Volatility of Cu, Ni, Cr, Co, Pb, and As in Fluidised-Bed Combustion Chamber in Relation to Their Modes of Occurrence in Coal
Modes of occurrence of Pb, As, Cr, Co, Cu, and Ni in bituminous coal and lignite were determined by means of sequential extraction using NH4OAc, HCl, HF and HNO3 extraction solutions. Elemental affinities obtained were then evaluated in relation to volatility of these elements during the combustion of these coals in two circulating fluidised-bed power stations. It was found out that higher percentage of the elements bound in silicates brought about lower volatility, while higher elemental proportion with monosulphides association (or bound as exchangeable ion) resulted in higher volatility. The only exception was the behavior of arsenic, whose volatility depended on amount of limestone added during the combustion process (as desulphurisation additive) rather than to its association in coal.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1076786Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1457
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