Treatment of Oily Wastewater by Fibrous Coalescer Process: Stage Coalescer and Model Prediction
Authors: Pisut Painmanakul, Kotchakorn Kongkangwarn, Nattawin Chawaloesphonsiya
Abstract:
The coalescer process is one of the methods for oily water treatment by increasing the oil droplet size in order to enhance the separating velocity and thus effective separation. However, the presence of surfactants in an oily emulsion can limit the obtained mechanisms due to the small oil size related with stabilized emulsion. In this regard, the purpose of this research is to improve the efficiency of the coalescer process for treating the stabilized emulsion. The effects of bed types, bed height, liquid flow rate and stage coalescer (step-bed) on the treatment efficiencies in term of COD values were studied. Note that the treatment efficiency obtained experimentally was estimated by using the COD values and oil droplet size distribution. The study has shown that the plastic media has more effective to attach with oil particles than the stainless one due to their hydrophobic properties. Furthermore, the suitable bed height (3.5 cm) and step bed (3.5 cm with 2 steps) were necessary in order to well obtain the coalescer performance. The application of step bed coalescer process in reactor has provided the higher treatment efficiencies in term of COD removal than those obtained with classical process. The proposed model for predicting the area under curve and thus treatment efficiency, based on the single collector efficiency (ηT) and the attachment efficiency (α), provides relatively a good coincidence between the experimental and predicted values of treatment efficiencies in this study.
Keywords: Stage coalescer, stabilized emulsions, treatment efficiency, model prediction.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1328350
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[1] Y. Aurelle, Treatments of oil-containing wastewater. Chulalongkorn University, Bangkok, 1985.
[2] S. Saipanich, Y. Aurelle, and H. Roques, "Emulsion separation by coalescence technique," in Thailand Engineering Journal, vol. 36, no. 1, 1983, pp. 76-84.
[3] J. Li, and Y. Gu, "Coalescence of oil-in-water emulsions in fibrous and granular beds," in Separation and Purification Technology, vol. 42, 2005, pp. 1-13.
[4] R.M.┼á. Sokolović, T.J.Vulić, and S. M. Sokolović, "Effect of bed length on steady-state coalescence of oil-in-water emulsion," in Separation and Purification Technology, vol. 56, 2007, pp. 79-84.
[5] F. Rebelein, E. Blass," Separation of micro-dispersions in fibre-beds," in Filtration & Separation, 3 ed., vol. 9, 1990, pp. 360-363.
[6] B. Wanichkul, "Comparison of ultrafiltration and distillation processes for treatment of cutting oil emulsion," Ph.D. dissertation, The Institut National des Sciences Appliquées of Toulouse., Toulouse, France, 2000.
[7] J. R. Madia, S. M. Fruh, C. A. Miller, and A. Beerbower, "Granular packed bed coalescer: influence of packing wettability on coalescence," in Envir Sci& Technol, vol. 10, no. 10, 1976, pp 1044-1046.
[8] S.D. Bhagat, K. Y. Ha, and A. Y. Soo, "Room temperature synthesis of water repellent silica coatings by the dip coat technique," in Applied Surface Science, vol. 253, no. 4, 1996, pp. 2217-2221.
[9] J. Fei, L. Chaolin, D. Xiaoqing, L. Yang, and W. Dandan, "Separation of oil from oily wastewater by sorption and coalescence technique using ethanol grafted polyacrulonitrile," in Environmental Science & Engineering Research Center, Shenzhen Graduate School, Harbin Institute of Technology, China, 2008.
[10] G.N.Mathavan, and T. Viraraghavan, "Coalescence/filtration of an oilinwater emulsion in a peat bed," in Water Res, vol. 26, 1992, pp. 91-98.
[11] A. Gammoun, S. Tahiri, A. Albizane, M. Azzi, J. Moros, S. Garrigues, and M. de la Guardia, "Separation of motor oils, oily wastes and hydrocarbons from contaminated water by sorption on chrome shavings," in J. Hazard Mater., vol. 145, 2007, pp. 148-153.
[12] S.S. Banerjee, M.V. Joshi, and R.V. Jayaram, "Treatment of oil spill by sorption technique using fatty acid grafted sawdust," in Chemosphere, vol. 64, 2006, pp. 1026-1031.
[13] Guidance document for Pretreatment with oil/water separators draft, Water Quality Division Aquifer Protection Program, BADCT, Arizona Department of Environmental Quality, Arizona, 1996.
[14] S. Titasupawat, P. Sastaravet, K. Kongkangwarn, and P. Painmanakul, "Treatment of oily wastewater by Modified Induced Air Flotation process (MIAF)," Department of environmental engineering, Faculty of engineer, Chulalongkorn University, Bangkok, Thailand , 2008.
[15] C. Chooklin, "Removal of stabilized oil in wastewater emulsions by induced air flotation," M.Eng. thesis, Chulalongkorn University, Bangkok, 2004.
[16] Standard Methods for Examination of Water and Wastewater, APHA, AWWA, WPCF, 20th ed., United Book Press, Ind. Maryland, USA, 1998.
[17] R. G. Griskey, "Transport phenomena and unit operations: A combined approach," John Wiley & Sons, Inc., New Jersey. 2002
[18] H. Wadell, "Volume, shape and roundness of quartz particles," in Journal of Geology, vol. 43, 1935, pp. 250-280.
[19] Flingoh, C. H. Oh, and C. C. Let, "Surface tension of palm oil, palm olein and palm steatin," in ELAEIS, vol. 4, no. 1, 1992, pp. 27-31.