Commenced in January 2007
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Obtaining Composite Cotton Fabric by Cyclodextrin Grafting

Authors: U. K. Sahin, N. Erdumlu, C. Saricam, I. Gocek, M. H. Arslan, H. Acikgoz-Tufan, B. Kalav


Finishing is an important part of fabric processing with which a wide range of features are imparted to greige or colored fabrics for various end-uses. Especially, by the addition or impartation of nano-scaled particles to the fabric structure composite fabrics, a kind of composite materials can be acquired. Composite materials, generally shortened as composites or in other words composition materials, are engineered or naturally occurring materials made from two or more component materials with significantly different physical, mechanical or chemical characteristics remaining separate and distinctive at the macroscopic or microscopic scale within the end product structure. Therefore, the technique finishing which is one of the fundamental methods to be applied on fabrics for obtainment of composite fabrics with many functionalities was used in the current study with the same purpose. However, regardless of the finishing materials applied, the efficient life of finished product on offering desired feature is low, since the durability of finishes on the material is limited. Any increase in durability of these finishes on textiles would enhance the life of use for textiles, which will result in happier users. Therefore, in this study, since higher durability was desired for the finishing materials fixed on the fabrics, nano-scaled hollow structured cyclodextrins were chemically imparted by grafting to the structure of conventional cotton fabrics by the help of finishing technique in order to be fixed permanently. By this way, a processed and functionalized base fabric having potential to be treated in the subsequent processes with many different finishing agents and nanomaterials could be obtained. Henceforth, this fabric can be used as a multi-functional fabric due to the encapturing ability of cyclodextrins to molecules/particles via physical/chemical means. In this study, scoured and rinsed woven bleached plain weave 100% cotton fabrics were utilized because textiles made of cotton are the most demanded textile products in the textile market by the textile consumers in daily life. Cotton fabric samples were immersed in treating baths containing β-cyclodextrin and 1,2,3,4-butanetetracarboxylic acid and to reduce the curing temperature the catalyst sodium hypophosphite monohydrate was used. All impregnated fabric samples were pre-dried. The reaction of grafting was performed in dry state. The treated and cured fabric samples were rinsed with warm distilled water and dried. The samples were dried for 4 h and weighed before and after finishing and rinsing. Stability and durability of β-cyclodextrins on fabric surface against external factors such as washing as well as strength of functionalized fabric in terms of tensile and tear strength were tested. Presence and homogeneity of distribution of β-cyclodextrins on fabric surface were characterized.

Keywords: Cotton fabric, cyclodextrin, improved durability, multifunctional composite textile.

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[1] Bojana Voncina and Vera Vivod, (n. d.). Cyclodextrins in textile finishing. Chapter 3.
[2] Aurelia Grigoriu and Octavian Popescu, (2011). Applications of cyclodextrins in textiles – A review. pp. 48-64.
[3] E.M. Martin Del Valle, (2003). Cyclodextrins and their uses: a review. pp. 1-12.
[4] Jun-hua Wang, Zaisheng Cai, (2008). Incorporation of the antibacterial agent, miconazole nitrate into a cellulosic fabric grafted with β-cyclodextrin. pp. 695-700.
[5] F.A. Abdel-Mohdy, Moustafa M.G. Fouda, M.F. Rehan, A.S. Aly, (2008). Repellency of controlled-release treated cotton fabrics based on cypermethrin and prallethrin. pp. 92-97.
[6] E.S. Abdel-Halim, Mostafa M.G. Fouda, I. Hamdy, (2010). Incorporation of chlorohexidin diacetate into cotton fabrics grafted with glycidyl methacrylate and cyclodextrin. pp. 47-53.
[7] Amira El Shafei, S. Shaarawy, A. Hebeish, (2010). Application of reactive cyclodextrin poly butyl acrylate preformed polymers containing nano-ZnO to cotton fabrics and their impact on fabric performance. pp. 852-857.
[8] N.A. Ibrahim, W.R. E-Zairy, B.M. Eid, (2010). Novel approach for improving disperse dyeing and UV-protective function of cotton-containing fabrics using MCT-β-CD. pp. 839-846.
[9] A. Hebeish, A. El-Shafei∗, S. Sharaf, S. Zaghloul, (2011). Novel precursors for green synthesis and application of silver nanoparticles in the realm of cotton finishing. pp. 605-613.
[10] E.S. Abdel-Halim, F.A. Abdel-Mohdy, Moustafa M.G. Fouda, (2011). Antimicrobial activity of monochlorotriazinyl – β-cyclodextrin/ chlorohexidin diacetate finished cotton fabrics. pp. 1389-1394.
[11] Malihe Nazi, Reza Mohammad Ali Malek, Richard Kotek, (2012). Modification of β-cyclodextrin with itaconic acid and application of the new derivative to cotton fabrics. pp. 950-958.
[12] Cezar-Doru Radu, Mihaela Salariu, Manuela Avadanei, (2013). Cotton-made cellulose support for anti-allergic pajamas. pp. 479-486.
[13] A. Hebeish, S.M. EL-Sawy, M.Ragaei, (2014). New textiles of biocidal activity by introduce insecticide in cotton-poly (GMA) copolymer containing β-Cd. pp. 208-217.
[14] E.S. Abdel-Halim∗, Salem S. Al-Deyab, Ali Y.A. Alfaifi, (2014). Cotton fabric finished with β-cyclodextrin: Inclusion ability toward antimicrobial agent. pp. 550-556.
[15] Vasilica Popescu, Ecaterina Vasluianu, Gabriel Popescu, (2014). Quantitative analysis of the multifunctional finishing of cotton fabricwith non-formaldehyde agents. pp. 870-882.
[16] A. Hebeish, A. El-Shafei, S. Sharaf, S. Zaghloul, (2014). Development of improved nanosilver-based antibacterial textiles viasynthesis of versatile chemically modified cotton fabrics. pp. 455-462.
[17] Vahid Ameri Dehabadi, Hans-Jurgen Buschmann, Jochen Stefan Gutmann, (2013). A novel approach for fixation of β-cyclodextrin on cotton fabrics. pp. 459-464.
[18] Myung Hak Lee, Kee Jong Yoon, Sohk-Won Ko, (2000). Grafting onto cotton fiber with acrylamidomethylated β-cyclodextrin and ıts application. pp. 1987-1991.
[19] Santo Scalia, Rosanna Tursilli, Anna Bianchi, (2006). Incorporation of the sunscreen agent, octyl methoxycinnamate in a cellulosic fabric grafted with β-cyclodextrin. pp. 155-159.
[20] Pierandrea Lo Nostro, Laura Fratoni, Pıero Baglioni, (2002). Modification of a cellulosic fabric with β-cyclodextrin for textile finishing applications. pp. 423-427.
[21] B. Medronho, R. Andrade, V. Vivod, (2013). Cyclodextrin-grafted cellulose: physico-chemical characterization. pp. 324-330.