Effects of Coupling Agent and Flame Retardant on the Performances of Oil Palm Empty Fruit Bunch Fiber Reinforced Polypropylene Composites
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Effects of Coupling Agent and Flame Retardant on the Performances of Oil Palm Empty Fruit Bunch Fiber Reinforced Polypropylene Composites

Authors: R. Ridzuan, M. D. H. Beg, M. Y. Rosli, M. H. Rohaya, A. A. Astimar S. Samahani, I. Zawawi

Abstract:

Alkali treated oil palm empty fruit bunch (EFB) fibres (TEFBF) and untreated EFBF fibers (UEFBF) were incorporated in polypropylene (PP) with and without malic anhydride grafted PP (MAPP) and magnesium hydroxide as flame retardant (FR) to produce TEFBF-PP and UEFBF-PP composites by the melt casting method. The composites were characterized by mechanical and burning tests along with a scanning electron microscope and Fourier transform infrared spectroscopy. The significant improvement in flexural modulus (133%) and flame retardant property (60%) of TEFBF-PP composite with MAPP and FR is observed. The improved mechanical property is discussed by the development of encapsulated textures.

Keywords: Empty fruit bunch fibers, polypropylene, mechanical property, flame retardant.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1056958

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[1] Satyanarayana, K. G., Sukumaran, K., Mukherjee, P. S., Pavithran, C., and Pillai, S. G. K., ., "Natural fibre-polymer composites". Cem. Conc. Compos, 1990, ch. 12(2),pp. 117-136.
[2] Ku, H., Wang, H., Pattarachaiyakoop, N. M., and Trada, M. "A review on the tensile properties of natural fibre reinforced polymer composites". (Compos.Part B Eng) ,2011, ch. 42(4),pp. 856-873.
[3] Bledzki, A. K. and Gassan, J., "Composites reinforced with cellulose based fibers". Prog. Polym. Sci.1999, ch. 24, pp. 221-274.
[4] Rozman, H. D., Lai, C. Y., Ismail, H., and Ishak Z. A. M., "The effect of coupling agents on the mechanical and physical properties of oil palm empty fruit bunch-polypropylene composites". Polym. In. 2000, ch. 49, pp. 1273-1278.
[5] Alam, A. K. M. M., Beg, M. D. H., Prasad, D. M. R., Khan, M. R., and Mina, M. F. "Structures and Performances of Simultaneous Ultrasound and Alkali Treated Oil Palm Empty Fruit Bunch Fiber Reinforced Poly(Lactic Acid) Composites". Compos.-Part B: Appl. Sci. Manuf., 2012,ch. 43, pp. 1921-1929.
[6] Nabi, S. D and Jog, J. P. Adv. Polym.. Technol.,1999 ,ch. 18(4), pp. 351-363.
[7] Liu, W., Mohanty , A.K., Drzal, L.T., Askel, P., and Misra, M., "Natural Fiber Polymer Composites (A review)". J.Mater. Sci., 2004, ch. 39(3), pp. 1051-1054.
[8] Cao, Y., Sakamoto, S., and Goda, K., "Effects of heat and alkali treatments on mechanical properties of kenaf fibers,"
[16th international conference on composite materials, Kyoto, Japan, 2007,pp. 1-4.]
[9] Bledzki1, A. K., Mamun, A. A., Lucka-Gabor, M., and Gutowski, V. S. "The effects of acetylation on properties of flax fibre and its polypropylene composites," Express Polym. Lett., 2008, ch. (6)2, pp. 413-422.
[10] Yang, H.S., Wolcott, M.P., Kim, H.S., Kim, S. and Kim, H.J. "Effect of different compatibilizing agents on the mechanical properties of lignocellulosic material filled polyethylene bio-composites." Compos. Struc., 2007, ch. 79(3), pp. 369-375.
[11] Islam, M.S., Pickering, K.L., and Foreman, N.J., "Influence of alkali treatment on the interfacial and physico-mechanical properties of industrial hemp fibre reinforced polylactic acid composites." Compos. Part A Appl. Sci. and Manuf., 2010,ch. 41, pp. 596-603.
[12] Li, X., Tabil, L. G., and Panigrahi S., "Chemical treatments of natural fiber for use in natural fiber-reinforced composites(A Review. J. Polym. Environ)." 2007,ch.15, pp. 25-33.
[13] Xie, Y., Hill, C. A. S., Xiao, Z., Militz, H., and Mai, C. "Coupling agents used for natural fiber/polymer composites(A review. Compos. Part A Appl. Sci. Manuf)." 2010, ch. 41, pp. 806-819.
[14] Gao, C. and Yan, D., "Hyperbranched polymers: from synthesis to applications(Prog. Polym. Sci)., 2004, ch. 29, pp. 183-275.
[15] Kim, H. S., Lee, B. H., Choi, S. W., Kim, S., and Kim, H. J. "The effect of types of maleic anhydride-grafted polypropylene (MAPP) on the interfacial adhesion properties of bio-flour-filled polypropylene composites (Compos. Part A Appl. Sci. Manuf)."2007, ch. 38, pp. 1473- 1482.
[16] Mina, M. F., Seema, S., Matin, R. Rahaman, M. J. Sarker, R. B., Gafur, M. A., and Bhuiyan, M. A. H., "Improved performance of isotactic polypropylene/titanium dioxide composites: Effect of processing conditions and filler content (Polym. Degrad. Stab).", 2009, ch. 94(2), pp. 183-188.
[17] Sharma, S.K. and Nayak, S.K., "Surface modified clay/polypropylene (PP) nanocomposites: Effect on physico-mechanical, thermal and morphological properties (Polym. Degrad. Stab).", 2009, ch. 94, pp. 132-138.
[18] Zebarjad, S.M., Tahani, M., and Sajjadi, S.A., "Influence of filler particles on deformation and mechanism of isotactic polypropylene.", J. Mater. Proc. Technol., 2004,pp. 155-156, pp. 1459-1464.
[19] Suppakarn, N. and Jarukumjorn, K., "Mechanical properties and flammability of sisal/PP composites: Effect of flame retardant type and content (Compos. Part B Appl. Sci. Manuf).", 2009, ch. 40, pp. 613- 618.
[20] Zhang, S. and Horrocks, A.R., "A review of flame retardant polypropylene fibres Prog (Polym. Sci)." , 2003, ch. 28, pp. 1517-1538.
[21] Shinoj, S., Visvanathan, R., and Panigrahi, S., "Towards industrial utilization of oil palm fibre: Physical and dielectric characterization of linear low density polyethylene composites and comparison with other fibre sources (Biosys. Eng).", 2010, ch. 106, pp. 378-388.
[22] Eichhorn, S. J., Baillie, C. A., Zafeiropoulos, N., Mwaikambo, L.Y., Ansell, M. P., Dufresne, A., Entwistle, K. M., Herrera-Franco, P.J., Escamilla, G. C., Groom, L., Hughes, M., Hill, C., Rials, T. G., and Wild, P. M., "Current international research into cellulosic fibers and composites ," J Mater Sci, 2001, ch. 36, pp. 2107-2131.
[23] Khalil, H. P. S. A., Alwani, M. S., Ridzuan, R., Kamarudin, H., and Khairul, A., "Chemical Composition, Morphological Characteristics, and Cell Wall Structure of Malaysian Oil Palm Fibers (Polym. Plast. Technol. Eng).", 2008, ch. 47, pp. 273-280.
[24] Li, B. and He, J., "Investigation of mechanical property, flame retardancy and thermal degradation of LLDPE-wood-fibre composites (Polym Degrad. Stab).", 2004, ch. 83, pp. 241-246.
[25] Park, J. M., Quang, S. T., Hwang, B. S., and DeVries, K. L., "Interfacial evaluation of modified Jute and Hemp fibers/polypropylene (PP)-maleic anhydride polypropylene copolymers (PP-MAPP) composites using micromechanical technique and nondestructive acoustic emission (Compos. Sci. Tecnol).", 2006, ch. 66, pp.15, pp. 1, pp. 2686-2699 .
[26] Sun, R.C. Sun, X.F., Fowler, P., and Tomkinson, J., "Structural and physico-chemical characterization of lignins solubilized during alkaline peroxide treatment of barley straw Eur (Polym. J).", 2002, ch. 38, pp. 1399-1407.
[27] Metin, D., Tihminliog, F., Balko, D. and Iku, S.U., "The effect of interfacial interactions on the mechanical properties of polypropylene/natural zeolite composites (Compos. Part A Appl. Sci. Manuf).", 2004, ch. 35, pp. 23-32.
[28] Islam, M.D.N., Rahman, M.D. R., and Haque, M.D.M., "Physicomechanical properties of chemically treated coir reinforced polypropylene composites (Compos. Part A Appl. Sci. Manuf).", 2010, ch. 41(2), pp. 192-198.
[29] Rahman, M.D.R., Huque, M.D.M. Islam, M.D.N., and Hasan, M., "Mechanical properties of polypropylene composites reinforced with chemically treated abaca (Compos. Part A Appl. Sci. Manuf).", 2009, ch. 40(4), pp. 511-517.
[30] Fang, J.M., Sun, R.C., Salisbury, D., Fowler, P., and Tomkinson, J., "Comparative study of hemicelluloses from wheat straw by alkali and hydrogen peroxide extractions (Polym Degrad. Stab).", 1999, ch. 66, pp. 423-432.
[31] Rozman, H.D., Saad, M.J., and Ishak, Z.A. M., "Flexural and impact properties of oil palm empty fruit bunch (EFB)-polypropylene composites- the effect of maleic anhydride chemical modification of EFB (Polym. Test).", 2003, ch. 22(3), pp. 335-341.
[32] Beckermann, G.W. and Pickering, K.L., "Engineering and evaluation of hemp fibre reinforced polypropylene composites: Fibretreatment and matrix modification (Compos. Part A Appl. Sci. Manuf).", 2008, ch. 39, pp. 979-988.