A Critics Study of Neural Networks Applied to ion-Exchange Process
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A Critics Study of Neural Networks Applied to ion-Exchange Process

Authors: John Kabuba, Antoine Mulaba-Bafubiandi, Kim Battle

Abstract:

This paper presents a critical study about the application of Neural Networks to ion-exchange process. Ionexchange is a complex non-linear process involving many factors influencing the ions uptake mechanisms from the pregnant solution. The following step includes the elution. Published data presents empirical isotherm equations with definite shortcomings resulting in unreliable predictions. Although Neural Network simulation technique encounters a number of disadvantages including its “black box", and a limited ability to explicitly identify possible causal relationships, it has the advantage to implicitly handle complex nonlinear relationships between dependent and independent variables. In the present paper, the Neural Network model based on the back-propagation algorithm Levenberg-Marquardt was developed using a three layer approach with a tangent sigmoid transfer function (tansig) at hidden layer with 11 neurons and linear transfer function (purelin) at out layer. The above mentioned approach has been used to test the effectiveness in simulating ion exchange processes. The modeling results showed that there is an excellent agreement between the experimental data and the predicted values of copper ions removed from aqueous solutions.

Keywords: Copper, ion-exchange process, neural networks, simulation

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1062030

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[1] J. Warchol, R. Petrus, "modeling of heavy metal removal dynamics in clinoptilolite packed beds," Microporous and Mesoporous Materials. vol. 93, 2006, pp. 29-39.
[2] B. B. Mamba, D.W. Nyembe and A.F. Mulaba-Bafubiandi. "Removal of copper and cobalt from aqueous solutions using natural clinoptilolite" Water SA, vol. 3-35, 2009, pp. 307-314.
[3] S. Kesraoui-Ouki, C.R. Cheeseman, R. Perry, "Natural Zeolite utilization in pollution control: A review of applications to metals effluents," J. Chem.Tech. Biotechnol. vol. 59, 1994, pp.121-126.
[4] P. Kittisupakom, P. Tangteerasunun and P. Thitiyasook, "Dynamic Neural Network Modeling for Hydrochloric Acid Recovery Process", Korean J. Chem. Eng. vol. 22(6), 2005, pp. 813-821.
[5] M. M. Van den Bosch. "Simulation of ion exchange processes using neuro-fuzzy reasoning". Cape Peninsula University of Technology, South Africa, Theses & Dissertation. 2009
[6] S. Haykin. "A Comprehensive Foundation, Prentice Hall". 1999.
[7] X. Du, J. Yuan, Y. Zhao, Y. Li. "Comparison of general rate model with a new model-artificial neural network model in describing chromatographic kinetics of solanesol adsorption in packed column by macro porous resins." J. Chromatogr. vol. A 23, 2007, pp.165-174.
[8] W. Gao and S. Engell. "Estimation of general nonlinear adsorption isotherms from chromatograms". Comput. Chem.Eng. vol. 29, pp. 2242- 2255.
[9] J. S. J. Deventer van, S. P. Liebenbert, L. Lorenzen. "Dynamic modeling of competitive elution of activated carbo in columns using neural networks." Miner. Eng., vol. 8, 1995, pp. 1489-1501.