The Use of FBC Ash for Preparation of Types of Hydraulic Binders Similar to Portland Cement
Authors: Karel Dvořák, Karel Kulísek, Radek Magrla
Abstract:
The reduction of greenhouse gases emissions is highly discussed ecological theme at present. In addition to power industry also main production sectors of binders, i.e. cement, air and hydraulic lime are very sensitive to these questions. One of the possibilities how CO2 emissions can be reduced directly at clinker burnout is represented by partial substitution of lime with a material containing limy ions at absence of carbonate group. Fluidised fly ash is one of such potential raw materials where CaO can be found free and also bound in anhydrite, CaSO4. At application of FBC (fluidized bed combustion) fly ash with approximate 20% CaO content and its dosing ratio to high percent lime 1:2, corresponding stechiometrically to the preparation of raw material powder, approximately 0,37 t CO2 per 1 ton of one-component cement would be released at clinker burnout compared to 0,46 t CO2 when orthodox raw materials are used. The reduction of CO2 emissions thus could reach even 20%.
Keywords: FBC ash, cement, hydraulic binders.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1096650
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[1] García-Díaz, J.G. Palomo, F. Puertas,:Belite cements obtained from ceramic wastes and the mineral pair. CaF2/CaSO4, Cem. Concr. Comp. 33-10 (2011).
[2] Singh M, Upadhayay SN, Prasad PM,: Preparation of special cements from red mud. Waste Manag ;16:665–70. (1996)
[3] Ozturk, A.; Suyadal, Y.; Oguz, H.,: The formation of belite phase by using phosphogypsum and oil shale, Cement and Concrete Research, 30 967-971 (2000)
[4] Raupp-Pereira F., James Ball R., Rocha J., Labrincha J.A., Allen G.: "New based clinkers: belite and lime formulations" Cement and Concrete Research. 38, 511 (2008).
[5] Singh M, Upadhayay SN, Prasad PM.: Preparation of special cements from red mud. Waste Manag;16:665–70.(1996)
[6] Zapata A, Bosch P. A combustion method to synthesize a belite cement clinker. J Am Ceram Soc ;93:987–92. (2010)
[7] Meyer, C., Baxter, S.: Use of recycled glass and fly ash for precast concrete, Final Report to New York State Energy Research and Development Authority, Rep. 98–18, Albany, NY, Oct. 1998
[8] Poon, C.S., Kou, S.C., Lam, L., Lin, Z.S., Activation of Fly Ash/Cement Systems Using Calcium Sulfate Anhydrite (CaSO4), Cement and Concret Research
[9] GAZDIČ, D.; Slag-Sulphate Binder Preparation. Advanced Materials Research. 2013. 2013(818). p. 68 - 71. ISSN 1022-6680
[10] Keppert, M., Reiterman, P., Pavlík, Z., Pavlíková, M., Jerman, M. Černý, R.: Municipal solid waste incineration ashes and their potential for partial replacement of Portland cement and fine aggregates in concrete. Cement WapnoBeton. 2010, vol. 15/77, no. 4, p. 187-193. ISSN 1425-8129.