Simulation of Polymeric Precursors Production from Wine Industrial Organic Wastes
The production of Dimethyl acetal, Isovaleradehyde and Pyridine were simulated using Aspen Plus simulation. Upgrading cleaning water from wine industrial production is the main objective of the project. The winery waste composes of Acetaldehyde, Methanol, Ethyl Acetate, 1-propanol, water, iso-amyl alcohol and iso-butyl alcohol. The project is separated into three parts; separation, reaction, and purification. Various processes were considered to maximize the profit along with obtaining high purity and recovery of each component with optimum heat duty. The results show a significant value of the product with purity more than 75% and recovery over 98%.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1089235Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2061
 Perez, V. H.; Miranda, E. A.; Valença, G. P., Kinetics of gas-phase hydrolysis of ethyl acetate catalyzed by immobilized lipase. Applied biochemistry and biotechnology 2007, 136 (1), 23-37.
 Ayyappan, K.; Toor, A. P.; Gupta, R.; Bansal, A.; Wanchoo, K., Catalytic Hydrolysis of Ethyl Acetate using Cation Exchange Resin (Amberlyst-15): A Kinetic Study. Bulletin of Chemical Reaction Engineering & Catalysis 2010, 4 (1), 16-22.
 Tesser, R.; Maradei, V.; Di Serio, M.; Santacesaria, E., Kinetics of the oxidative dehydrogenation of ethanol to acetaldehyde on V2O5/TiO2-SiO2 catalysts prepared by grafting. Industrial & engineering chemistry research 2004, 43 (7), 1623-1633.
 Chimentao, R. J.; Herrera, J. E.; Kwak, J. H.; Medina, F.; Wang, Y.; Peden, C. H., Oxidation of ethanol to acetaldehyde over Na-promoted vanadium oxide catalysts. Applied Catalysis A: General 2007, 332 (2), 263-272.
 Gandi, G. K.; Silva, V. M.; Rodrigues, A. E., Acetaldehyde dimethylacetal synthesis with Smopex 101 fibres as catalyst/adsorbent. Chemical engineering science 2007, 62 (4), 907-918.
 Gandi, G. K.; Silva, V. M.; Rodrigues, A. E., Process development for dimethylacetal synthesis: Thermodynamics and reaction kinetics. Industrial & engineering chemistry research 2005, 44 (19), 7287-7297.
 Suresh Kumar Reddy, K.; Sreedhar, I.; Vijaya Raghavan, K., Kinetic studies on vapour phase pyridine synthesis and catalyst regeneration studies. The Canadian Journal of Chemical Engineering 2011, 89 (4), 854-863.
 Shiau, C.-Y.; Chen, S.; Tsai, J.; Lin, S., Effect of zinc addition on copper catalyst in isoamyl alcohol dehydrogenation. Applied Catalysis A: General 2000, 198 (1), 95-102.
 Blanch, G. P.; Reglero, G.; Herraiz, M., Rapid extraction of wine aroma compounds using a new simultaneous distillation-solvent extraction device. Food chemistry 1996, 56 (4), 439-444.
 López, E. F.; Gómez, E. F., Comparison of solvents for determination of monoterpenes in wine using liquid-liquid extraction. Chromatographia 2000, 52 (11-12), 798-802.
 Seader, J., Separation process principles. Wiley. com: 2006.
 Wennekes, W. B., Adhesion of RFL-treated cords to rubber: new insights into interfacial phenomena. University of Twente: 2008.
 Berg, L.; Yang, Z., Separation of pyridine from water by extractive distillation. Google Patents: 1992.