Study of Compost Maturity during Humification Process using UV-Spectroscopy
The increments of aromatic structures are widely used to monitor the degree of humification. Compost derived from mix manures mixed with agricultural wastes was studied. The compost collected at day 0, 7, 14, 21, 28, 35, 49, 77, 91, 105, and 119 was divided into 3 stages, initial stage at day 0, thermophilic stage during day 1-48, and mature stage during day 49-119. The change of highest absorptions at wavelength range between 210-235 nm during day 0- 49 implied that small molecules such as nitrates and carboxylic occurred faster than the aromatic molecules that were found at wavelength around 280 nm. The ratio of electron-transfer band at wavelength 253 nm by the benzonoid band at wavelength 230 nm (E253/E230) also gradually increased during the fermenting period indicating the presence of O-containing functional groups. This was in agreement with the shift change from aliphatic to aromatic structures as shown by the relationship with C/N and H/C ratios (r = - 0.631 and -0.717, p< 0.05) since both were decreasing. Although the amounts of humic acid (HA) were not different much during the humification process, the UV spectral deconvolution showed better qualitative characteristics to help in determining the compost quality. From this study, the compost should be used at day 49 and should not be kept longer than 3 months otherwise the quality of HA would decline regardless of the amounts of HA that might be rising. This implied that other processes, such as mineralization had an influence on the humification process changing HA-s structure and its qualities.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1079774Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1287
 M. Domeizel, A. Khalil, and P. Prudent,”UV spectroscopy: a tool for monitoring humification and for proposing an index of the maturity of compost,” Bioreour. Technol.., vol. 94, pp. 174-184, Feb. 2004.
 M. Fuentes, G. González-Gaitano, and J. M. García-Mina, "The usefulness of UV-visible and fluorescence spectroscopies to study the chemical nature of humic substances from soils and composts,” Org. Geochem., vol. 37, pp.1949-1959, Sept. 2006.
 M. Fukushima, K. Yamamoto, K. Ootsuka, T. Komai, T. Aramaki, S. Ueda, and S. Horiya, "Effects of the maturity of wood waste compost on the structural features of humic acids,” Bioresour. Technol., vol. 100, pp.791-797, Jul. 2008.
 F. Sellami, S. Hachicha, M. Chtourou, K. Medhioub, and D. Ammar, "Maturity assessment of composted olive mill wastes using UV spectra and humification parameters,” Bioresour. Technol., vol. 99, pp.6900-6907, Mar. 2008.
 International Humic Substances Society, Isolation of IHSS Samples. Located at http//ihss.gatech.edu/isolation.html. Accessed Apr 8, 2010.
 M. Benito, A. Masaguer, A. Moliner, N. Arrigo, and R. M. Palma, "Chemical and microbilogical parameters for the characterization of the stability and maturity of pruning waste compost,” vol. 37, pp. 184-189, Feb. 2003.
 K. H. Tan, Humic matter in soil and the environment. New York: Marcel Dekker, Inc., 2003, pp. 131-133.
 J. Pajaczkowska, A. Sulkowska, W. W. Sulkowski, and M. Jedrzejczyk, "Spectroscopic study of the humification process during sewage sludge treatment,” vol. 651-653, pp. 141-149, Jan. 2003.