Removal of Heavy Metals from Wastewater by Adsorption and Membrane Processes: a Comparative Study

Authors: Nermen N. Maximous, George F. Nakhla, W. K. Wan

Abstract:

This research aimed at investigating the Cr (III), Cd (II) and Pb (II) removal efficiencies by using the newly synthesized metal oxides/ polyethersulfone (PES), Al2O3/PES and ZrO2/PES, membranes from synthetic wastewater and exploring fouling mechanisms. A Comparative study between the removal efficiencies of Cr (III), Cd (II) and Pb (II) from synthetic and natural wastewater by using adsorption onto agricultural by products and the newly synthesized Al2O3/PES and ZrO2/PES membranes was conducted to assess the advantages and limitations of using the metal oxides/PES membranes for heavy metals removal. The results showed that about 99 % and 88 % removal efficiencies were achieved by the tested membranes for Pb (II) and Cr (III), respectively.

Keywords: Adsorption, metals removal, ultrafiltrationmembranes, wastewater

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1080125

References:

[1] X. Zhou, T. Korenage, T. Takahashi, T. Moriwake, and S. Shinoda "A process monitoring/controlling system for the treatment of wastewater containing chromium (VI)," J. Water Res., vol. 27, 1993, pp. 1049- 1054.
[2] G.Tiravanti, D. Petruzzelli, R. Passino, "Pretreatment of tannery wastewater bu an ion exchange process for Cr (III) removal and recovery", J. Water Sci. Technol., vol. 36, 1997, pp. 197-207.
[3] S. Rengaraj, C. K. Joo, Y. Kim, J. Yi, "Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resin", J. Hazard Mat., vol. 102, 2003, pp. 257-275.
[4] D. Petruzzelli, R. Passino, G. Tiravanti, "Ion exchange process for chromium removal and recovery from tannery wastes", J. Ind. Eng. Chem. Res., vol.. 34, 1995, pp. 2612-2617.
[5] S. K. Srivastava, V. K. Gupta, D. Mohan,"Kinetic parameters for the reomoval of lead and chromium from wastewater using activated carbon developed from fertilizer waste material", J. Environ. Model. Assess, vol. 1, 1997, pp. 281-290.
[6] V. K.. Gupta, K. T. Park, S. Sharma, D. Mohan," Removal of chromium (VI) from electroplating industry wastewater using bagasse flyash-a sugar industry waste material", J. The Environmentalist, vol. 19, 1999, pp. 129-136.
[7] H. Shaalan, M. Sorour, S. Tewfik,"Simulation and optimization of a membrane system for chromium recovery from tanning wastes", J. Desalination, vol. 141, 2001, pp. 315-324.
[8] C. A. Kozlowski, W. Walkowiak,"Removal of chromium (VI) from aqueous solutions by polymer inclusion membranes", J. Water Res., vol. 36, 2002, 4870-4876.
[9] N. Kongsricharoern, C. Polprasert, "Chromium removal by a bipolar electrochemical precipitation process", J. Water Sci., Technol., vol. 34, 1996, pp. 109-116.
[10] S. Babel, T. A. Kurniawan, "Low-cost adsorbents for heavy metal uptake from contaminated water: a review", J. Hazard. Mat. , vol. 97, 2003, pp. 219-243.
[11] Z. Reddad, C. Gerente, Y. Andres, P. LeCloirece," Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies", J. Environ. Sci. & Technol., vol. 36, no. 9, 2002, pp. 2067- 2073.
[12] M. Kobya, "Removal of Cr (VI) from aqueous solution by adsorption onto hazelnut shell activated carbon: kinetic and equilibrium studies", J. Biores. Technol., vol. 91, 2004, pp. 317-321.
[13] S. P. Bingulac, "On the compatibility of adaptive controllers (Published Conference Proceedings style)," in Proc. 4th Annu. Allerton Conf. Circuits and Systems Theory, New York, 1994, pp. 8-16.R. R. Bansode, J. N. Losso, W. E. Marshall, R. M. Rao, R. J. Portier," Adsorption of metal ions by pecan shell-based grsnular activated carbons", J. Biores. Technol., vol. 89, 2003, pp. 115-119.
[14] U. Kumar, M. Bandyopadhyay,"Sorption of cadmium from aqueous solution using pretreated rice husk", J. Biores. Technol., vol. 97, 2006, pp. 104-109.
[15] K. K. Wong, C. K. Lee, K. S. Low, M. Haron, "Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions", J. Chemospere, vol. 50, 2003, pp. 23-28
[16] C. K. Lee, K. S. Low, S.J. Mah,"Removal of a gold (III) complex by quaterized rice husk", J. Adv. Environ. Res., vol. 2, no. 3, 1998, pp. 351- 359.
[17] Y. Guo, J. Qi, S.Yang, K. Yu, Z. Wang, H. Xu, "Adsorption of Cr (VI) on micro-and mesoporous rice husk-based activated carbon", J. Materials Chem. And Physics, vol. 78, 2002, pp. 132-137.
[18] M. M. Jogi, I. A. Ansari,"Non-conventional utilization of maize husk for the removal of iron from industrial wastewater, J. Biosci. & Biotechnol. Res. Asia, vol.1, no. 1, 2003, pp. 63-66.
[19] R.S. Juang, R.C. Shiau," Metal removal from aqueous solutions using chitosan-enhanced membrane filtration", J. Membr. Sci., vol. 165, 2000, pp. 159-167.
[20] N. Maximous, M. Masoud, R. Nessim, G. Nakhla, "Adsorption of Cr (III), Cd (II) and Pb (II) on natural adsorptents", J. Adsorption, submitted for publication.
[21] T. Matsuura, "Synthetic Membranes and Membrane Separation Processes", CRC Press: Boca Raton, FL, 1994.
[22] N. Maximous, G. Nakhla, W. Wan, K. Wong, "Preparation, characterization and performance of Al2O3/PES membrane for wastewater filtration", J. Membr.Sci. , vol. 341, 2009, pp. 67-75.
[23] N. Maximous, G. Nakhla, W. Wan, "Performance of a novel ZrO2 /PES membrane for wastewater filtration", J. Membr.Sci. , submitted for publication.
[24] D. C. Sharma, C. F. Foster, "A preliminary examination into the adsorption of hexavalent chromium using low-cost adsorbents", Biores. Technol., vol. 47, no. 3, 1994, pp. 257-264.
[25] K. S. Low, C. K. Lee, A. C. Leo, "Removal of metals from electroplating wastes using banana pith", J. Biores. Tecnol., vol. 51, no. 2-3, 1995, pp. 227-231.
[26] S.P. Hong, T.H. Bae, T.M. Tak, S. Hong, "A. Randall, Fouling control in activated sludge submerged hollow fiber membrane bioreactor", J. Desalination, vol.. 143, 2002, pp. 219-228.
[27] W.H. Hoell and J. Horst, "Description of sorption equilibria for ions onto activated carbon using the surface complexation theory", J. Water Sci. Tech., vol. 35, no. 7, 1997, pp. 287-294.
[28] M. Lehmann, A.I. Zouboulis and K.A. Matis, "Removal of metal ions from dilute aqueous solutions: A comparative study of inorganic sorbent materials", J. Chemosphere, vol. 39, no. 6, 1999, pp. 881-892.