Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33104
Carrageenan Properties Extracted From Eucheuma cottonii, Indonesia
Authors: Sperisa Distantina, Wiratni , Moh. Fahrurrozi, Rochmadi
Abstract:
The effect of extraction solvent upon properties of carrageenan from Eucheuma cottonii was studied. The distilled water and KOH solution (concentration 0.1- 0.5N) were used as the solvent. Extraction process was carried out in water bath equipped by stirrer with constant speed of 275 rpm with a constant ratio of seaweed weight to solvent volume ( 1:50 g/mL) at 86oC for 45 minutes. The extract was then precipitated in 3 volume of 90% ethanol, oven dried at 60oC. Based on experimental data, alkali significantly influenced yield and properties of extracted carrageenan. The extracted carrageenan was found to have essentially identical FTIR spectra to the reference samples of kappa-carrageenan. Increasing the KOH concentration led to carrageenan containing less sulfate content and intrinsic viscosity. The gel strength increased along with the increasing of KOH concentration. The decreasing of intrinsic viscosity value indicates that a polymer degradation occurs during alkali extraction.Keywords: gel strength, sulfate, intrinsic viscosity, Eucheumacottonii
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1333328
Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 6057References:
[1] Campo, V.L., Kawano,D.F., Silva J├║nior, D.B., Ivone Carvalho, I., 2009, "Carrageenans: Biological Properties, Chemical Modifications and Structural Analysis", Carbohydrate Polymers, 77, 167-180.
[2] Ciancia, M., Noseda, M.D., Matulewicz, M.C., and Cerezo, A.S., 1993, "Alkali-modification of carrageenans: Mechanism and Kinetics in the kappa/iota-, mu/nu- and lambda-series", Carbohydrate Polymers 20, 95-98.
[3] Ciancia, M.,. Matulewicz, M.C. and. Cerezo, A.S., 1997, "Alkaline modification of carrageenans. Part III. Use of mild alkaline media and high ionic strengths", Carbohydrate Polymers, 32, 293-295
[4] Falshaw, R., Bixler, H.J., and Johndro, K., 2001, "Structure and Performance of Commercial kappa-2 Carrageenan Extracts", Food Hydrocolloids, 15, pp. 441-451.
[5] Falshaw, R., Furneaux, R.H., and Stevenson, D.E., 1998, "Agars from Nine Species of Red Seaweed in the Genus Curdie (glacilariaceae, rhodophyta)", Carbohydrate Reasearch, 308, 107-115.
[6] Freile-Pelegrín Y., and Daniel Robledo, D., 2007, Carrageenan of Eucheuma isiforme (Solieriaceae, Rhodophyta) from Nicaragua, J Appl Phycol.
[7] Gupta R.K., 2000, "Polymer and Composite Rheology", Marcel Dekker Inc., Switzerland
[8] Higiro, J., Herald, T.J., Alavi, S., and Bean, S., "Rheological study of xanthan and locust bean gum interaction in dilute solution: Effect of salt", Food Research International, 40 (2007) 435-447.
[9] Hilliou,L., Larotonda, F.D.S., Abreu, P., Ramos, A.M., Sereno, A.M., Gonc┬©alves, M.P., 2006, "Effect of extraction parameters on the chemical structure and gel properties of k/i-hybrid carrageenans obtained from Mastocarpus stellatus", Biomolecular Engineering, 23, 201-208.
[10] Hoffmann,R.A., Gidley, M.J., David Cooke, D., and Frith, W.J., "Effect of Isolation Procedurs on the molecular composition and Physical Properties of Eucheuma cottonii Carrageenan", Food Hydrocolloids, Vol. 9 no. 4 pp.281-289, 1995.
[11] JECFA, 2001, Processed Eucheuma cottonii, www.marinalg.org, acessed on 23 June 2010.
[12] Kumar,V., and Fotedar, R., 2009, "Agar extraction process for Gracilaria cliftonii", Carbohydrate Polymers, 78, 813-819.
[13] Lai, L.S., Tung, J, and Lin, P.S., 2000, "Solution properties of hsiantsao (Mesona procumbens Hemsl) leaf gum", Food Hydrocolloids, 14 , 287-294.
[14] Montolalu, R.I., Tashiro, Y., Matsukawa, S., and Ogawa, H., 2007, "Effect of Extraction Parameters on Gel Properties of Carrageenan from Kappaphycus alvarezii (Rhodophyta)", J. Of App. Phycology, 20, 521- 526
[15] Nickerson, M.T., Paulson, A.T., Hallett, F.R., 2004, "Dilute solution properties of k-carrageenan polysaccharides: effect of potassium and calcium ions on chain conformation", Carbohydrate Polymers, 58, 25- 33.
[16] Van de Velde,.F.,Knutsen, S.H., Usov, A.I., Romella, H.S., and Cerezo, A.S., 2002, "1H and 13 C High Resolution NMR Spectoscopy of Carrageenans: Aplication in Research and Industry", Trend in Food Science and Technology, 13, 73-92.
[17] Viana, A.G., Noseda, M.D,. Duarte, M.E.R., and Cerezo, A.S, 2004, "Alkali modification of carrageenans. Part V. The iota-nu hybrid carrageenan from Eucheuma denticulatum and its cyclization to iotacarrageenan", Carbohydrate Polymers, 58, 455-460.
[18] Walstra, P., 2003, Physical Chemistry of Foods, Marcel Dekker, p.99.