A Review of Methanol Production from Methane Oxidation via Non-Thermal Plasma Reactor
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33090
A Review of Methanol Production from Methane Oxidation via Non-Thermal Plasma Reactor

Authors: M. Khoshtinat, N. A. S. Amin, I. Noshadi

Abstract:

Direct conversion of methane to methanol by partial oxidation in a thermal reactor has a poor yield of about 2% which is less than the expected economical yield of about 10%. Conventional thermal catalytic reactors have been proposed to be superseded by plasma reactors as a promising approach, due to strength of the electrical energy which can break C-H bonds of methane. Among the plasma techniques, non-thermal dielectric barrier discharge (DBD) plasma chemical process is one of the most future promising technologies in synthesizing methanol. The purpose of this paper is presenting a brief review of CH4 oxidation with O2 in DBD plasma reactors based on the recent investigations. For this reason, the effect of various parameters of reactor configuration, feed ratio, applied voltage, residence time (gas flow rate), type of applied catalyst, pressure and reactor wall temperature on methane conversion and methanol selectivity are discussed.

Keywords: Dielectric barrier discharge, methane, methanol, partial oxidation, Plasma.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1329214

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2930

References:


[1] G.A. Olah, A. Goeppert, and A. Prakash, Beyond Oil and Gas: The Methanol Economy,1st Ed. Wiley-VCH, 2006.
[2] P. S. Casey, T. MacAllister, and K. Foger, "Selective oxidation of methane to methanol at high pressures," Ind. Eng. Chem. Res, vol. 33, pp. 1120-1125, 1994.
[3] S. L. Yao, T. Takemoto, F. Ouyang, A. Nakayama, E. Suzuki, A. Mizuno, and M. Okumoto, "Selective oxidation of methane using a nonthermal pulsed plasma," Energ. Fuel, vol. 14, pp. 459-463, 2000.
[4] C. G. Liu, R. Mallinson, L.Lobban, and S. Rusek. "Nonoxidative methane conversion to acetylene over zeolite in a low temperature plasma," J. Catal, vol. 179, pp. 326-334, 1998.
[5] V. Goujard, J. M. Tatibouet, and C. Batiot-Dupeyrat, "Use of nonthermal plasma for the production of synthesis gas from biogas," Appl. Catal. A: Gen, vol. 353, pp. 228-235, 2009.
[6] L.M. Zhou, B. Xue, U. Kogelschatz, and B. Elliason, "Partial oxidation of methane to methanol with oxygen or air in a nonequilibrium discharge plasma," Plasma Chem. Plasma Process, vol. 18, no. 3, pp. 375-393,1998.
[7] L. Chen, X. W. Zhang, L. Huang, and L. C. Lei, "Partial oxidation of methane with air for methanol production in a post-plasma catalytic system," Chem. Eng. Process, vol. 48, pp.1333-1340, 2009.
[8] D. Larkin, L. Zhou, L. Lobban, and R. G. Mallinson, "Product selectivity control and organic oxygenate pathways from partial oxidation of methane in a silent electric discharge reactor," Ind. Eng. Chem. Res, vol. 40, pp. 5496-5506, 2001.
[9] D. Larkin, L. L. Lobban, and R. G. Mallinson, "The direct partial oxidation of methane to organic oxygenates using a dielectric barrier discharge reactor as a catalytic reactor analog," Catal. Today, vol. 71, pp. 199-210, 2001.
[10] F.M.Aghamir, N. S. Matin, H. A. Jalili, M. H. Esfarayeni, M. A. Khodagholi, and R. Ahmadi, "Conversion of methane to methanol in an ac dielectric barier discharge," Plasma Sources Sci. Thecnol, vol. 13, pp. 707-711, 2004.
[11] Y-P. Zhang, Y. Li, Y. Wang, C-J. Liu, and B. Eliasson, "Plasma methane conversion in the presence of carbon dioxide using dielectricbarrier discharges," Fuel Process. Technol, vol. 83, 101-109, 2003.
[12] A. Indarto, D. R. Yang, J. palgunadi, J-W. Choi, H. Lee, and H. K. Song, "Partial oxidation of methane with Cu-Zn-Al catalyst in a dielectric barrier discharge," Chem. Eng. Process, vol. 47, pp. 780-786, 2008.
[13] A. Indarto, C. Jai-Wook, L. Hwaung, and S.H. Keun, "The kinetic studies of direct methane oxidation to methanol in the plasma process," Chin. Sci. Bull, vol. 53, no. 18, pp. 2783-2792, 2008.
[14] M. Okumoto, K. Tsunoda, S. Katsura, and J. Mizuno, "Direct methanol synthesis using non-thermal pulsed plasma generated by a solid state pulse generator," J. Electrostat, vol. 42, pp. 167-175, 1997.
[15] K. Okazaki, S. Hirari, T. Nozaki, K. Ogawa, and K. Hijikata, "Plasma chemical reactions at atmospheric pressure at high efficiency use of hydrocarbon fuels," Energy, vol. 22, 369-374, 1997.
[16] R.Bhatnagar, and R. G, Mallinson, "Methane and Alkane Conversion Chemistry," Plenum Press, 1995.
[17] H. K. Song, H. Lee, J. W. Choi, and B. K. Na, "Effect of electrical pulse forms on the CO2 reforming of CH4 using atmospheric barrier discharge," Plasma Chem. Plasma Process, vol. 24, 57-72, 2004.
[18] A. Indarto, J. W. Choi, H. Lee, and H. K. Song, "Methane conversion using dielectric barrier discharge: comparison with thermal process and catalytic effects," J. Nat. Gas Chem, vol. 15, pp. 87-92, 2006.
[19] Istadi, N. A. S. Amin, "Co-generation of synthesis gas and C2+ hydrocarbons from methane and carbon dioxide in a hybrid catalyticplasma reactor: A review," Fuel, vol. 85, pp. 577-592, 2006.