Adsorption Kinetics of Alcohols over MCM-41 Materials
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Adsorption Kinetics of Alcohols over MCM-41 Materials

Authors: Farouq Twaiq, Mustafa Nasser, Siham Al-Hajri, Mansoor Al-Hasani

Abstract:

Adsorption of methanol and ethanol over mesoporous siliceous material are studied in the current paper. The pure mesoporous silica is prepared using tetraethylorthosilicate (TEOS) as silica source and dodecylamine as template at low pH. The prepared material was characterized using nitrogen adsorption,nX-ray diffraction (XRD) and scanning electron microscopy (SEM). The adsorption kinetics of methanol and ethanol from aqueous solution were studied over the prepared mesoporous silica material. The percent removal of alcohol was calculated per unit mass of adsorbent used. The 1st order model is found to be in agreement with both adsorbates while the 2nd order model fit the adsorption of methanol only.

Keywords: Adsorption, Kinetics, Mesoprous silica, Methanol

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1062602

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[1] F. A. Twaiq, A.R. Mohamed and S. Bhatia, "Liquid Hydrocarbon Fuels from Palm oil by Catalytic Cracking over Aluminosilicate Mesoporous Catalysts with Various Si/Al Ratios". Mesoporous Materials. 64, 2003. pp. 95-107
[2] J.Y. Ying, and C.P. Mehnert "Synthesis and Applications of Supramolecular-Templated Mesoporous Materials", Angew. Chem. Int. Ed, 38, 1999, pp. 57 - 74.
[3] S. Biz and M. L. Ocelli, "Synthesis and Characterization of Mesostructures Materials", Catal. Rev. Sci. Eng., 40(3), 1998, pp. 329 - 407.
[4] B.G. Trewyn, I.I. Slowing, S. Giri, H.-T. Chen, V. S-Y Lin. "Synthesis and Functionalization of a Mesoporous Silica Nanoparticle Based on the Sol-Gel Process and Applications in Controlled Release". Accounts of Chemical Research. 40 (9), 2007, pp. 846-853
[5] M. Yates, J. Blanco, M. A. Martin-Luengo and M. P. "Vapour adsorption capacity of controlled porosity honeycomb monoliths". Microporous Materials. 65 (2-3) 2003, pp. 219-231.
[6] M. Vallet-Regí, F Balas, D.Arcos "Mesoporous materials for drug delivery" Angew. Chem. Int. Ed. 46, 2007, pp. 7548-7558.
[7] B. H. Hameed, "Equilibrium and kinetic studies of methyl violet sorption by agricultural by-product" Journal of Hazardous Materials. 154, (1-3), 2008, pp. 204-212.
[8] H. A. Jamali, A. H. Mahvi and S. Nazmara. "Removal of Cadmium from Aqueous Solutions by Hazel Nut Shell". World Applied Science Journal. 5, 2009, pp. 16-20.
[9] K. Kasim, N. Abu-bakur, S.N. Mustafa, A.M. and Mohamed Z.M. Daud. "Methylene Blue Removal from Simulated Wastewater by Adsorption Using Gandoderma Cultivation Waste Sawdust". World Applied Sciences Journal, 2009, pp. 104-113.
[10] S.A. Mirji, S.B. Halligudi, N. Mathew, N.E. Jacob, K.R. Patil, A.B. Gaikwad. "Adsorption of methanol on mesoporous SBA-15". Materials Letters, 61, 2007, pp. 88-92.
[11] A. Galíková and A. Galík. "The study of the adsorption kinetics of acetylene and methanol on silica gel by gravimetry and global fitting". 31th Intl Conf of SSCHE. Tatransk'e Matliare, Slovakia.May 24-28, 2004, pp.1.
[12] E. Demirbasa, M. Kobyab, E. Senturkb, T. Ozkana. "Adsorption kinetics for the removal of chromium (VI) from aqueous solutions on the activated carbons prepared from agricultural wastes". Water SA, 30 (4), 2004, pp. 533-5337.