscopy study and band-gap opening." ACS nano 2.11 (2008): 2301-2305.
[19] Wang, W. X., et al. "The study of interaction between graphene and metals by Raman spectroscopy." Journal of Applied Physics 109.7 (2011): 07C501.
[20] Ziegler, D., et al. "Variations in the work function of doped single-and few-layer graphene assessed by Kelvin probe force microscopy and density functional theory." Physical Review B 83.23 (2011): 235434.
[21] Yu, Young-Jun, et al. "Tuning the graphene work function by electric field effect." Nano letters 9.10 (2009): 3430-3434.
[22] Giovannetti, G. A. K. P. A., et al. "Doping graphene with metal contacts." Physical Review Letters 101.2 (2008): 026803.
[23] Khomyakov, P. A., et al. "First-principles study of the interaction and charge transfer between graphene and metals." Physical Review B 79.19 (2009): 195425.