Weight Loss Degradation of Hybrid Blends LLDPE/Starch/PVA upon Exposure to UV Light and Soil Burial
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Weight Loss Degradation of Hybrid Blends LLDPE/Starch/PVA upon Exposure to UV Light and Soil Burial

Authors: M. Rahmah, Noor Zuhaira Abd Aziz, M. Mohd Muizz Fahimi, M. Farhan

Abstract:

Poly bag and mulch films for agricultural field caused pose environmental problem due to the non-degradable plastics wastes upon disposal. Thus, a degradable poly bag was designed with hybrid sago starch (SS) and polyvinyl alcohol (PVA). Two Different blended compositions of SS and PVA hybrid have been compounded. Then, the hybrids blended are mixed with linear line density polyethylene (LLDPE) resin to fabricate poly bag film through conventional film blowing process. Samples of LLDPE, SS and PVA hybrid film were exposed to UV light and soil burial. The weight losses were determined during degradation process. Hybrid film by degradation of starch was found to hydrolyze and hydroxyl groups decrease on esterification upon exposure to soil burial and uv radiation. It was found out that, the hybrid film for 60% of SS composition showed greatest degradation in soil and UV radiation.

Keywords: LLDPE, PVA, sago starch, degradation, soil burial, UV radiation.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1100571

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[1] Rahmah, M., Farhan, M., & Akidah, N. M. Y. (2013). Mechanical and Thermal Properties of Hybrid Blends of LLDPE/Starch/PVA. Int. J. Chem. Sci. Eng, 7(8), 1102-1106.
[2] Tang. X., Alavi, S., “Recent advances in starch, polyvinyl alcohol based polymer blends, nanocomposites and their biodegradability” Carb Polym, vol. 85, no.1, pp. 7-16, 2011.
[3] Thakore, I. M., Desai, S., Sarawade, B. D., & Devi, S. (2001). Studies on biodegradability, morphology and thermomechanical properties of LDPE/modified starch blends. European Polymer Journal, 37, 151–160.
[4] Rahmah, M., Farhan, M., &Akidah, N. M. Y. (2013). Mechanical and Thermal Properties of Hybrid Blends of LLDPE/Starch/PVA. Int. J. Chem. Sci. Eng,7(8), 1102-1106.
[5] Copinet, A., Bertrand, C., Govindin, S., Coma, V., & Couturier, Y. (2004). Effects of ultraviolet light (315 nm), temperature and relative humidity on the degradation of polylactic acid plastic films. Chemosphere, 55(5), 763-773.
[6] Miltz, J., &Narkis, M. (1976). The effect of ultraviolet radiation on chemically crosslinked low‐density polyethylene. Journal of Applied Polymer Science, 20(6), 1627-1633.
[7] Mao, L., Imam, S., Gordon, S., Cinelli, P., &Chiellini, E. (2000). Extruded cornstarch-glycerol-polyvinyl alcohol blends: mechanical properties, morphology, and biodegradability. Journal of Polymers and the Environment, 8(4), 205-211.