Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33093
Selective Separation of Lead and Mercury Ions from Synthetic Produced Water via a Hollow Fiber Supported Liquid Membrane
Authors: S. Suren, U. Pancharoen
Abstract:
A double module hollow fiber supported liquid membrane (HFSLM) was applied to selectively separate lead and mercury ions from dilute synthetic produced water. The experiments were investigated on several variables: types of extractants (D2EHPA, Cyanex 471, Aliquat 336, and TOA), concentration of the selected extractant and operating time. The results clearly showed that the double module HFSLM could selectively separate Pb(II) and Hg(II) in feed solution at a very low concentration to less than the regulatory discharge limit of 0.2 and 0.005 mg/L issued by the Ministry of Industry and the Ministry of Natural Resource Environment, Thailand. The highest extractions of lead and mercury ions from synthetic produced water were 96% and 100% using 0.03 M D2EHPA and 0.06 M Aliquat 336 as the extractant for the first and second modules.Keywords: Hollow fiber, Lead ions, Liquid membrane, Mercury ions, Selective separation
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1060353
Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2334References:
[1] D.R. Turner, "Speciation and cycling of arsenic, cadmium, lead and mercury in natural waters, in: T.C. Hutchinson, K.M. Meema (Eds.), Lead, Mercury, Cadmium and Arsenic in the Environment," John Wiley & Sons Ltd., England, pp. 175-186, 1987.
[2] G. Corvini, J. Stiltner, and K. Clark, "Mercury removal from natural gas and liquid streams," UOP LLC, pp. 3, 2007.
[3] D.L. Gallup, and J.B. Strong, "Removal of mercury and arsenic from produced water," Chevron Corporation, pp. 1-9, 2007.
[4] M. Z. Barciszewska, M. Szymanski, E. Wyszko, J. Pas, L. Rychlewski, and J. Barciszewski, "Lead toxicity through the leadzyme," Mutat. Res., Rev. Mutat. Res., vol. 589, pp. 103-110, 2005.
[5] F. Zahir, S. J. Rizwi, S. K. Haq, and R. H. Khan, "Low dose mercury toxicity and human health," Environ. Toxicol. Pharmacol., vol. 20, pp. 351-360, 2005.
[6] Thailand regulatory discharge standards, Ministry of Industry, Thailand, 1996.
[7] B. S. Inbaraj, J. S. Wang, J. F. Lu, F. Y. Siao, and B. H. Chen, "Adsorption of toxic mercury(II) by an extracellular biopolymer poly(
[gamma]-glutamic acid)," Bioresour. Technol., vol. 100, pp. 200- 207, 2009.
[8] R. Guell, E. Antico, V. Salvado, and C. Fontas, "Efficient hollow fiber supported liquid membrane system for the removal and preconcentration of Cr(VI) at trace levels," Sep. Purif. Technol., vol. 62, pp. 389-393, 2008.
[9] U. Pancharoen, W. Poonkum, and A. W. Lothongkum, "Treatment of arsenic ions from produced water through hollow fiber supported liquid membrane," J. Alloys Compd., vol. 482, pp. 328-334, 2009.
[10] P. Kandwal, S. A. Ansari, and P. K. Mohapatra, "Transport of cesium using hollow fiber supported liquid membrane containing calix
[4]arenebis( 2,3-naphtho)crown-6 as the carrier extractant: Part II. Recovery from simulated high level waste and mass transfer modeling," J. Membr. Sci., vol. 384, pp. 37-43, 2011.
[11] M. F. San Roman, E. Bringas, R. Ibanez, and I. Ortiz, "Liquid membrane technology: fundamentals and review of its applications," J. Chem. Technol. Biotechnol., vol. 85, pp. 2-10, 2010.
[12] I. M. Coelhoso, M. M. Cardoso, R. M. C. Viegas, and J. P. S. G. Crespo, "Transport mechanisms and modelling in liquid membrane contactors," Sep. Purif. Technol., vol. 19, pp. 183-197, 2000.
[13] U. Pancharoen, A.W. Lothongkum, and S. Chaturabul, "Mass transfer in hollow fiber supported liquid membrane for As and Hg removal from produced water in upstream petroleum operation in the gulf of Thailand, in: M. El-Amin (Ed.), Mass Transfer in Multiphase Systems and Its Applications," InTech, India, pp. 499-524, 2011.
[14] A. Escobar, K. A. Schimmel, J. de Gyves, and E. R. de San Miguel, "Hollow-fiber dispersion-free extraction and stripping of Pb(II) in the presence of Cd(II) using D2EHPA under recirculating operation mode," J. Chem. Technol. Biotechnol., vol. 79, pp. 961-973, 2004.
[15] F. d. M. Fabrega and M. B. Mansur, "Liquid-liquid extraction of mercury (II) from hydrochloric acid solutions by Aliquat 336," Hydrometallurgy., vol. 87, pp. 83-90, 2007.
[16] T. Francis, T. Prasada Rao, and M. L. P. Reddy, "Cyanex 471X as extractant for the recovery of Hg(II) from industrial wastes," Hydrometallurgy., vol. 57, pp. 263-268, 2000.
[17] U. Pancharoen, S. Somboonpanya, S. Chaturabul, and A. W. Lothongkum, "Selective removal of mercury as HgCl4 2- from natural gas well produced water by TOA via HFSLM," J. Alloys Compd., vol. 489, pp. 72-79, 2010.
[18] S. Suren, T. Wongsawa, U. Pancharoen, T. Prapasawat, and A. W. Lothongkum, "Uphill transport and mathematical model of Pb(II) from dilute synthetic lead-containing solutions across hollow fiber supported liquid membrane," Chem. Eng. J., vol. 191, pp. 503-511, 2012.
[19] Y. Kawamura, M. Mitsuhashi, H. Tanibe, and H. Yoshida, "Adsorption of metal ions on polyaminated highly porous chitosan chelating resin," Ind. Eng. Chem. Res., vol. 32, pp. 386-391, 1993.
[20] A. W. Lothongkum, S. Suren, S. Chaturabul, N. Thamphiphit, and U. Pancharoen, "Simultaneous removal of arsenic and mercury from natural-gas-co-produced water from the Gulf of Thailand using synergistic extractant via HFSLM," J. Membr. Sci., vol. 369, pp. 350- 358, 2011.
[21] L. Iberhan and M. Wisniewski, "Extraction of arsenic(III) and arsenic(V) with Cyanex 925, Cyanex 301 and their mixtures," Hydrometallurgy., vol. 63, pp. 23-30, 2002.
[22] B. Wassink, D. Dreisinger, and J. Howard, "Solvent extraction separation of zinc and cadmium from nickel and cobalt using Aliquat 336, a strong base anion exchanger, in the chloride and thiocyanate forms," Hydrometallurgy., vol. 57, pp. 235-252, 2000