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Microstructure and Electrochemical Properties of LiNi1/3Co1/3Mn1/3-xAlxO2 Cathode Material for Lithium Ion Batteries
Abstract:The layered structure LiNi1/3Co1/3Mn1/3-xAlxO2 (x = 0 ~ 0.04) series cathode materials were synthesized by a carbonate co-precipitation method, followed by a high temperature calcination process. The influence of Al substitution on the microstructure and electrochemical performances of the prepared materials was investigated by X-Ray diffraction (XRD), scanning electron microscopy (SEM), and galvanostatic charge/discharge test. The results show that the LiNi1/3Co1/3Mn1/3-xAlxO2 has a well-ordered hexagonal α-NaFeO2 structure. Although the discharge capacity of Al-doped samples decreases as x increases, LiNi1/3Co1/3Mn1/3-0.02Al0.02O2 exhibits superior capacity retention at high voltage (4.6 V). Therefore, LiNi1/3Co1/3Mn1/3-0.02Al0.02O2 is a promising material for “green” vehicles.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1338784Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1606
 Y.K. Sun, D.H. Kim, C.S. Yoon, S.T. Myung, J. Prakash, K. Amine, A Novel Cathode Material with a Concentration-Gradient for High-Energy and Safe Lithium-Ion Batteries, Adv. Funct. Mater., 20 (2010) 485-491.
 W. Luo, X. Li, J.R. Dahn, Synthesis, Characterization, and Thermal Stability of Li(Ni1/3Mn1/3Co1/3−z(MnMg)z/2)O2, Chem. Mater., 22 (2010) 5065-5073.
 J.N. Reimers, J.R. Dahn, Electrochemical and In Situ X-Ray Diffraction Studies of Lithium Intercalation in LixCoO2, J. Electrochem. Soc., 139 (1992) 2091-2097.
 M. Me´ne´trier, I. Saadoune, S.n.p. Levasseur, C. Delmas, The insulator–metal transition upon lithium deintercalation from LiCoO2: electronic properties and Li NMRstudy, J. Mater. Chem., 9 (1999) 1135-1140.
 T. Ohzuku, Y. Makimura, Layered Lithium Insertion Material of LiCo1/3Ni1/3Mn1/3O2 for Lithium-Ion Batteries, Chem. Lett., (2001) 642-643.
 Y.-S. Hea, Z.-F. Maa, X.-Z. Liaoa, Y. Jiang, Synthesis and characterization of submicron-sized LiCo1/3Ni1/3Mn1/3O2 by a simple self-propagating solid-state metathesis method, Journal of Power Sources 163 (2007) 1053-1058.
 T. Mei, Y. Zhu, K. Tang, Y. Qian, Synchronously synthesized core–shell LiCo1/3Ni1/3Mn1/3O2/carbon nanocomposites as cathode materials for high performance lithium ion batteries, RSC Advances, 2 (2012) 12886.
 K. Yin, W. Fang, B. Zhong, X. Guo, Y. Tang, X. Nie, The effects of precipitant agent on structure and performance of LiCo1/3Ni1/3Mn1/3O2 cathode material via a carbonate co-precipitation method, Electrochim. Acta, 85 (2012) 99-103.
 S.-C. Yin, Y.-H. Rho, I. Swainson, L. F. Nazar*, X-ray/Neutron Diffraction and Electrochemical Studies of Lithium De/Re-Intercalation in Li1-xCo1/3Ni1/3Mn1/3O2 (x= 0 to 1), Chem. Mater., 18 (2006) 1901-1910.
 S.H. Ju, Y.C. Kang, The characteristics of Ni–Co–Mn–O precursor and Li(Ni1/3Co1/3Mn1/3)O2 cathode powders prepared by spray pyrolysis, Ceramics International, 35 (2009) 1205-1210.
 K.M. Shaju, P.G. Bruce, Macroporous Li(Ni1/3Co1/3Mn1/3)O2: A High-Power and High-Energy Cathode for Rechargeable Lithium Batteries, Adv. Mater., 18 (2006) 2330-2334.
 X. Bie, F. Du, Y. Wang, K. Zhu, H. Ehrenberg, K. Nikolowski, C. Wang, G. Chen, Y. Wei, Relationships between the crystal/interfacial properties and electrochemical performance of LiNi0.33Co0.33Mn0.33O2 in the voltage window of 2.5–4.6V, Electrochim. Acta, 97 (2013) 357-363.
 B. Xu, D. Qian, Z. Wang, Y.S. Meng, Recent progress in cathode materials research for advanced lithium ion batteries, Materials Science and Engineering: R: Reports, 73 (2012) 51-65.
 S.-T. Myung, S. Komaba, K. Hosoya, N. Hirosaki, Y. Miura, N. Kumagai, Synthesis of LiNi0.5Mn0.5-xTixO2 by an Emulsion Drying Method and Effect of Ti on Structure and Electrochemical Properties, Chem. Mater. , 17 (2005) 2427-2435.
 W. Luo, F. Zhou, X. Zhao, Z. Lu, X. Li, J.R. Dahn, Synthesis, Characterization, and Thermal Stability of LiNi1/3Mn1/3Co1/3−zMgzO2, LiNi1/3−zMn1/3Co1/3MgzO2, and LiNi1/3Mn1/3−zCo1/3MgzO2†, Chem. Mater., 22 (2010) 1164-1172.
 P. Yue, Z. Wang, H. Guo, X. Xiong, X. Li, A low temperature fluorine substitution on the electrochemical performance of layered LiNi0.8Co0.1Mn0.1O2−zFz cathode materials, Electrochim. Acta, 92 (2013) 1-8.
 S.H. Park, S.S. Shin, Y.K. Sun, The effects of Na doping on performance of layered Li1.1−xNax(Ni0.2Co0.3Mn0.4)O2 materials for lithium secondary batteries, Materials Chemistry and Physics, 95 (2006) 218-221.
 A. Milewska, M. Molenda, J. Molenda, Structural, transport and electrochemical properties of LiNi1−yCoyMn0.1O2 and Al, Mg and Cu-substituted LiNi0.65Co0.25Mn0.1O2 oxides, Solid State Ionics, 192 (2011) 313-320.
 L. Liao, X. Wang, X. Luo, X. Wang, S. Gamboa, P.J. Sebastian, Synthesis and electrochemical properties of layered Li(Ni0.333Co0.333Mn0.293Al0.04)O2−zFz cathode materials prepared by the sol–gel method, J. Power Sources, 160 (2006) 657-661.
 Q. Liu, K. Du, H. Guo, Z.-d. Peng, Y.-b. Cao, G.-r. Hu, Structural and electrochemical properties of Co–Mn–Mg multi-doped nickel based cathode materials LiNi0.9Co0.1−x(Mn1/2Mg1/2)xO2 for secondary lithium ion batteries, Electrochim. Acta, 90 (2013) 350-357.
 Y. Huang, J. Chen, J. Ni, H. Zhou, X. Zhang, A modified ZrO2-coating process to improve electrochemical performance of LiNi1/3Co1/3Mn1/3O2, Journal of Power Sources, 188 (2009) 538-545.
 J. Lu, Q. Peng, W. Wang, C. Nan, L. Li, Y. Li, Nanoscale coating of LiMO2 (M = Ni, Co, Mn) nanobelts with Li+-conductive Li2TiO3: toward better rate capabilities for Li-ion batteries, Journal of the American Chemical Society, 135 (2013) 1649-1652.
 C.-H. Lu, Y.-K. Lin, Microemulsion preparation and electrochemical characteristics of LiNi1/3Co1/3Mn1/3O2 powders, Journal of Power Sources, 189 (2009) 40-44.
 N.N. Sinha, N. Munichandraiah, Synthesis and characterization of carbon-coated LiNi1/3Co1/3Mn1/3O2 in a single step by an inverse microemulsion route, ACS applied materials & interfaces, 1 (2009) 1241-1249.
 S.K. Jeong, K.S. Nahm, A.M. Stephan, Synthesis of Li(Co0.8Ni0.2−yAly)O2 (y≤0.02) by combustion method as a possible cathode material for lithium batteries, Materials Science and Engineering: A, 445-446 (2007) 657-662.
 F. Zhou, X. Zhao, C. Goodbrake, J. Jiang, J.R. Dahn, Solid-State Synthesis as a Method for the Substitution of Al for Co in LiNi1/3Mn1/3Co1/3−zAlzO2, Journal of The Electrochemical Society, 156 (2009) A796.
 F. Zhou, X. Zhao, Z. Lu, J. Jiang, J.R. Dahn, The effect of Al substitution on the reactivity of delithiated LiNi1/3Mn1/3Co1/3−zAlzO2 with non-aqueous electrolyte, Electrochemistry Communications, 10 (2008) 1168-1171.
 F. Zhou, X. Zhao, J.R. Dahn, Synthesis, Electrochemical Properties, and Thermal Stability of Al-Doped LiNi1/3Mn1/3Co1/3−zAlzO2 Positive Electrode Materials, Journal of The Electrochemical Society, 156 (2009) A343.
 H. Ren, X. Li, Z. Peng, Electrochemical properties of Li(Ni1/3Mn1/3Al1/3−xCox)O2 as a cathode material for lithium ion battery, Electrochimica Acta, 56 (2011) 7088-7091.
 F. Zhou, X. Zhao, Z. Lu, J. Jiang, J.R. Dahn, The Effect of Al Substitution on the Reactivity of Delithiated LiNi0.5−zMn0.5−zA12zO2 with Nonaqueous Electrolyte, Electrochemical and Solid-State Letters, 11 (2008) A155.
 L. Croguennec, J. Bains, J. Bréger, C. Tessier, P. Biensan, S. Levasseur, C. Delmas, Effect of Aluminum Substitution on the Structure, Electrochemical Performance and Thermal Stability of Li1+x(Ni0.40Mn0.40Co0.20−zAlz)1−xO2, Journal of The Electrochemical Society, 158 (2011) A664.
 Y. Ding, P. Zhang, Z. Long, Y. Jiang, F. Xu, Morphology and electrochemical properties of Al doped LiNi1/3Co1/3Mn1/3O2 nanofibers prepared by electrospinning, Journal of Alloys and Compounds, 487 (2009) 507-510.
 T. Ohzuku, Atsushi Ueda, M. Nagayama, Electrochemistry and Structural Chemistry of LiNiO2 (R3m) for 4 Volt Secondary Lithium Cells, J. Electrochem. Soc., 140 (1993) 1862-1869.
 T.E. Conry, A. Mehta, J. Cabana, M.M. Doeff, Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1–yAlyO2 Positive Electrode Materials for Li-ion Batteries, Chem. Mater., 24 (2012) 3307-3317.