Enhanced Thermal Properties of Rigid PVC Foams Using Fly Ash
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Enhanced Thermal Properties of Rigid PVC Foams Using Fly Ash

Authors: Nidal H. Abu-Zahra, Parisa Khoshnoud, Murtatha Jamel, Subhashini Gunashekar

Abstract:

PVC foam-fly ash composites (PVC-FA) are characterized for their structural, morphological, mechanical and thermal properties. The tensile strength of the composites increased modestly with higher fly ash loading, while there was a significant increase in the elastic modulus for the same composites. On the other hand, a decrease in elongation at UTS was observed upon increasing fly ash content due to increased rigidity of the composites. Similarly, the flexural modulus increased as the fly ash loading increased, where the composites containing 25 phr fly ash showed the highest flexural strength. Thermal properties of PVC-fly ash composites were determined by Thermo Gravimetric Analysis (TGA). The microstructural properties were studied by Scanning Electron Microscopy (SEM). SEM results confirm that fly ash particles were mechanically interlocked in PVC matrix with good interfacial interaction with the matrix. Particle agglomeration and debonding was observed in samples containing higher amounts of fly ash.

Keywords: PVC Foam, Polyvinyl Chloride, Rigid PVC, Fly Ash Composites.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1337789

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References:


[1] Sreekanth MS, Bambole VA. Effect of Particle Size and Concentration of Flyash on Properties of Polyester Thermoplastic Elastomer Composites. J Miner Mat CharacEng, 2009; 8(3): 237-48.
[2] Matsunaga T, Kim JK, Hardcastle S, Rohatgi PK, Crystallinity and selected properties of fly ash particles. J Mat SciEng, 2002: 333-43.
[3] White SC, Case ED. Characterization of fly ash from coal-fired power plants. J Mat Sci, 1990; 25: 5215-19.
[4] Das A, Satapathy BK, Structural, thermal, mechanical and dynamic mechanical properties of cenosphere filled polypropylene composites. J Mat Des, 2011; 32: 1477–84.
[5] Labella M, Zeltmann SE, Shunmugasamy VC, Gupta N, Rohatgi PK. Mechanical and thermal properties of fly ash/vinyl ester syntactic foams. J. Fuel, 2014; 121: 240–49.
[6] Senapati AK, Bhatta A, Mohanty S, Mishra PC, Routra BC, An Extensive Literature Review on the Usage of Fly Ash as a Reinforcing Agent for Different Matrices. Int J InnovSci Mod Eng, 2014; 2(3); 4-9.
[7] Qiao J, Amirkhizi AV, Schaaf K, Nemat-Nasser S. Dynamic Mechanical Analysis of Fly Ash Filled Polyurea Elastomer. J. Eng Mat Tech, 2011;133: 110161-7.
[8] Anandhan S, Sundar SM, Senthil T, Mahendran AR, Shibulal GS. Extruded poly(ethylene-co-octene)/fly ash composites-value added products from an environmental pollutant. J Polym Res, 2012; 9840-51.
[9] Deepthi MV, Sharma M, Sailaja RRN, Anantha P, Sampathkumaran P, Seetharamu S, Mechanical and thermal characteristics of high density polyethylene–fly ash Cenospheres composites. J Mat Des, 2010; 31:2051–60.
[10] Doddamani MR, Kulkarni SM. Dynamic response of fly ash reinforced functionally graded rubber composite sandwiches- a Taguchi approach. Int J EngSci Tech, 2011; 3(1):166-82.
[11] Nath DCD, Bandyopadhyay S, Yu A, Zeng Q, Das T, Blackburn D, White C. Structure–property interface correlation of fly ash–isotactic polypropylene composites. J Mater Sci, 2009; 44:6078–89.
[12] Nath DCD, Bandyopadhyay S, Yu A, Blackburn D, White C. Novel observations on kinetics of nonisothermal crystallization in fly ash filled isotactic-polypropylene composites. J Appl Poly Sci. 2010;115:1510–17.
[13] Nath DCD, Bandyopadhyay S, Yu A, Blackburn D, White C, Varughese S. Isothermal crystallization kinetics of fly ash filled iso-polypropylene composite-and a new physical approach. J Therm Anal Calorim. 2010; 99:423–29.
[14] Nath DCD, Bandyopadhyay S, Boughton P, Yu A, Blackburn D, White C. High‐strength biodegradable poly(vinyl alcohol)/fly ash composite films. J ApplPolymSci, 2010117:114–21.
[15] Nath DCD, Bandyopadhyay S, Yu A, Blackburn D, White C. High strength bio-composite films of poly(vinyl alcohol) reinforced with chemically modified-fly ash. J Mater Sci, 2010;45:1354–60.
[16] Vijaykumar HK, Prashanth M, Saheb S, Nayak V. Experimental Investigation of the Tensile strength and Compressive strength of Fly Ash Core Sandwiched Composite Material. J Int org Sci Res, 2014; 4(6): 1-10.
[17] Guhanathan S, Sarojadevi M. Studies on interface in polyester/fly-ash particulate composites. J Comp Interface, 2004; 11:43–66
[18] Bishoyee N, Dash A, Mishra A, Patra S, Mahapatra SS. A Grey-Based Taguchi Approach for Characterization of Erosive Wear Phenomenon of Glass–Polyester Fly Ash Filled Composites. J Polym Environ, 2010; 18:177–87
[19] N. Usta. Investigation of Fire Behavior of Rigid Polyurethane Foams Containing Fly Ash and Intumescent Flame Retardant by Using a Cone Calorimeter. J ApplPolymSci, 2012; 124, 3372–82.
[20] Chow JD, Chai WL, Yeh CM, Chuang FS. Recycling and Application Characteristics of Fly Ash from Municipal Solid Waste Incinerator Blended with Polyurethane Foam. J Environ EngSci, 2008; 25(4): 461- 71.
[21] Guptaa N, Woldesenbetb E, Mensah P. Compression properties of syntactic foams: effect of cenosphere radius ratio and specimen aspect ratio. J Composites: Part A, 2004;35: 103–11.
[22] Rabinovich EB, Isner JD, SIDOR JA, Wiedl D J. Effect of Extrusion Conditions on Rigid PVC Foam. J Vin Add Tech, 1997; 3(3): 210-15.
[23] Thomas NL. Rigid PVC Foam, Formulating for sustainability, Blowing agent and foaming process. 2004.
[24] Eaves D. Handbook of Polymer Foams. 2004.
[25] Thomas NL. Blowing agent and foaming process. 2004.
[26] Gupta N, Woldesenbet E. Characterization of Flexural Properties of Syntactic Foam Core Sandwich Composites and Effect of Density Variation. J Comp Mat, 2005; 39 (24):2197-212.
[27] Purushothama HL, Hyatt J. Co-firing high-sulfur with refuse-derived fuel. J ThermochimicaActa. 1996; 284: 161-177.
[28] Lodi PC, Souza BBD. Thermo-gravimetric Analysis (TGA) after Different Exposures of High Density Polyethylene (HDPE) and Poly Vinyl Chloride (PVC) Geomembranes. Elec J GeotechEng, 2012;17:3339-49.