Effect of Gamma Radiation on Bromophenol Blue Dyed Films as Dosimeter
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Effect of Gamma Radiation on Bromophenol Blue Dyed Films as Dosimeter

Authors: Priyanka R. Oberoi, Chandra B. Maurya, Prakash A. Mahanwar

Abstract:

Ionizing radiation can cause a drastic change in the physical and chemical properties of the material exposed. Numerous medical devices are sterilized by ionizing radiation. In the current research paper, an attempt was made to develop precise and inexpensive polymeric film dosimeter which can be used for controlling radiation dosage. Polymeric film containing (pH sensitive dye) indicator dye Bromophenol blue (BPB) was casted to check the effect of Gamma radiation on its optical and physical properties. The film was exposed to gamma radiation at 4 kGy/hr in the range of 0 to 300 kGy at an interval of 50 kGy. Release of vinyl acetate from an emulsion on high radiation reacts with the BPB fading the color of the film from blue to light blue and then finally colorless, indicating a change in pH from basic to acidic form. The change was characterized by using CIE l*a*b*, ultra-violet spectroscopy and FT-IR respectively.

Keywords: Bromophenol blue, dosimeter, gamma radiation, polymer.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1126471

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References:


[1] W. L. McLaughlin, “Radiation processing dosimetry,” Radiation Physics and Chemistry, vol. 21, no. 4, pp. 359-366, 1983.
[2] A. C. R. Blackwell, B. M. Coursey, K. P. Gall, J. M. Galvin, W. L. Mclaughlin, A. S. Meigooni et al., "Report of the American association of physicists in medicine task Group No. 55: Radiochromic film dosimetry," Medical Physics, vol. 25, pp. 2093-2115, 1998.
[3] S. Ebraheem and M. El-kelany, “Dosimeter film based on ethyl violet-bromophenol blue dyed poly (vinyl alcohol),” vol. 2013, no. February, pp. 1–5, 2013.
[4] A. Arshak, K. Arshak, O. Korostynska, and S. Zleetni, “Review of various gamma radiation dosimeters based on thin and thick films of metal oxides and polymer materials,” In Nuclear Science Symposium Conference Record, IEEE, vol. 1, pp. 78-82, 2003.
[5] M. A. Rauf and S. S. Ashraf, “Radiation induced degradation of dyes—an overview,” Journal of hazardous materials, vol. 166, no. 1, pp. 6-16, 2009.
[6] T. Hussain, “Gamma Radiation Effect on Commercial Reactive Dye in the Range 0-100kgy Using the Idea of the De-Coloration Factor and Extinction Coefficient,” Journal of Basic and Applied Science, vol. 30, pp. 581–584, 2012.
[7] F. Abdel Rehim and A. A. Abdel-Fattah, “A thin-film radiation monitoring label and dosimetry system,” Applied radiation and isotopes 44, no. 7, pp. 1047–1053, 1993.
[8] Holm, Niels W., and Roger J. Berry, “Manual on radiation dosimetry,” Marcel Dek, vol. 10. 1970.
[9] W. L. Ed., A. J. Goudie, E. R. L. Gaughran, W. L. McLaughlin, “Solid-Phase Chemical Dosimeter,” no. 25265. 1975.
[10] Abdel Rehim, S. Ebraheem, W. Z. Ba, and W. L. Mclaughlin, “A thin dyed-plastic dosimeter for large radiation doses,” International journal of radiation applications and instrumentation. Part A. Applied radiation and isotopes, vol. 43, no. 12, pp. 1503–1510, 1992.
[11] A. A. Abdel-Fattah, M. El-Kelany, F. Abdel-Rehim, and A. A. El Miligy, “UV-sensitive indicators based on bromophenol blue and chloral hydrate dyed poly(vinyl butyral),” Journal of Photochemistry and Photobiology A: Chemistry, vol. 110, no. 3, pp. 291–297, 1997.
[12] N. V. Bhat, M. M. Nate, M. B. Kurup, V. A. Bambole, and S. Sabharwal, “Effect of γ-radiation on the structure and morphology of polyvinyl alcohol films,” Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, vol. 237, no. 3–4, pp. 585–592, 2005.
[13] A. M. Sisti Galante, A. L. C. H. Villavicencio, and L. L. Campos, “Preliminary investigations of several new dyed PMMA dosimeters,” Radiation Physics and Chemistry, vol. 71, no. 1–2, pp. 391–394, 2004.
[14] A. M. S. Galante and L. L. Campos, “Electron dose radiation response of dyed PMMA detectors developed at IPEN,” Radiation protection dosimetry, vol. 120, no. 1–4, pp. 113–116, 2006.
[15] Tauste, David Gutiérrez, “Development of Soft Chemical Processes: Preparation of Tio2 Films and Powders at Low Temperature,” Universitat Autònoma de Barcelona, pp. 2–3, 2008.
[16] M. Attique, K. Shahid, B. Bashir, H. Bashir, and H. Bashir, “Dosimetric characterization and spectroscopic study of radiochromic films as natural dye dosimeters,” International journal of chemistry and material science, vol. 2, no. 2, pp. 28–45, 2014.
[17] M. Kattan, Y. Daher, and H. Alkassiri, “A high-dose dosimeter-based polyvinyl chloride dyed with malachite green,” Radiation Physics and Chemistry, vol. 76, no. 7, pp. 1195–1199, 2007.
[18] N. V. Bhat, M. M. Nate, R. M. Bhat, and B. C. Bhatt, “Effect of gamma-irradiation on polyvinyl alcohol films doped with some dyes and their use in dosimetric studies,” Indian Journal of Pure and Applied Physics 45, vol. 45, no. 6, pp. 545–548, 2007.
[19] T. Hussain, M. Shahbaz, H. Farooq, N. Amin, and Y. Jamil, “Dosimetric Characteristics of Aqueous Solutions of Sandalfix Red Dye for Gamma Dosimetry,” Journal of Basic Applied Science, vol. 8, no. 30 C, pp. 437–443, 2012.
[20] A. A. Abdel-Fattah, S. Ebraheem, M. El-Kelany, and F. Abdel-Rehim, “High-dose film dosimeters based on bromophenol blue or xylenol orange dyed polyvinyl alcohol,” Applied radiation and isotopes, vol. 47, no. 3, pp. 345–350, 1996.
[21] El-Kelany, M. “Effect of Gamma-radiation on the physical properties of poly (vinyl alcohol) Dyed with Tetrabromo phenolphthalein Ethyl Ester,” Egyptian Journal of Radiation Sciences and Applications, vol. 24, pp. 153-164, 2011.
[22] S. Practice, “Standard Practice for Computing the Colors of Objects by Using the CIE System 1,” ASTM E308, no. November, pp. 1–34, 2009.
[23] O. Evaluation, S. Using, H. Geometry, and M. C. Using, “Standard Practice for Calculating Yellowness and Whiteness Indices from Instrumentally Measured Color Coordinates 1,” ASTM E313-98, Annu. B. ASTM Stand. E313, vol. 06, no. C, pp. 1–6, 2010.
[24] X-Rite, A Guide to Understanding Color Communication, pp. 1-14, 2007.
[25] S. a. Nouh and R. a. Bahareth, “Color changes in some irradiated polymers,” Radiation Effects and Defects in Solids, vol. 167, no. 10, pp. 766–773, 2012.