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Fabrication and Characterization of CdS Nanoparticles Annealed by using Different Radiations

Authors: Aneeqa SABAH, Saadat Anwar Siddiqi, Salamat Ali


The systematic manipulations of shapes and sizes of inorganic compounds greatly benefit the various application fields including optics, magnetic, electronics, catalysis and medicine. However shape control has been much more difficult to achieve. Hence exploration of novel method for the preparation of differently shaped nanoparticles is challenging research area. II-VI group of semiconductor cadmium sulphide (CdS) nanostructure with different morphologies (such as, acicular like, mesoporous, spherical shapes) and of crystallite sizes vary from 11 to 16 nm were successfully synthesized by chemical aqueous precipitation of Cd2+ ions with homogeneously released S2- ions from decomposition of cadmium sulphate (CdSO4) and thioacetamide (CH3CSNH2) by annealing at different radiations (microwave, ultrasonic and sunlight) with matter and systematic research has been done for various factors affecting the controlled growth rate of CdS nanoparticles. The obtained nanomaterials have been characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravometric (DSC-TGA) analysis and Scanning Electron Microscopy (SEM). The result indicates that on increasing the reaction time particle size increases but on increasing the molar ratios grain size decreases.

Keywords: Morphology, Oxidation, CdS nanoparticles, Radiations

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[1] Efros AL, Rosen M Annu, Rev. Mater. Sci. vol. 30, 2003, pp. 475.
[2] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and Calorimetry. Vol 61, 2000, pp. 181-189.
[3] P. Raji, C. Sanjeeviraja and K. Ramachandran, Cryst. Res. Technol, vol 28, 2005, pp. 233-238.
[4] Pushpa Ann Kurian, C. Vijayan, K. Sathiyamoorthy, C. S. Suchand Sandeep, Reji Philip Res, Lett. 2, 2007, pp. 561-568.
[5] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Materials Chemistry and Physics, Vol. 11, 1971, pp. 493.
[6] J. Jakimavicious, A. Alisauskas and A. Sirvaitis, Chem, vol. 76, 1972, pp. 38400.
[7] K. Matsumoto, K. Takagi and S. Kaneko, J. Electrochem. Soc, vol. 130, 1983, pp. 423.
[8] Clare R. Collins, K. Vala Ragnarsdottir, David M. Sherman, Geochemical et Cosmochimica Acta, vol. 63, 1999, pp. 2989-3002.
[9] Murugan, Vadivel, Kale, B.B.Swaminathan, V.Sonawane, vol. 4594, 2001, pp. 440-446.
[10] Yonghong Ni, Fei Wang, Hongjiang liu, Gui Yin, Jianming Hong, Xiang Ma, and Zheng Xu, J. Cryst. Growth, Vol. 262, 2004, pp. 399-402.
[11] Eugenio Caponetti, Delia Chillura Martino, Maurizio Leone, Lucia Pedone, Maria Luisa Saladino and Valeria Vetri, Journal of Colloid and Inteface Science, vol. 304, 2006, pp. 413A-418.
[12] R. Banerjee, R. Jayakrishnan and P. Ayyub, J. Phys. Condens. Matter. Vol. 12, 2000, pp. 10647-10654.
[13] R.I.Dimitrov, N. Moldovanska and I. K. Bonev, vol. 385, 2002, pp. 41- 49.
[14] Jun Chen, Xinbo Wang and Zhicheng Zhang, Materials letters, vol. 62, 2008, pp. 787-790.
[15] J. Barman, J. P. Borah, K. C. Sarma, Chalcogenide Letters, vol. 5, 2008, 265 - 271.
[16] R. Devi, P. Purkayastha, P. K. Kalita and B. Sarma, Sci. vol. 30, 2007, 123-128.
[17] C. Yohannan Panicker, Hema Tresa Varghese and Daizy Philip, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 65, 2006, pp. 802-804.
[18] R. I. Dimitrov and B. S. Boyanov, Journal of Thermal Analysis and Calorimetry, vol. 61, 2000, pp. 181-189.
[19] R. I. Dimitrov, N. Moldovanska and I. K. Bonev, Cadmium sulphide oxidation, vol. 385, 2002, pp. 41-49.