Chromium Adsorption by Modified Wood
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33090
Chromium Adsorption by Modified Wood

Authors: I. Domingos, B. Esteves, A. Figueirinha, Luísa P. Cruz-Lopes, J. Ferreira, H. Pereira

Abstract:

Chromium is one of the most common heavy metals which exist in very high concentrations in wastewater. The removal is very expensive due to the high cost of normal adsorbents. Lignocellulosic materials and mainly treated materials have proven to be a good solution for this problem.

Adsorption tests were performed at different pH, different times and with varying concentrations.

Results show that is at pH 3 that treated wood absorbs more chromium ranging from 70% (2h treatment) to almost 100% (12 h treatment) much more than untreated wood with less than 40%. Most of the adsorption is made in the first 2-3 hours for untreated and heat treated wood. Modified wood adsorbs more chromium throughout the time. For all the samples, adsorption fitted relatively well the Langmuir model with correlation coefficient ranging from 0.85 to 0.97.

The results show that heat treated wood is a good adsorbent ant that this might be a good utilization for sawdust from treating companies.

Keywords: Adsorption, chromium, heat treatment, wood modification.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1093370

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[1] I. Villaescusa N. Fiol, M. Martinez, N. Niralles, J. Poch and J. Serols "Removal of copper and nickel ions from aqueous solutions by grape stalks wastes”. Water research. 38, 992-1002, 2004
[2] N. Chubar, J. Carvalho, and M. Correia "Heavy metals biosorption on cork biomass: effect of the pre-treatment.” Colloids and Surfaces A:Physicochemical and Engineering Aspects 238, 51-58, 2004.
[3] M. Aliabadi, K. Morshedzadeh, and H. Soheyli, "Removal of hexavalent chromium from aqueous solution by lignocellulosic solid wastes,” Int. J. Environmental Science and Technology, vol. 3, pp. 321–325, 2006.
[4] P. Miretzky and A. F. Cirelli, "Cr (VI) and Cr (III) removal from aqueous solution by raw and modified lignocellulosic materials: A review,” Journal of Hazardous Materials, vol. 180, pp. 1–19, 2010.
[5] K. Krishnani and S. Ayyappan, "Heavy metals remediation of water using plants and lignocellulosic agrowastes,” Reviews of Environmental Contamination and Toxicology, pp. 59–84, 2006
[6] M. C. Basso, E. G. Cerrella, and A. L. Cukierman, "Lignocellulosic materials as potential biosorbents of trace toxic metals from wastewater,” Industrial & Engineering Chemistry Research., vol. 41, pp. 3580–3585, 2002.
[7] A. Demirbas, "Heavy metal adsorption onto agro-based waste materials: A review,” Journal of Hazardous Materials, vol. 157, pp. 220–229, 2008.
[8] M. Šćiban, B. Radetić, Ž. Kevrešan, and M. Klašnja, "Adsorption of heavy metals from electroplating wastewater by wood sawdust,” Bioresource Technology, vol. 98, pp. 402–409, 2007.
[9] F. N. Acar and E. Malkoc, "The removal of chromium(VI) from aqueous solutions by Fagus orientalis L,” Bioresource Technology, vol. 94, pp. 13–15, 2004.
[10] Shin, E.W., Karthikeyan, K.G., Tshabalala, M.A., 2007. Adsorption mechanism of cadmium on juniper bark and wood. Bioresour. Technol. 98, 588–594.
[11] M. Šćiban, M. Klašnja, and B. Škrbić, "Adsorption of copper ions from water by modified agricultural by-products,” Desalination, vol. 229, pp. 170–180, 2008.
[12] P. Álvarez, C. Blanco, and M. Granda, "The adsorption of chromium (VI) from industrial wastewater by acid and base-activated lignocellulosic residues,” Journal of Hazardous Materials, vol. 144, pp. 400–405, 2007.
[13] A. Sen, A., Olivella, N. Fiol, I., Miranda, I., Villaescusa, and H. Pereira, "Chromium sorption by cork” Bioresources 7(4), 4843-4857, 2012.