Novel Glycopolymers Containing Carbohydrate Moiety: Copolymerization and Thermal Properties
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32926
Novel Glycopolymers Containing Carbohydrate Moiety: Copolymerization and Thermal Properties

Authors: Liliana M. Ştefan, Ana M. Pană, Geza Bandur, Marcel Popa, Lucian M. Rusnac

Abstract:

Polymers are one of the most widely used materials in our every day life. The subject of renewable resources has attracted great attention in the last period of time. New polymeric materials derived from renewable resources, like carbohydrates draw attention to public eye especially because of their biocompatibility and biodegradability. The aim of our paper was to obtain environmentally compatible polymers from monosaccharides. Novel glycopolymers based on D-glucose have been obtained from copolymerization of a new monomer carrying carbohydrate moiety with methyl methacrylate (MMA) via free radical bulk polymerization. Differential scanning calorimetry (DSC) was performed in order to study the copolymerization process of the monomer into the chosen co-monomer; the activation energy of this process was evaluated using Ozawa method. The copolymers obtained were characterized using ATR-FTIR spectroscopy. The thermal stability of the obtained products was studied by thermogravimetry (TG).

Keywords: DSC, glycopolymer, monosaccarides, TG.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1058079

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1684

References:


[1] O. D. Satyanarayanaa, P. R. Chatterjia, "Biodegradable Polymers: Challenges and Strategies", Polymer Reviews, 33:3, 1993, pp. 349 -368.
[2] X. Wang, X. Geng, L. Ye, A-y Zhang, Z-g Feng, "Synthesis and characterization of novel glucose- and lactose-containing methacrylatebased radiopaque glycopolymers", Reactive & Functional Polymers 69, 2009, pp. 857-863.
[3] R. Cuervo-Rodr├¡guez, V. Bordegé, M. Fern├índez-Garc├¡a, "Synthesis and characterization of novel glycopolymers based on ethyl hydroxy methylacrylate", Carbohydrate Polymers, 68, 2007, pp. 89-94.
[4] S. Slavin, J. Burns, D. M. Haddleton, C. Remzi Becer. "Synthesis of glycopolymers via click reactions", European Polymer Journal, 47, 2011, pp. 435-446.
[5] A. M. Panâ, V. Gherman, P. Sfarloaga, G. Bandur, L. M. Stefan, M. Popa, L. M. Rusnac, "Thermal stability and biodegradation of novel DMannose based glycopolymers", Polymer Testing 31, 2012, pp. 384- 392.
[6] K. Van de Velde, P. Kiekens, "Biopolymers: overview of several properties and consequence on their applications", Polymer Testing, 21, 2002, pp. 433-442.
[7] H. Yang, T. Y. Guo, D. Zhou, "Surface modification with well-defined glycopolymer for protein imprinting matrix", International Journal of Biological macromolecules, 48, 2011, pp. 432-438.
[8] Q. Shi, C. Chen, L. Gao, H. Xu, W. Guo, "Physical and degradation properties of binary or ternary blands composed of poly(lactic acid), thermoplastic starch and GMA grafted POE", Polymer Degradation and stability, 96, 2011, pp. 175-182.
[9] M. Khalid, C. T. Ratnam, C. A Luqman, A. Salmiaton, T. S. Y. Choong, and H. Jalaludin, "Thermal and Dynamic Mechanical Behavior of Cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-Filled Polypropylene Biocomposites", Polymer-Plastics Technology and Engineering, 48:12, 2009, pp. 1244-1251.
[10] H. Tian, Z. Tang, X.. Zhuang, X. Chen "Preparation, functionalization and biomedical application", Progress in Polymer Science, 2011, to be published.
[11] A. M. Panâ, L. Rusnac, G. Bandur, E. ┼×i┼ƒu, V. Badea, M. Silion, "Synthesis and Characterization of New Glycopolymers Based on Monosachharides and Maleic Anhydride I. Glucose derivatives", Materiale Plastice, Bucure┼ƒti, 47(1), ´Çá2010.
[12] L. M ┼×tefan., A. M. Panâ., M. C. Pascariu, E. Sisu, G. Bandur, L. M. Rusnac, "Synthesis and Characterization of a new methacrylic glycomonomer", Turkish Journal of Chemistry, 35, 2011, pp. 757-767.
[13] J. Menczel, P. R. Bruce, Thermal Analysis of Polymers Fundamentals and Applications. John Wiley and Sons. New Jersey, USA. 2009, pp. 7- 150.
[14] H. E. Kissinger, Anal . Chem., 1957, pp. 1702-1706.