Study of Mechanical Properties of Glutarylated Jute Fiber Reinforced Epoxy Composites
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Study of Mechanical Properties of Glutarylated Jute Fiber Reinforced Epoxy Composites

Authors: V. Manush Nandan, K. Lokdeep, R. Vimal, K. Hari Hara Subramanyan, C. Aswin, V. Logeswaran

Abstract:

Natural fibers have attained the potential market in the composite industry because of the huge environmental impact caused by synthetic fibers. Among the natural fibers, jute fibers are the most abundant plant fibers which are manufactured mainly in countries like India. Even though there is a good motive to utilize the natural supplement, the strength of the natural fiber composites is still a topic of discussion. In recent days, many researchers are showing interest in the chemical modification of the natural fibers to increase various mechanical and thermal properties. In the present study, jute fibers have been modified chemically using glutaric anhydride at different concentrations of 5%, 10%, 20%, and 30%. The glutaric anhydride solution is prepared by dissolving the different quantity of glutaric anhydride in benzene and dimethyl-sulfoxide using sodium formate catalyst. The jute fiber mats have been treated by the method of retting at various time intervals of 3, 6, 12, 24, and 36 hours. The modification structure of the treated fibers has been confirmed with infrared spectroscopy. The degree of modification increases with an increase in retention time, but higher retention time has damaged the fiber structure. The unmodified fibers and glutarylated fibers at different retention times are reinforced with epoxy matrix under room temperature. The tensile strength and flexural strength of the composites are analyzed in detail. Among these, the composite made with glutarylated fiber has shown good mechanical properties when compared to those made of unmodified fiber.

Keywords: Flexural properties, glutarylation, glutaric anhydride, tensile properties.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.2643557

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References:


[1] J. R. Barone, W. F. Schmidt / Composites Science and Technology, Elsevier, (2005) 173–181, P 65.
[2] Chawla KK/ Composite materials, Springer; 1987. p. 200–202;79–86.
[3] V. R. Gowariker, N. V. Viswanathan, Jayadev Sreedhar, Polymer Science, First Edition New age International Publishers, India, 2014, pp466.
[4] B. F. Yousif et al. / Materials and Design 40 (2012) 378–385.
[5] Abdul Khalil H. P. S, Ismail. H, Ahmad. M. N, Ariffin. A and Hassan. K. / The effect of various anhydride modifications on mechanical properties and water absorption of oil palm empty fruit bunches reinforced polyester composites / Polymer International 50, 395- 402.
[6] Abdul Khalil, H. P. S., Khairul, A., Bakare, I. O., and Bhat, I.-U.-H. (2010) Thermal, spectroscopic, and flexural properties of anhydride modified cultivated Acacia spp, Wood Science Technology, DOI 10.1007/s00226-010-0365-z.
[7] Corrales F, Vilaseca F, Llop M, Gironès J, Méndez, J. A., and Mutjè P. Chemical modification of jute fibers for the production of green composites,” Journal of Hazardous Materials 144, (2007) 730-735.
[8] Edeerozey, A. M. M., Akil, H. M., Azhar, A. B., and Zainal Ariffin, M. I. (2007). “Chemical modification of kenaf fibers,” Materials Letters 61, 2023-2025.
[9] George, J., Sreekala, M. S., and Thomas, S. (2001). “A review on interface modification and characterization of natural fiber reinforced plastic composites,” Polymer Engineering & Science 41(9), 1471-1485.
[10] John, M. J., and Anandjiwala, R. D. (2008). “Recent developments in chemical modification and characterization of natural fiber-reinforced composites,” Polymer Composites 29(2), 187-207.
[11] Li, X., Tabil, L. G., and Panigrahi, S. (2007). “Chemical treatments of natural fiber for use in natural fiber-reinforced composites: A review,” J Polym Environ 15, 25-33.
[12] Rowell, R. M. (1991). “Chemical modification of wood,” In: Wood and Cellulosic Chemistry, Hon, D. N. S., and Shiraishi, N. (eds.), Marcel Dekker Inc., New York, 703-756.Y. Yorozu, M. Hirano, K. Oka, and Y. Tagawa, “Electron spectroscopy studies on magneto-optical media and plastic substrate interfaces(Translation Journals style),” IEEE Transl. J. Magn.Jpn., vol. 2, Aug. 1987, pp. 740–741 (Dig. 9th Annu. Conf. Magnetics Japan, 1982, p. 301).
[13] Tserki, V, Zafeiropoulos, N. E, Simon, F, and Panayiotou, C. (2005). “A study of the effect of acetylation and propionylation surface treatments on natural fibres,” Composites Part A 36, 1110-1118.
[14] Xiao, B., Sun, X. F., and Sun, R. C. (2001). “The chemical modification of lignins with succinic anhydride in aqueous systems,” Polymer Degradation and Stability 71, 223- 231.
[15] Hong CK, Hwang I, Kim N, Park DH, Hwang BS, Nah C. Mechanical properties of silanized jute-polypropylene composites. J Ind Eng Chem 2008;14:1471–6.
[16] Y. R. Sharma, Elementary Organic Spectroscopy, Principles and chemical applications, S. Chand & Company Ltd, Delhi.
[17] R. Vimal, K. Harihara Subramaniyan, C. Aswin, V. Logewaran, Materials Today: Proceedings. 2 (2015) 2918-2927.
[18] H. Anuar, A. Zuraida, Composites: B, 42 (2011) 462–465.
[19] B. K. Goriparthi, K. N. S. Suman, N. M. Rao, Composites:A, 43 (2012) 1800–1808.
[20] M. Ramesh, K. Palanikumar, K. Hemachandra Reddy, Comparative Evaluation on Properties of Hybrid Glass Fiber- Sisal/Jute Reinforced Epoxy Composites, Procedia Engineering, Elsevier. 51 (2013) 745 – 750.