Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33122
Modification of Anodized Mg Alloy Surface By Pulse Condition for Biodegradable Material
Authors: Y.K. Kim, Y.S. Jang, H.H. Park, J.H. Ji, I.S. Park, T.S. Bae, M.H. Lee
Abstract:
Magnesium is used implant material potentially for non-toxicity to the human body. Due to the excellent bio-compatibility, Mg alloys is applied to implants avoiding removal second surgery. However, it is found commercial magnesium alloys including aluminum has low corrosion resistance, resulting subcutaneous gas bubbles and consequently the approach as permanent bio-materials. Generally, Aluminum is known to pollution substance, and it raises toxicity to nervous system. Therefore especially Mg-35Zn-3Ca alloy is prepared for new biodegradable materials in this study. And the pulsed power is used in constant-current mode of DC power kinds of anodization. Based on the aforementioned study, it examines corrosion resistance and biocompatibility by effect of current and frequency variation. The surface properties and thickness were compared using scanning electronic microscopy. Corrosion resistance was assessed via potentiodynamic polarization and the effect of oxide layer on the body was assessed cell viability. Anodized Mg-35Zn-3Ca alloy has good biocompatibility in vitro by current and frequency variation.Keywords: Biodegradable material, Mg, anodization, osteoblast cell, pulse power.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1333616
Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2169References:
[1] J. E. Gray and B. Luan, "Protective coatings on magnesium and its alloys ÔÇö a critical review," Journal of Alloys and Compounds vol. 336, pp. 88-113, 2002.
[2] H. Kuwahara, N. Mazaki, M. Mabuchi, C. Wein, and T. Aizawa, "Behavior of magnesium in Hank's solution aimed to trabecular pattern of natural bone," Materials Science Forum vol. 419-422, pp. 1007-1012 2003.
[3] H. Kuwahara, Y. Al-Abdullat, N. Mazaki, S. Tsutsumi, and T. Aizawa, "Precipitation of Magnesium Apatite on Pure Magnesium Surface during Immersing in Hanks solution," Materias transactions vol. 42, pp. 1317-1321 2001.
[4] H. Li, Y. He, and Z. D. Zeng, "A neural network model for prediction on mechanical properties of QA110-5-5 aluminum bronze after aging," Jinshu Rechuli/Heat Treatment of Metals, vol. 31, pp. 28-30, 2006.
[5] V. T. Truong, P. K. Lai, B. T. Moore, R. F. Muscat, and M. S. Russo, "Corrosion protection of magnesium by electroactive polypyrrole/paint coatings," Synthetic Metals, vol. 110, pp. 7-15, 2000.
[6] A. A. Voevodin, A. L. Yerokhin, V. V. Lyubimov, M. S. Donley, and J. S. Zabinski, "Characterization of wear protective Al-Si-O coatings formed on Al-based alloys by micro-arc discharge treatment " Surface and Coatings Technology vol. 86-87, pp. 516-521 1996.
[7] W. B. Xue, Z. W. Deng, R. Y. Cheng, and T. H. Zhang, "Growth regularity of ceramic coatings formed by microarc oxidation on Al-Cu-Mg alloy " Thin Solid Films, vol. 372, p. 114, 2000.
[8] V. S. Rudnev, T. P. Yarovaya, D. L. Boguta, L. M. Tyrina, P. M. Nedozorov, and P. S. Gordienko, "Anodic spark deposition of P, Me(II) or Me(III) containing coatings on aluminium and titanium alloys in electrolytes with polyphosphate complexes " Journal of Electroanalytical Chemistry vol. 497, pp. 150-158 2001.
[9] A. L. Yerokhin, A. Leyland, and A. Matthews, "Kinetic aspects of aluminium titanate layer formation on titanium alloys by plasma electrolytic oxidation " Applied Surface Science vol. 200, pp. 172-184, 2002.
[10] H. Duan, K. Du, C. Yan, and F. Wang, "Electrochemical corrosion behavior of composite coatings of sealed MAO film on magnesium alloy AZ91D," Electrochimica Acta, vol. 51, pp. 2898-2908, 2006.
[11] (1999). Biological evaluation of medical devices. Part 5. Tests for cytotoxicity: in vitro methods Arlington, VA: ANSI/AAMI ISO 10993-5.
[12] Y. S. Jang, Y. K. Kim, I. S. Park, S. J. Lee, M. H. Lee, J. M. Yoon, and T. S. Bae, "Film characteristics of anodic oxidized AZ91D magnesium alloy by applied power," Surface interface analysis, vol. 41, pp. 524-530, 2009.
[13] I. S. Park, Y. S. Jang, Y. K. Kim, M. H. Lee, J. Yoon, and T. S. Bae, "Surface characteristics of AZ91D alloy anodized with various conditions," surface and interface analysis, vol. 40, pp. 1270-1277, 2008.
[14] I. Ostrovsky, "Method of anodizing of magnesium and producing conductive layers on anodized surface," United states Patent, 2003.
[15] N. Kurihara, S. Ishizuka, M. Kiyoki, Y. Haketa , K. Ileda, and M. Kumegawa "Effects of 1,25-dihydroxyvitamin D3 on osteoblastic MC3T3-E1 cells," Endocrinology, vol. 118, pp. 940-947, 1986.
[16] S. El-Rahman, "Neuropathology of aluminum toxicity in rats (glutamate and GABA impairment)," Pharmacological Research, vol. 47, pp. 189-194, 2003.
[17] N. Yumiko, T. Yukari, T. Yasuhide, S. Tadashi, and I. Yoshio, "Differences in behavior among the chlorides of seven rare earth elements administered intravenously to rats," Fundam Appl Toxicol, vol. 37, pp. 106-116, 1997.