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Study of Soil Contaminated with Arsenic, Cadmium and Lead in Ancient Tailings in Zacatecas, México

Authors: J. Ramírez-Ortiz, J. Núñez Monreal

Abstract:

Due to the growth of the urban area towards lands contaminated with ancient tails, in this work we evaluated if the leaching with calcium thiosulfate (CaS2O3) for the recovery of silver, gold and mercury from this soil, also dissolves arsenic, cadmium and lead; for this, we determined their quantity per each fraction of size of particle of the soil before and after the dissolution. Half of the soil samples were leached in the plant Beneficiadora de Jales del Centro, S. A. de C.V. and the rest of them remained in the laboratory. The ICP-OES technique was used to determine the amounts of arsenic, cadmium and lead, in the samples of both lots. The soil samples were collected in a neighboring area at El Lampotal, Vetagrande, Zacatecas, México, with an extension of 600 m2 at 22º52' 37.69'' N, 102º25' 11.73'' W. The amount of arsenic, cadmium and lead found in nonleached soil and for a particle size of 47 μm was 203.72±3.73, 33.63±1.31 and 3480.99±20.4 mg/kg respectively.

Keywords: Arsenic, Cadmium, Lead, Soil, Tails.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1079010

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References:


[1] M. Bargall├│ "La miner├¡a y la metalurgia en la América Espa├▒ola durante la época colonial", México: Fondo de Cultura Econ├│mica. 1955, pp. 115.
[2] M. Bargall├│ "La amalgamaci├│n de los minerales de plata en Hispanoamérica colonial", México Compa├▒├¡a Fundidora de Fierro y Acero de Monterrey. 1969, pp. 60.
[3] SEMARNAT. Action plan for La Zacatecana dam for the contention of heavy metals. México, 2002.
[4] T. Ogura, J. Ram├¡rez-Ortiz, Z. M. Arroyo-Villase├▒or, S. Hern├índez- Mart├¡nez, J. P. Palafox-Hern├índez, L. H. Garc├¡a de Alba, Q. Fernando. "Zacatecas (México) companies extract Hg from surface soil contaminated by ancient mining industries": Water Air Soil Pollut, vol. 148, no. , pp. 167-177. 2003.
[5] E. Santos-Santos, M. Yarto-Ramírez , I. Gavilán-García, J. Castro-Díaz, A. Gavilán-García, R. Rosiles, S. Suarez, T. López-Villegas, "Analysis of arsenic, lead and mercury in farming areas with mining contaminated soils at Zacatecas, Mexico", J Mex Chem Soc, vol. 50, no. , pp. 57-63, 2006.
[6] C. A. Stetefelt "The lixiviation of silver-ore with hyposulphite solutions with special reference to the Russell process", 2nd ed. The Tutle Morehouse & Taylor, New Haven , Conn. 1895, pp. 210.
[7] B. J. Mason, "Preparation of soil sampling protocols: sampling techniques and strategies" US-EPA/600/R-92/128. 1992.
[8] Google 2008 Lead Dog consulting, 2008Cnes/Spot Image, 2008 Digital globe.
[9] Link, D. Dirk, P. J. Walter, H. M. Skip Kingston, "Development and Validation of the New EPA Microwave-Assisted Leach Method 3051A," Environ. Sci. Technol. vol. 32, pp. 3628-3632, 1998.
[10] U.S. EPA. 2007, Test Method 3015A. on line "Microwave Assisted Acid Digestion of aqueous samples and extracts". Available on: http:// www.epa.gov/osw/hazard/testmethods/sw846/pdfs/3015a.pdf.
[11] K. S. Subramanian, "Deterrmination of lead in blood: comparison of two GFAAS methods", Atomic Spectroscopy vol. 8, pp. 7-11, 1987.
[12] D. B. Levy, K. H.Custis, W. H. Casey, P. A. Rock, "A comparation of metal attenuation in mine residue and overburden material from an abandoned copper mine", Appl. Geochem. vol. 12, pp. 203-211, 1997.
[13] M. Delfini, M. Ferrini, A. Manni, P. Massacci, L. Piga, "Arsenic leaching by Na2S to descontaminate tailings coming from colemanite processing", Minerals Engineering, vol. 16, pp. 45-50, 2003.
[14] NOM-147-SEMARNAT/SSA1-2004.
[15] D. R. Lide (ed) 2000, Handbook of Chemistry and Physics, 2000-2001, 81st ed., CRC Press, Boca Raton , pp.8-21-8-26.
[16] I. Cano-Aguilera, B.E. rubio-Campos, G. De la Rosa, A.F. Aguilera- Alvarado. "Arsenic mobility from mining tailings of monte san nicolas to presa de mata in Guanajuato, mexico" International Journal of Chemical and Biomolecular Engineering. vol. 4, no. 1, pp. 181-184. 2008.