Green Building Materials: Hemp Oil Based Biocomposites
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32807
Green Building Materials: Hemp Oil Based Biocomposites

Authors: Nathan W. Manthey, Francisco Cardona, Gaston M. Francucci, Thiru Aravinthan

Abstract:

Novel acrylated epoxidized hemp oil (AEHO) based bioresins were successfully synthesised, characterized and applied to biocomposites reinforced with woven jute fibre. Characterisation of the synthesised AEHO consisted of acid number titrations and FTIR spectroscopy to assess the success of the acrylation reaction. Three different matrices were produced (vinylester (VE), 50/50 blend of AEHO/VE and 100% AEHO) and reinforced with jute fibre to form three different types of biocomposite samples. Mechanical properties in the form of flexural and interlaminar shear strength (ILSS) were investigated and compared for the different samples. Results from the mechanical tests showed that AEHO and 50/50 based neat bioresins displayed lower flexural properties compared with the VE samples. However when applied to biocomposites and compared with VE based samples, AEHO biocomposites demonstrated comparable flexural performance and improved ILSS. These results are attributed to improved fibre-matrix interfacial adhesion due to surface-chemical compatibility between the natural fibres and bioresin.

Keywords: Biocomposite, hemp oil based bioresin, green building materials, mechanical properties.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1328854

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 3408

References:


[1] D. Ray, et al., "Impact fatigue behaviour of vinylester resin matrix composites reinforced with alkali treated jute fibres," Composites Part A: Applied Science and Manufacturing, vol. 33, pp. 233-241, 2002
[2] C. Datta, et al., "Mechanical and dynamic mechanical properties of jute fibers-Novolac-epoxy composite laminates," Journal of Applied Polymer Science, vol. 85, pp. 2800-2807, 2002.
[3] S. S. Tripathy, et al., "Mechanical properties of jute fibers and interface strength with an epoxy resin," Journal of Applied Polymer Science, vol. 75, pp. 1585-1596, 2000.
[4] A. Singha and V. Thakur, "Mechanical properties of natural fibre reinforced polymer composites," Bulletin of Materials Science, vol. 31, pp. 791-799, 2008.
[5] J. Gassan and A. K. Bledzki, "Possibilities for improving the mechanical properties of jute/epoxy composites by alkali treatment of fibres," Composites Science and Technology, vol. 59, pp. 1303-1309, 1999.
[6] N. G. J├║stiz-Smith, et al., "Potential of Jamaican banana, coconut coir and bagasse fibres as composite materials," Materials Characterization, vol. 59, pp. 1273-1278, 2008.
[7] A. K. Mohanty and M. Misra, "Studies on Jute CompositesÔÇöA Literature Review," Polymer-Plastics Technology and Engineering, vol. 34, pp. 729-792, 1995/09/01 1995.
[8] H. K. Mishra, et al., "A study on mechanical performance of jute-epoxy composites," Polymer-Plastics Technology and Engineering, vol. 39, pp. 187-198, 2000/02/16 2000.
[9] T. Cooney, "Epoxidised resins from natural renewable resources," USQ Honours research project, 2009.
[10] N. Manthey, "Environmentally friendly natural fibre composites with Qld. based vegetable oils" USQ Honours research project, 2009.
[11] N. W. Manthey, et al., "Mechanical properties of epoxidized hemp oil based biocomposites: Preliminary results " in The First International Postgraduate Conference on Engineering, Designing and Developing the Built Environment for Sustainable Wellbeing, Brisbane, Queensland, 2011, pp. 100-105.
[12] N. W. Manthey, et al., "Cure kinetic study of epoxidized hemp oil cured with a multiple catalytic system," Journal of Applied Polymer Science, vol. 125, pp. E511-E517, 2012.
[13] N. W. Manthey, et al., "Cure kinetics of an epoxidized hemp oil based bioresin system," Journal of Applied Polymer Science, vol. 122, pp. 444-451, 2011.
[14] N. W. Manthey, et al., "Natural fibre composites with QLD based fibres and vegetable oils," presented at the 21st Australasian Conference on the Mechanics of Structures and Materials: Incorporating Sustainable Practice in Mechanics of Structures and Materials (ACMSM21), Melbourne, Australia, 2010.
[15] K. Adekunle, et al., "Biobased composites prepared by compression molding with a novel thermoset resin from soybean oil and a naturalfiber reinforcement," Journal of Applied Polymer Science, vol. 116, pp. 1759-1765, 2010.
[16] G. Mehta, et al., "Biobased resin as a toughening agent for biocomposites," Green Chemistry, vol. 6, pp. 254-258, 2004.
[17] J. Espinoza-Pérez, et al., "Canola-based epoxy resins applied to plastic composites," in 2007 ASABE/CSBE North Central Intersectional Conference, Fargo, North Dakota, USA, 2007.
[18] S. N. Khot, et al., "Development and application of triglyceride-based polymers and composites," Journal of Applied Polymer Science, vol. 82, pp. 703-723, 2001.
[19] G. Van Erp and D. Rogers, "Development of sunflower oil resins for fibre composite applications," in 14th Australian Sunflower Association Conference, Gold Coast, Queensland, 2003.
[20] J. La Scala and R. Wool, "Effect of FA composition on epoxidation kinetics of TAG," Journal of the American Oil Chemists' Society, vol. 79, pp. 373-378, 2002.
[21] J. Scala and R. Wool, "The effect of fatty acid composition on the acrylation kinetics of epoxidized triacylglycerols," Journal of the American Oil Chemists' Society, vol. 79, pp. 59-63, 2002.
[22] J. Wisniak, et al., "Epoxidation of Anchovy Oils. A Study of Variables," I&EC Product Research and Development, vol. 3, pp. 306-311, 1964.
[23] R. Mungroo, et al., "Epoxidation of Canola Oil with Hydrogen Peroxide Catalyzed by Acidic Ion Exchange Resin," Journal of the American Oil Chemists' Society, vol. 85, pp. 887-896, 2008.
[24] S. Dinda, et al., "Epoxidation of cottonseed oil by aqueous hydrogen peroxide catalysed by liquid inorganic acids," Bioresource Technology, vol. 99, pp. 3737-3744, 2008.
[25] V. V. Goud, et al., "Epoxidation of Jatropha (Jatropha curcas) oil by peroxyacids," Asia-Pacific Journal of Chemical Engineering, vol. 5, pp. 346-354, 2010.
[26] V. Goud, et al., "Epoxidation of karanja (Pongamia glabra) oil by H2O2," Journal of the American Oil Chemists' Society, vol. 83, pp. 635- 640, 2006.
[27] V. Goud, et al., "Epoxidation of karanja (Pongamia glabra) oil catalysed by acidic ion exchange resin," European Journal of Lipid Science and Technology, vol. 109, pp. 575-584, 2007.
[28] P. Meyer, et al., "Epoxidation of soybean oil and jatropha oil," Thammasat International Journal of Science and Technology, vol. 13, 2008.
[29] Z. S. Petrovic, et al., "Epoxidation of soybean oil in toluene with peroxoacetic and peroxoformic acids - kinetics and side reactions," European Journal of Lipid Science and Technology, vol. 104, pp. 293- 299, 2002.
[30] M. T. Benaniba, et al., "Epoxidation of sunflower oil with peroxoacetic acid in presence of ion exchange resin by various processes," Energy Education Science and Technology, vol. 21, pp. 71-82, 2008.
[31] J. Espinoza-Pérez, et al., "Epoxy resins from high-oleic oils applied to composites," in 2009 ASABE Annual International Meeting, Reno, Nevada, 2009.
[32] A. O'Donnell, et al., "Natural fiber composites with plant oil-based resin," Composites Science and Technology, vol. 64, pp. 1135-1145, 2004.
[33] J. Lu, et al., "New sheet molding compound resins from soybean oil. I. Synthesis and characterization," Polymer, vol. 46, pp. 71-80, 2005.
[34] Y. Li, et al., "Synthesis and characterization of cast resin based on different saturation epoxidized soybean oil," European Journal of Lipid Science and Technology, vol. 112, pp. 511-516, 2010.
[35] L. Fu, et al., "Thermal and mechanical properties of acrylated expoxidized-soybean oil-based thermosets," Journal of Applied Polymer Science, vol. 117, pp. 2220-2225, 2010.
[36] J. Espinoza-Pérez, et al., "Production and characterization of epoxidized canola oil," ASABE vol. 52, pp. 1289-1297, 2009.
[37] V. Goud, et al., "Kinetics of in situ Epoxidation of Natural Unsaturated Triglycerides Catalyzed by Acidic Ion Exchange Resin," Industrial & Engineering Chemistry Research, vol. 46, pp. 3078-3085, 2006.
[38] V. V. Goud, et al., "Kinetics of epoxidation of jatropha oil with peroxyacetic and peroxyformic acid catalysed by acidic ion exchange resin," Chemical Engineering Science, vol. 62, pp. 4065-4076, 2007.
[39] V. V. Goud, et al., "Studies on the epoxidation of mahua oil (Madhumica indica) by hydrogen peroxide," Bioresource Technology, vol. 97, pp. 1365-1371, 2006.
[40] J. J. La Scala, et al., "Fatty acid-based monomers as styrene replacements for liquid molding resins," Polymer, vol. 45, pp. 7729- 7737, 2004.
[41] J. Espinoza-Pérez, et al., "Study of the process parameters of the canola oil epoxidation," in 2008 ASABE Annual International Meeting, Providence, Rhode Island, 2008.
[42] D. Ebbing and S. Gammon, General chemistry, 8th ed.: Houghton Mifflin, 2005.
[43] J. Chen, et al., "Epoxidation of partially norbornylized linseed oil," Macromolecular Chemistry and Physics, vol. 203, pp. 2042-2057, 2002.
[44] T. Vl─ìek and Z. Petrović, "Optimization of the chemoenzymatic epoxidation of soybean oil," Journal of the American Oil Chemists' Society, vol. 83, pp. 247-252, 2006.
[45] M. V. Kahraman, et al., "Soybean oil based resin: A new tool for improved immobilization of ╬▒-amylase," Journal of Applied Polymer Science, vol. 100, pp. 4757-4761, 2006.
[46] R. Wool and S. Khot, "Bio-based resins and natural fibers," in ASM Handbook. vol. 21, ed: ASM International, 2001, pp. 184-193.