Carbon Supported Cu and TiO2 Catalysts Applied for Ozone Decomposition
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Carbon Supported Cu and TiO2 Catalysts Applied for Ozone Decomposition

Authors: Katya Milenova, Penko Nikolov, Irina Stambolova, Plamen Nikolov, Vladimir Blaskov

Abstract:

In this article a comparison was made between Cu and TiO2 supported catalysts on activated carbon for ozone decomposition reaction. The activated carbon support in the case of TiO2/AC sample was prepared by physicochemical pyrolysis and for Cu/AC samples the supports are chemically modified carbons. The prepared catalysts were synthesized by impregnation method. The samples were annealed in two different regimes- in air and under vacuum. To examine adsorption efficiency of the samples BET method was used. All investigated catalysts supported on chemically modified carbons have higher specific surface area compared to the specific surface area of TiO2 supported catalysts, varying in the range 590÷620 m2/g. The method of synthesis of the precursors had influenced catalytic activity.

Keywords: Activated carbon, adsorption, copper, ozone decomposition, TiO2.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1099714

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[1] H. Destaillats, R. L. Maddalena, B. C. Singer, A. T. Hodgson, Thomas E. McKon, “Indoor pollutants emitted by office equipment: A review of reported data and information needs,” Atmos Environ, vol. 42 no.7, pp.1371-1664, 2008.
[2] B. Dhandapani, S. T. Oyama, Appl Catal B, ”Gas phase ozone decomposition catalysts,” vol.11, no. 2, pp. 129-166, 1997.
[3] Y. Lu, X. Zhao, M. Wang, Z. Yang, X. J. Zhang, C. Yang,” Feasibility analysis on photocatalytic removal of gaseous ozone in aircraft cabins”, Build Environ, vol.81, pp.42-50, 2014.
[4] J. Lin, A. Kawai, T. Nakajima, “Effective catalysts for decomposition of aqueous ozone,” Appl Catal B Environ, vol.39, pp.157–165, 2002.
[5] I. Somiya (Ed.), “Water Treatment Technology Using Ozone” (in Japanese), Pollution Countermeasure Comrade Group, Tokyo, pp. 1, 158, 1989.
[6] G. Gordon, “Feasibility analysis on photocatalytic removal of gaseous ozone in aircraft cabins,” Prog. Nucl. Energy, vol.29, pp.89, 1995.
[7] Budd AER, “Ozone control in high-flying jet aircraft: platinum catalyst ensures decomposition,” Platin Met Rev; vol. 24, no.3, pp.90-94, 1980.
[8] S.T. Oyama,” Chemical and Catalytic Properties of Ozone”, Catal. Rev. Sci. Eng, vol.42, pp.279- 322, 2000.
[9] B. Kasprzyk-Hordern, M. Ziólek, J. Nawrocki, “Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment,” Appl Catal B: Environ, vol. 46, no.4, pp.639-69, 2003.
[10] G. Asgaria, A. S. Mohammadia, S. B. Mortazavi, B. Ramavandi, “Investigation on the pyrolysis of cow bone as a catalyst for ozone aqueous decomposition: Kinetic approach,” J Anal Appl Pyrol, vol. 99, pp.149–154, 2013.
[11] M. Muruganandham, S.H. Chen, J.J. Wu, “Evaluation of water treatment sludge as a catalyst for aqueous ozone decomposition”, Catalysis Communications, vol. 8, pp.1609–1614, 2007.
[12] M. F. R. Pereira, A. G. Gonçalves, J. J.M. Órfão, “Carbon materials as catalysts for the ozonation of organic pollutants in water”, Marzo, vol.31, pp.18-24, 2014.
[13] C. Subrahmanyam, D. Bulushev, L. Kiwi-Minsker, “Dynamic behaviour of activated carbon catalysts during ozone decomposition at room temperature,” Appl Catal B Environ, vol. 61, pp.98–106, 2005.
[14] T. Charinpanitkul, P. Limsuwan, C. Chalotorn, N. Sano, T. Yamamoto, P. Tongpram, P. Wongsarivej, A. Soottitantawat, W. Tanthapanichakoon, “Synergetic removal of aqueous phenol by ozone and activated carbon within three-phase fluidized-bed reactor,” J Ind Eng Chem, vol.16, pp. 91–95, 2010.
[15] M. Wang, P. Zhang, J.Li, C. Jiang,” The effects of Mn loading on the structure and ozone decomposition activity of MnOx supported on activated carbon,” Chin J Catal, vol. 35, pp.335–341, 2014.
[16] Li, X., Huang, R., Zhang, Q., Yang, W., Li, L, “Catalytic Ozonation for the Degradation of P-Chlorobenzoic Acid in Aqueous Solution by Ni Supported Activated Carbon”, 2010, 4th International Conference on Bioinformatics and Biomedical Engineering, iCBBE, art. no. 5514898, pp.1-4.
[17] H. Zhuang, H. Han, B. Hou, S. Jia, Q. Zhao, “Heterogeneous catalytic ozonation of biologically pretreated Lurgi coal gasification wastewater using sewage sludge based activated carbon supported manganese and ferric oxides as catalysts,” Bioresource Technology, vol.166, pp.178– 186, 2014.
[18] S. Ye, M. Li, X. Song, S. Luo, Y. Fang, “Enhanced photocatalytic decomposition of gaseous ozone in cold storage environments using a TiO2/ACF film,” Chem Eng J, vol. 167, pp.28–34, 2011.
[19] F.A. Banat, B. Al-Bashir, S. Al-Asheh, O. Hayajneh,” Adsorption of phenol by bentonite,” Environ Pollut, vol.107, pp. 391-398, 2000.
[20] A. Klijanienko, E. Lorenc-Grabowska, G. Gryglewicz, “Development of meso-porosity during phosphoric acid activation of wood in steam atmosphere”, Bioresource Technology, vol.99, pp.7208–7214, 2008.
[21] Yan-Juan Zhang, Zhen-Jiao Xing, Zheng-Kang Duan, Meng Li, Yin Wang, “Effects of steam activation on the pore structure and surface chemistry of activated carbon derived from bamboo waste,” Appl Surf Sci, vol.315,pp. 279–286, 2014.
[22] F.C. Wu, R.L. Tseng, R.S. Juang, Preparation of highly microporous carbons from fir wood by KOH activation for adsorption of dyes and phenols from water, Separ Purif Tech, vol.47, pp.10–19, 2005.
[23] M.M.F. Sze, G. Mckay, “An adsorptive diffusion model for removal of parachlorophenol by activated carbon derived from bituminous coal”, Environ Pollut, vol.158, pp.1669–1674, 2010.
[24] H. Chen, Z. Hashisho, “Fast preparation of activated carbon from oil sand coke using microwave-assisted activation,” Fuel, vol. 95 pp.178– 276, 2012.
[25] F. Rodriguez-Reinoso, M. Molina-Sabio, “Activated carbons from lignocellulosic materials bychemical and/or physical activation: an overview,” Carbon, vol. 30, no.7, pp.1111–1118, 1992.
[26] A. A. Ceyhan, O. Sahin, C. Saka, “Surface and porous characterization of activated carbon prepared from pyrolysis of biomass by two-stage procedure at low activation temperature and it’s the adsorption of iodine,” J Anal Appl Pyrol, vol.104, pp.378–383, 2013.
[27] A. A. Ceyhan, O. Sahin, C. Saka, “A novel thermal process for activated carbon production from the vetch biomass with air at low temperature by two-stage procedure,” J Anal Appl Pyrol, vol.104, pp.170–175, 2013.
[28] C. Qin, Y. Chen, J. Gao,” Manufacture and characterization of activated carbon from marigold straw (Tageteserecta L) by H3PO4 chemical activation,” Mater Lett, vol.135,pp.123–126, 2014.
[29] J. Xua, L. Chena, H. Qua, Y. Jiaoa, J. Xiea, G. Xing, “Preparation and characterization of activated carbon from reedy grassleaves by chemical activation with H3PO4,” Appl Surf Sci, vol.320, pp. 674–680, 2014.
[30] K. Ennaciri, A. Baçaoui, M. Sergent, A. Yaacoubi,” Application of fractional factorial and Doehlert designs for optimizing the preparation of activated carbons from Argan shells,” Chemometr Intell Lab Syst, vol.139, pp. 48–57, 2014.
[31] L. Ljutzkanov, A. Atanasov, R. Ljutzkanova, D. Dushanov, Bulgarian Patent, Classification Index № 63594, (in Bulgarian), 2002.
[32] S. Brunauer, L. Deming, W. Deming, E. Teller,” On a Theory of the van der Waals Adsorption of Gases” ,J Amer Chem Soc, vol.62, no.7, pp. 1723–1732, 1940.
[33] S. Gregg, K. Sing, Adsorption, Surface Area and Porosity, London: Academic Press, 2 edition, February 11, 1982.
[34] B. Tryba, A. W. Morawski, M .A. Inagaki, “A new route for preparation of TiO2-mounted activated carbon,” Appl Catal B Environ, vol.46, no.1, 203-208, 2003.
[35] S. Timur, I.C. Kantarli, S. Onenc, J. Yanik, “Characterization and application ofactivated carbon produced from oak cups pulp,” J Anal Appl Pyrol., vol.89, pp.129–136, 2010.
[36] S. C. Kim, J. Y. Ryu,” Properties and performance of silver‐based catalysts on the catalytic oxidation of toluene,” Environ Tech, vol.32, no.5, pp. 561-568, 2011.
[37] J. Hoigné,” Inter-calibration of OH radical sources and water quality parameters,” Water Sci Tech, 35, no.4, pp.1-8, 1997.