Up Scaling of Highly Transparent Quasi-Solid State, Dye-Sensitized Solar Devices Composed of Nanocomposite Materials
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33104
Up Scaling of Highly Transparent Quasi-Solid State, Dye-Sensitized Solar Devices Composed of Nanocomposite Materials

Authors: Dimitra Sygkridou, Andreas Rapsomanikis, Elias Stathatos, Polycarpos Falaras, Evangelos Vitoratos

Abstract:

At the present work, highly transparent strip type quasi-solid state dye-sensitized solar cells (DSSCs) were fabricated through inkjet printing using nanocomposite TiO2 inks as raw materials and tested under outdoor illumination conditions. The cells, which can be considered as the structural units of large area modules, were fully characterized electrically and electrochemically and after the evaluation of the received results a large area DSSC module was manufactured. The module design was a sandwich Z-interconnection where the working electrode is deposited on one conductive glass and the counter electrode on a second glass. Silver current collective fingers were printed on the conductive glasses to make the internal electrical connections and the adjacent cells were connected in series and finally insulated using a UV curing resin to protect them from the corrosive (I-/I3-) redox couple of the electrolyte. Finally, outdoor tests were carried out to the fabricated dye-sensitized solar module and its performance data were collected and assessed.

Keywords: Dye-sensitized solar devices, inkjet printing, quasi-solid state electrolyte, transparency, up scaling.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1109830

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1642

References:


[1] M. Späth, P. M. Sommeling, J. A. M. Van Roosmalen, H. J. P. Smit, N. P. G. van der Burg, D. R. Mahieu, N. J. Bakker, J. M. Kroon, “Reproducible Manufacturing of Dye-Sensitized Solar Cells on a Semi- Automated Baseline”, Progress in Photovoltaics: Research and applications, vol. 11, pp. 207-220, February 2003.
[2] F. E. Gálvez, E. Kemppainen, H. Míguez and J. Halme, “Effect of Diffuse Light Scattering Designs on the Efficiency of Dye Solar Cells: An Integral Optical and Electrical Description”, J. Phys. Chem. C, vol. 116, pp. 11426-11433, May 2012.
[3] S. Mathew, A. Yella, P. Gao, R. Humphry-Baker, B. F. E. Curchod, N. Ashari-Astani, I. Tavernelli, U. Rothlisberger, Md. K. Nazeeruddin, M. Grätzel, “Dye-Sensitized Solar Cells with 13% Efficiency Achieved through the Molecular Engineering of Porphyrin Sensitizers”, Nature Chemistry, vol. 6, pp. 242-247, February 2014.
[4] J. Goldstein, I; Yakypov, B. Breen, “Development of Large Area Photovoltaic Dye Cells at 3GSolar”, Solar Energy Materials and Solar cells, vol. 94, pp/ 638-641, April 2010.
[5] G. R. A. Kumara, S. Kawasaki, P. V. V. Jayaweera, E. V. A. Premalal, S. Kaneko, “Large Area Dye-Sensitized Solar Cells with Titanium based Counter Electrode”, Thin Solid Films, vol. 520, pp. 4119-4121, April 2011.
[6] “Fabrication and Characterization of Interconnected Grip-type Dye- Sensitized Solar Modules”, Int. J. Electrochem. Sci., vol. 7, pp. 11904- 11916, December 2012.
[7] “Design Methods for Large Scale Dye-Sensitized Solar Modules and the Progress of Stability Research”, Renewable and Sustainable Energy Reviews, vol. 14, pp. 3178-3184, June 2010.
[8] E. Stathatos, P. Lianos, A. Surca Vuk, B. Orel, “Optimization of a Quasi-Solid-State Dye-Sensitized Photoelectrochemical Solar Cell Employing a Ureasil/Sulfolane Gel Electrolyte”, Adv. Funct. Mater., vol. 14, pp. 45-48, January 2004.
[9] E. Stathatos, “Organic-Inorganic Nanocomposite Materials Prepared by the Sol-Gel Route as New Ionic Conductors in Quasi Solid State Electrolytes”, Ionics, vol. 11, pp. 140–145, November 2004.
[10] E. Stathatos, P. Lianos, U. L. Stangar, B. Orel, and P. Judeinstein, “Structural Study of Hybrid Organic/Inorganic Polymer Gels Using Time-Resolved Fluorescence Probing”, Langmuir, vol. 16, pp. 8672– 8676, June 2000.
[11] J. E. Benedetti, F. S. Freitas, F. C. Fernandes, A. S. Gonçalves, A. Magalhães, A. F. Nogueira, “Investigation of the Structural Properties of Poly(Ethylene Oxide) Copolymer as Gel Polymer Electrolyte and Durability Test in Dye-Sensitized Solar Cells”, Ionics, vol. 21, pp. 1771- 1780, December 2014.
[12] F. Fabregat-Santiago, G. Garcia-Belmonte, I. Mora-Seró, J. Bisquert, “Characterization of Nanostructured Hybrid and Organic Solar Cells by Impedance Spectroscopy”, Phys. Chem. Chem. Phys., vol. 13, pp. 9083- 9118, March 2011.
[13] Q. Wang, J.-E. Moser, M. Grätzel, “Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells”, J. Phys. Chem. B, vol. 109, pp. 14945-14953, July 2005.
[14] E. Barsoukov, J. R. Macdonald, “Impedance Spectroscopy Theory, Experiment, and Applications”, Wiley- Interscience, pp.65, 79, April 2005.