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Optimization of Soybean Oil by Modified Supercritical Carbon Dioxide

Authors: N. R. Putra, A. H. Abdul Aziz, A. S. Zaini, Z. Idham, F. Idrus, M. Z. Bin Zullyadini, M. A. Che Yunus

Abstract:

The content of omega-3 in soybean oil is important in the development of infants and is an alternative for the omega-3 in fish oils. The investigation of extraction of soybean oil is needed to obtain the bioactive compound in the extract. Supercritical carbon dioxide extraction is modern and green technology to extract herbs and plants to obtain high quality extract due to high diffusivity and solubility of the solvent. The aim of this study was to obtain the optimum condition of soybean oil extraction by modified supercritical carbon dioxide. The soybean oil was extracted by using modified supercritical carbon dioxide (SC-CO2) under the temperatures of 40, 60, 80 °C, pressures of 150, 250, 350 Bar, and constant flow-rate of 10 g/min as the parameters of extraction processes. An experimental design was performed in order to optimize three important parameters of SC-CO2 extraction which are pressure (X1), temperature (X2) to achieve optimum yields of soybean oil. Box Behnken Design was applied for experimental design. From the optimization process, the optimum condition of extraction of soybean oil was obtained at pressure 338 Bar and temperature 80 °C with oil yield of 2.713 g. Effect of pressure is significant on the extraction of soybean oil by modified supercritical carbon dioxide. Increasing of pressure will increase the oil yield of soybean oil.

Keywords: Soybean oil, SC-CO2 extraction, yield, optimization.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1474711

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References:

Koszegi, K., G. Vatai, and E. Békássy-Molnár, "Comparison the Soxhlet and Supercritical Fluid Extraction of Nettle Root (Urtica dioica L.)". Periodica Polytechnica. Chemical Engineering, 59(3): p. 168, 2015.
[2] Bimakr, M., R. A. Rahman, F. S. Taip, A. Ganjloo, L. M. Salleh, J. Selamat, A. Hamid, and I. Zaidul, "Comparison of different extraction methods for the extraction of major bioactive flavonoid compounds from spearmint (Mentha spicata L.) leaves". Food and bioproducts processing, 89(1): p. 67-72, 2011.
[3] Guan, W., S. Li, R. Yan, S. Tang, and C. Quan, "Comparison of essential oils of clove buds extracted with supercritical carbon dioxide and other three traditional extraction methods". Food Chemistry, 101(4): p. 1558-1564, 2007.
[4] Corzzini, S. C., H. D. Barros, R. Grimaldi, and F. A. Cabral, "Extraction of edible avocado oil using supercritical CO 2 and a CO 2/ethanol mixture as solvents". Journal of Food Engineering, 194: p. 40-45, 2017.
[5] Machmudah, S., Y. Kawahito, M. Sasaki, and M. Goto, "Supercritical CO2 extraction of rosehip seed oil: Fatty acids composition and process optimization". Journal of Supercritical Fluids, 41(3): p. 421-428, 2007.
[6] Yunus, A., NH, S. Zhari, Z. Idham, S. Setapar, and A. Mustapha, "Effect of supercritical carbon dioxide condition on oil yield and solubility of Pithecellobium Jiringan (Jack) Prain seeds". J. Teknologi, 60: p. 45-50, 2013.
[7] Putra, N. R., A. H. A. Aziz, L. N. Yian, W. D. Ramli, and M. A. C. Yunus. Optimization of Supercritical Carbon Dioxide and Co-solvent Ethanol Extraction of Wasted Peanut Skin Using Response Surface Methodology. in MATEC Web of Conferences. 2018. EDP Sciences.
[8] Zancan, K. C., M. O. Marques, A. J. Petenate, and M. A. A. Meireles, "Extraction of ginger (Zingiber officinale Roscoe) oleoresin with CO 2 and co-solvents: a study of the antioxidant action of the extracts". The Journal of supercritical fluids, 24(1): p. 57-76, 2002.
[9] Duarte, M. C. T., G. M. Figueira, A. Sartoratto, V. L. G. Rehder, and C. Delarmelina, "Anti-Candida activity of Brazilian medicinal plants". Journal of ethnopharmacology, 97(2): p. 305-311, 2005.
[10] Gião, M. S., C. I. Pereira, S. C. Fonseca, M. E. Pintado, and F. X. Malcata, "Effect of particle size upon the extent of extraction of antioxidant power from the plants Agrimonia eupatoria, Salvia sp. and Satureja montana". Food Chemistry, 117(3): p. 412-416, 2009.
[11] Herrero, M., A. Cifuentes, and E. Ibañez, "Sub-and supercritical fluid extraction of functional ingredients from different natural sources: Plants, food-by-products, algae and microalgae: A review". Food chemistry, 98(1): p. 136-148, 2006.
[12] Jokić, S., S. Svilović, Z. Zeković, and S. Vidović, "Mathematical modelling of soybean oil solubility in supercritical carbon dioxide". International journal of food science & technology, 46(5): p. 1031-1037, 2011.
[13] Lummaetee, K., H. M. Ku, W. Wongrat, and A. Elkamel, "Optimization of supercritical fluid extraction of isoflavone from soybean meal". The Canadian Journal of Chemical Engineering, 95(6): p. 1141-1149, 2017.
[14] Mohamed, H. B., K. S. Duba, L. Fiori, H. Abdelgawed, I. Tlili, T. Tounekti, and A. Zrig, "Bioactive compounds and antioxidant activities of different grape (Vitis vinifera L.) seed oils extracted by supercritical CO 2 and organic solvent". LWT-Food Science and Technology, 74: p. 557-562, 2016.
[15] Kopcak, U. and R. S. Mohamed, "Caffeine solubility in supercritical carbon dioxide/co-solvent mixtures". The Journal of supercritical fluids, 34(2): p. 209-214, 2005.
[16] Marongiu, B., A. Piras, and S. Porcedda, "Comparative analysis of the oil and supercritical CO2 extract of Elettaria cardamomum (L). Maton". Journal of Agricultural and Food Chemistry, 52(20): p. 6278-6282, 2004.
[17] Salleha, L. M., H. M. Nasira, H. Yaakobc, and M. A. C. Yunusa, "Determination of Supercritical Carbon Dioxide Extraction Parameters for Quercus infectoria Galls and the Effects on Extraction Yield and Antioxidant Activity". J. Teknol, 67: p. 1-4, 2014.
[18] Ikushima, Y., N. Saito, M. Arai, and K. Arai, "Solvent polarity parameters of supercritical carbon dioxide as measured by infrared spectroscopy". Bulletin of the Chemical Society of Japan, 64(7): p. 2224-2229, 1991.
[19] Freed, B.K., J. Biesecker, and W. Middleton, "Spectral polarity index: a new method for determining the relative polarity of solvents (1)". Journal of Fluorine Chemistry, 48(1): p. 63-75, 1990.
[20] Machmudah, S., A. Shotipruk, M. Goto, M. Sasaki, and T. Hirose, "Extraction of astaxanthin from Haematococcus p luvialis using supercritical CO2 and ethanol as entrainer". Industrial & engineering chemistry research, 45(10): p. 3652-3657, 2006.
[21] Trabelsi, D., A. Aydi, A.W. Zibetti, G. Della Porta, M. Scognamiglio, V. Cricchio, E. Langa, M. Abderrabba, and A. M. Mainar, "Supercritical extraction from Citrus Aurantium amara peels using CO 2 with ethanol as co-solvent". The Journal of Supercritical Fluids, 117: p. 33-39, 2016.
[22] Snyder, J., J. Friedrich, and D. Christianson, "Effect of moisture and particle size on the extractability of oils from seeds with supercritical CO2". Journal of the American Oil Chemists’ Society, 61(12): p. 1851-1856, 1984.
[23] Yunus, M., M. Hasan, N. Othman, S. Mohd-Septapar, M. Ahmad-Zaini, Z. Idham, and S. Zhari, "Effect of particle size on the oil yield and catechin compound using accelerated solvent extraction". J. Teknol. (Sci. Eng.), 60: p. 21-25, 2013.
[24] Putra, N. R., A. H. A. Aziz, Z. Idham, M. S. H. Ruslan, and M. A. C. Yunus, "Diffusivity optimization of supercritical carbon dioxide extraction with co-solvent-ethanol from peanut skin". Malaysian Journal of Fundamental and Applied Sciences, 14(1), 2018.
[25] Putra, N., L. Yian, H. Nasir, Z. B. Idham, and M. Yunus. Effects of process parameters on peanut skins extract and CO2 diffusivity by supercritical fluid extraction. in IOP Conference Series: Materials Science and Engineering. 2018. IOP Publishing.
[26] Hasmida, M., M. Liza, A. Nur Syukriah, Y. Harisun, C. Mohd Azizi, and A. Fadzilah Adibah, "Total Phenolic Content and Antioxidant Activity of Quercus infectoria Galls Using Supercritical CO2 Extraction Technique and Its Comparison with Soxhlet Extraction". Pertanika Journal of Science & Technology, 23(2), 2015.
[27] Danlami, J. M., M. A. A. Zaini, A. Arsad, and M. A. C. Yunus, "Solubility assessment of castor (Ricinus communis L) oil in supercritical CO 2 at different temperatures and pressures under dynamic conditions". Industrial Crops and Products, 76: p. 34-40, 2015.