Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 30174
Determination and Preconcentration of Iron (II) in Aqueous Solution with Amberlite XAD-4 Functionalized with 1-amino-2-naphthole by Flame Atomic Absorption Spectrometry

Authors: Homayon Ahmad Panahi, Mahshid Nikpour Nezhati, Faranak Mahmoudi, Elham Moniri, Meghdad Karimi

Abstract:

A new chelating resin is prepared by coupling Amberlite XAD-4 with 1-amino-2-naphthole through an azo spacer. The resulting sorbent has been characterized by FT-IR, elemental analysis and thermogravimetric analysis (TGA) and studied for preconcentrating of Fe (II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the iron ions was 6.5. The resin was subjected to evaluation through batch binding of mentioned metal ion. Quantitative desorption occurs instantaneously with 0.5 M HNO3. The sorption capacity was found 4.1 mmol.g-1 of resin for Fe (II) in the aqueous solution. The chelating resin can be reused for 10 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 97% was obtained the metal ions with 0.5 M HNO3 as eluting agent. The method was applied for metal ions determination from industrial waste water sample.

Keywords: Amberlite XAD-4, Iron (II), Flame atomic absorption, Chelator, 1-amino-2- naphthole

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1328494

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1587

References:


[1] Lemos VA, Silva DG, Carvalho AL, Andrade Santana D, Santos Novaes G, Passos AS (2006) Microchem J 84:14-21.
[2] Camel V (2003) Spectrochim Acta, Part B 58:1177-1233
[3] Cesur H, Aksu C (2006) Anal Sci 22(5):727-730
[4] Ghaedi M, Ahmadi F, Karimi H, Gharaghani S (2006) J Korean Chem Soc 50: 23-31.
[5] Ahmad Panahi H, Sid Kalal H, Moniri E, Nikpour Nezhati M, Taheri Menderjani M, Ranjbar Kelahrodi S, Mahmoudi F (2009) Microchem J 93: 49-54
[6] Hashemi-Moghaddam H, Ahmad Panahi H, Nikpour Nezhati M (2009) Anal Lett 42: 1-12
[7] FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Amrollahi M, Mahmoudi F (2009) Water Environ Res 81(5): 532-539
[8] Saito K, Taninaka I, Yamamoto Y, Murakami S, Muromatsu A (2000) Talanta 51: 913-919.
[9] Alguacil FJ, Adeva P, Alonso M (2005) Gold Bull 38: 9-13.
[10] Prasad K, Gopikrishna P, Kala R, Rao TP, Naidu GRK (2006) Talanta 69: 938-945.
[11] Kagaya S, Sagisaka T, Miwa S, Morioka K, Hasegawa K (2006) Bull Chem Soc Jpn 79(5): 717-724
[12] Karatepe AU, Soylak M, Elci L (2002) Anal Lett 35: 1561-1574.
[13] Sombra L, Luconi M, Silva MF, Olsina RA, Fernandez L (2001) The Analyst 126(7): 1172-1176
[14] Zhang Y, Luo WH, Li H (2005) Spectroscopy and Spectral Analysis 25: 576-578