Mechanical and Thermal Properties Characterisation of Vinyl Ester Matrix Nanocomposites Based On Layered Silicate: Effect of Processing Parameters
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32795
Mechanical and Thermal Properties Characterisation of Vinyl Ester Matrix Nanocomposites Based On Layered Silicate: Effect of Processing Parameters

Authors: A. I. Alateyah, H. N. Dhakal, Z. Y. Zhang

Abstract:

The mechanical properties including flexural and tensile of neat vinyl ester and polymer based on layered silicate nanocomposite materials of two different methodologies are discussed. Methodology 1 revealed that the addition of layered silicate into the polymer matrix increased the mechanical and thermal properties up to 1 wt.% clay loading. The incorporation of more clay resulted in decreasing the properties which was traced to the existence of aggregation layers. The aggregation layers imparted a negative impact on the overall mechanical and thermal properties. On the other hand, methodology 2 increased the mechanical and thermal properties up to 4 wt.% clay loading. The different amounts of improvements were assigned to the various preparation parameters. Wide Angle X-ray Diffraction, Scanning Electron Microscopy and Transmission Electron Microscopy were utilized in order to characterize the interlamellar structure of nanocomposites.

Keywords: Vinyl ester, nanocomposites, layered silicate, mechanical properties, thermal analysis.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1089231

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1679

References:


[1] W. Peng, X. Huang, J. Yu, P. Jiang, and W. Liu, "Electrical and thermophysical properties of epoxy/aluminum nitride nanocomposites: Effects of nanoparticle surface modification," Composites Part A: Applied Science and Manufacturing, vol. 41, pp. 1201-1209, 2010.
[2] A. I. Alateyah, H. N. Dhakal, and Z. Y. Zhang, "Processing, Properties, and Applications of Polymer Nanocomposites Based on Layer Silicates: A Review " Advances in Polymer Technology, vol. 32, 2013.
[3] S. Lapshin, S. K. Swain, and A. I. Isayev, "Ultrasound aided extrusion process for preparation of polyolefin–clay nanocomposites," Polymer Engineering & Science, vol. 48, pp. 1584-1591, 2008.
[4] A. I. Alateyah, H. N. Dhakal, and Z. Y. Zhang, "Mechanical and thermal properties characterisation of vinyl ester matrix nanocomposites based on layered silicate," World Academy of Science, Engineering and Technology, vol. 81, pp. 1-8, 2013.
[5] A. I. Alateyah, H. N. Dhakal, and Z. Y. Zhang, "Water absorption behaviour, mechanical and thermal properties of vinyl ester matrix nanocomposites based on layered silicate," Polymer-Plastics Technology and Engineering, vol. Accepted, 2013.
[6] C. A. Ittner Mazali and M. I. Felisberti, "Vinyl ester resin modified with silicone-based additives: III. Curing kinetics," vol. 45, pp. 2222-2233, 2009.
[7] I. Southern Clay Products. (11). Cloisite® 10A. Available: http://www.scprod.com/product_bulletins/PB%20Cloisite%2010A.pdf
[8] B. S. Institution. (1998). Glass fibre reinforced plastics — Flexural test —Three point bend method (2746 ed.). Available: http://www.standardsuk.com/products/BS-EN-2746-1998.php
[9] B. S. Institution. (1998). Glass fibre reinforced plastics — Tensile test (2747 ed.). Available: http://www.standardsuk.com/products/BS-EN-2747-1998.php
[10] S. Sinha Ray, K. Yamada, M. Okamoto, and K. Ueda, "New polylactide-layered silicate nanocomposites. 2. Concurrent improvements of material properties, biodegradability and melt rheology," Polymer, vol. 44, pp. 857-866, 2003.
[11] J.-H. Chang, Y. U. An, D. Cho, and E. P. Giannelis, "Poly (lactic acid) nanocomposites: comparison of their properties with montmorillonite and synthetic mica (II)," Polymer, vol. 44, pp. 3715-3720, 2003.
[12] J. H. Chang and Y. U. An, "Nanocomposites of polyurethane with various organoclays: Thermomechanical properties, morphology, and gas permeability*," Journal of Polymer Science Part B: Polymer Physics, vol. 40, pp. 670-677, 2002.
[13] H. Alamri and I. M. Low, "Effect of water absorption on the mechanical properties of nano-filler reinforced epoxy nanocomposites," Materials & Design, vol. 42, pp. 214-222, 12// 2012.
[14] H. Alamri and I. M. Low, "Microstructural, mechanical, and thermal characteristics of recycled cellulose fiber-halloysite-epoxy hybrid nanocomposites," Polymer Composites, vol. 33, pp. 589-600, 2012.
[15] T. P. Mohan and K. Kanny, "Water barrier properties of nanoclay filled sisal fibre reinforced epoxy composites," Composites Part A: Applied Science and Manufacturing, vol. 42, pp. 385-393, 4// 2011.
[16] A. Ashori and A. Nourbakhsh, "Characteristics of wood–fiber plastic composites made of recycled materials," Waste Management, vol. 29, pp. 1291-1295, 4// 2009.
[17] M. Avella, A. Buzarovska, M. Errico, G. Gentile, and A. Grozdanov, "Eco-Challenges of Bio-Based Polymer Composites," Materials, vol. 2, pp. 911-925, 2009.
[18] P. Jawahar, R. Gnanamoorthy, and M. Balasubramanian, "Tribological behaviour of clay – thermoset polyester nanocomposites," Wear, vol. 261, pp. 835-840, 10/20/ 2006.
[19] P. Kodgire, R. Kalgaonkar, S. Hambir, N. Bulakh, and J. P. Jog, "PP/clay nanocomposites: Effect of clay treatment on morphology and dynamic mechanical properties," Journal of Applied Polymer Science, vol. 81, pp. 1786-1792, 2001.
[20] S. Pavlidou and C. D. Papaspyrides, "A review on polymer–layered silicate nanocomposites," Progress in Polymer Science, vol. 33, pp. 1119–1198, 2008.
[21] M. Alexandre and P. Dubois, "Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials," Materials Science and Engineering: R: Reports, vol. 28, pp. 1-63, 2000.
[22] M. L. Q. A. Kaneko, R. B. Romero, R. E. F. de Paiva, M. I. Felisberti, M. C. Gonçalves, and I. V. P. Yoshida, "Improvement of toughness in polypropylene nanocomposite with the addition of organoclay/silicone copolymer masterbatch," Polymer Composites, 2013.
[23] P. Kiliaris and C. D. Papaspyrides, "Polymer/layered silicate (clay) nanocomposites: An overview of flame retardancy," Progress in Polymer Science, vol. 35, pp. 902-958, 7// 2010.
[24] C. Zhao, H. Qin, F. Gong, M. Feng, S. Zhang, and M. Yang, "Mechanical, thermal and flammability properties of polyethylene/clay nanocomposites," Polymer Degradation and Stability, vol. 87, pp. 183-189, 2005.
[25] F. Gong, M. Feng, C. Zhao, S. Zhang, and M. Yang, "Thermal properties of poly(vinyl chloride)/montmorillonite nanocomposites," Polymer Degradation and Stability, vol. 84, pp. 289-294, 5// 2004.
[26] W. D. Lee, S. S. Im, H.-M. Lim, and K.-J. Kim, "Preparation and properties of layered double hydroxide/poly(ethylene terephthalate) nanocomposites by direct melt compounding," Polymer, vol. 47, pp. 1364-1371, 2/8/ 2006.
[27] A. Yasmin, J. J. Luo, J. L. Abot, and I. M. Daniel, "Mechanical and thermal behavior of clay/epoxy nanocomposites," Composites Science and technology, vol. 66, pp. 2415-2422, 2006.
[28] Y.-L. Liu, C.-Y. Hsu, W.-L. Wei, and R.-J. Jeng, "Preparation and thermal properties of epoxy-silica nanocomposites from nanoscale colloidal silica," Polymer, vol. 44, pp. 5159-5167, 8// 2003.
[29] T. Lan and T. J. Pinnavaia, "Clay-Reinforced Epoxy Nanocomposites," Chemistry of Materials, vol. 6, pp. 2216-2219, 1994.
[30] C. Zilg, R. Mülhaupt, and J. Finter, "Morphology and toughness/stiffness balance of nanocomposites based upon anhydride-cured epoxy resins and layered silicates," Macromolecular Chemistry and Physics, vol. 200, pp. 661-670, 1999.
[31] O. Becker, R. Varley, and G. Simon, "Morphology, thermal relaxations and mechanical properties of layered silicate nanocomposites based upon high-functionality epoxy resins," Polymer, vol. 43, pp. 4365-4373, 2002.