The Improved Biofuel Cell for Electrical Power Generation from Wastewaters
Newly synthesized Polypropylene-g-Polyethylene glycol polymer was first time used for a compartment-less enzymatic fuel cell. Working electrodes based on Polypropylene-g-Polyethylene glycol were operated as unmediated and mediated system (with ferrocene and gold/cobalt oxide nanoparticles). Glucose oxidase and bilirubin oxidase was selected as anodic and cathodic enzyme, respectively. Glucose was used as fuel in a single-compartment and membrane-less cell. Maximum power density was obtained as 0.65 nW cm-2, 65 nW cm-2 and 23500 nW cm-2 from the unmediated, ferrocene and gold/cobalt oxide modified polymeric film, respectively. Power density was calculated to be ~16000 nW cm-2 for undiluted wastewater sample with gold/cobalt oxide nanoparticles including system.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1099642Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1978
 L. Brunel, J. Denele, K. Servat, K. B. Kokoh, C. Jolivalt, C. Innocent, M. Cretin, M. Rolland, S. Tingry, “Oxygen transport through laccase biocathodes for a membrane-less glucose/O2 biofuel cell,” Electrochem. Commun., vol. 9, pp. 331-336, February 2007.
 K. Kendall, “Fuel cell technology: A sweeter fuel,” Nature Mater., vol. 1, pp. 211-212, December 2002.
 R. F. Service, “Shrinking Fuel Cells Promise Power in Your Pocket,” Science, vol. 296, pp. 1222-1224, May 2002.
 N. Palomera, L. José, C. Vera, E. Meléndez, E. Jaime, Ramirez-Vick, M. S. Tomar, S. K. Arya, P. S. Surinder, “Redox active poly(pyrrole-Nferrocene- pyrrole) copolymer based mediator-less biosensors,” J Electroanal. Chem., vol. 658, pp. 33-37, July 2011.
 M. Ardhaoui, M. Zheng, J. Pulpytel, D. Dowling, C. Jolivalt, F. A. Khonsari, “Plasma functionalized carbon electrode for laccase-catalyzed oxygen reduction by direct electron transfer,” Bioelectrochemistry, vol. 91, pp. 52-61, June 2013.
 F. Barriere, Y. Ferry, D. Rochefort, D. Leech, “Targetting redox polymers as mediators for laccase oxygen reduction in a membrane-less biofuel cell,” Electrochem. Commun., vol. 6, pp. 237-241, March 2004.
 Ö. Kalaycı, F. Cömert, B. Hazer, T. Atalay, K. Cavicchi, M. Cakmak, “Synthesis, characterization, and antibacterial activity of metal nanoparticles embedded into amphiphilic comb-type graft copolymers,” Polym. Bull., vol. 65, pp. 215-226, July 2010.
 M. Balcı, A. Allı, B. Hazer, O. Güven, K. Cavicchi, M. Cakmak, “Synthesis and characterization of novel comb-type amphiphilic graft copolymers containing polypropylene and polyethylene glycol,” Polym. Bull., vol. 64, pp. 691-705, April 2010.
 Ö. Kalaycı, Ö. Duygulu, B. Hazer, “Optical characterization of CdS nanoparticles embedded into the comb-type amphiphilic graft copolymer,” Nanopart. Res., vol. 15, pp. 1355- 1366, December 2013.
 J. A. Cox, K. W. Kittredge, D. V. Ca, “Measurement platforms fabricated by layer-by-layer assembly of crown ether functionalized gold nanoclusters,” J. Solid State Electrochem., vol. 8, pp. 722-726, September 2004.
 J. A. Cox, K. M. Wiaderek, B. Layla Mehdi, B. P. Gudorf, D. Ranganathan, S. Zamponi, M. Berrettoni, “Influence of silanization on voltammetry at electrodes modified with silica films of controlled porosity formed by electrochemically initiated sol-gel processing,” J. Solid State Electrochem., vol. 15, pp. 2409-2417, December 2011.
 Q. Chen, L. Zhang, S. Ebrahim, M. Soliman, C. Zhang, Q. Qiao, “Synthesis and structure study of copolymers from thiadiazole fused indolocarbazole and dithienosilole,” Polymer, vol. 54, pp. 223-229, January 2013.
 T. Saito and M. Watanabe, “Characterization of poly(vinylferrocene-co- 2-hydroxyethyl methacrylate) for use as electron mediator in enzymatic glucose sensor,” Reactive and Functional Polymers, vol. 37, pp. 263- 269, June 1998.
 V. Flexer and N. Mano, “From dynamic measurements of photosynthesis in a living plant to sunlight transformation into electricity,” Anal. Chem., vol. 82, pp.1444-1449, January 2010.
 M. H. Osman, A. A. Shah, F. C. Walsh, “Recent progress and continuing challenges in bio-fuel cells. Part I: Enzymatic cells,” Biosens. Bioelectron., vol. 26, pp. 3087-3102, March 2011.
 E. Nazaruk, S. Smolinski, M. Swatko-Ossor, G. Ginalska, “Enzymatic biofuel cell based on electrodes modified with lipid liquid-crystalline cubic phases,” J Power Sources, vol. 183, pp. 533-538, September 2008.
 Y. Tan, Q. Xie, J. Huang, W. Duan, M. Ma, S. Yao, “Study on Glucose Biofuel Cells Using an Electrochemical Noise Device,” Electroanalysis, vol. 20, pp. 1599-1606, July 2008.
 L. Deng, L. Shang, Y. Wang, T. Wang, H. Chen, S. Dong, “Multilayer structured carbon nanotubes/poly-L-lysine/laccase composite cathode for glucose/O2 biofuel cell,” Electrochem. Commun., vol. 10, pp. 1012- 1015, July 2008.
 Y. Liu, S. Dong, “A biofuel cell with enhanced power output by grape juice,” Electrochem. Commun., vol. 9, pp. 1423-1427, July 2007.
 H. Liu and B. E. Logan, “Electricity generation using an air-cathode single chamber Microbial Fuel Cell in the presence and absence of a proton exchange membrane,” Environ. Sci. Technol., vol. 38, pp. 4040- 4046, June 2004.
 H. Yokoyama, H. Ohmori, M. Ishida, M. Waki, Y. Tanaka, “Treatment of cow-waste slurry by a microbial fuel cell and the properties of the treated slurry as a liquid manure,” Anim. Sci. J, vol. 77, pp. 634-638, December 2006.