Response Surface Based Optimization of Toughness of Hybrid Polyamide 6 Nanocomposites
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 32805
Response Surface Based Optimization of Toughness of Hybrid Polyamide 6 Nanocomposites

Authors: E. Hajizadeh, H. Garmabi

Abstract:

Toughening of polyamide 6 (PA6)/ Nanoclay (NC) nanocomposites with styrene-ethylene/butadiene-styrene copolymer (SEBS) using maleated styrene-ethylene/butadiene-styrene copolymer (mSEBS)/ as a compatibilizer were investigated by blending them in a co-rotating twin-screw extruder. Response surface method of experimental design was used for optimizing the material and processing parameters. Effect of four factors, including SEBS, mSEBS and NC contents as material variables and order of mixing as a processing factor, on toughness of hybrid nanocomposites were studied. All the prepared samples showed ductile behavior and low temperature Izod impact toughness of some of the hybrid nanocomposites demonstrated 900% improvement compared to the PA6 matrix while the modulus showed maximum enhancement of 20% compared to the pristine PA6 resin.

Keywords: Hybrid nanocomposites, PA6, SEBS rubber, toughness.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1056186

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 1583

References:


[1] T. Liu,W.C.Tjiu,C.He,S.S.Na, T.S.Chung, "Aprocessing-induced clay dispersion and its effect on the structure and properties of polyamide6", PolymInt,Vol.53,P.392-399,2004.
[2] L.S.Loo,K.K.Gleason,"investigation of polymer and nanoclayorientation distribution in nylon6/montmorillonite nanocomposites, polym,Vol.45,P.5933-5939,2004.
[3] T.C.Li,J.Ma,M.Wang,W.C.Tjiu, T.Liu,W.Huang,"Effect of clay addition on the morphology and thermal behavior of polyamide 6,Applied polym sci,Vol.103,P.1191-1199,2007.
[4] D.C.Lopez,I.G.Mitre,J.F.Fernandez,J.C.Merino,J.M.Pastor,"influence of clay modification process in PA6/layered silicate nanocomposite properties", Polym,Vol.46,P.2758-2765,2005.
[5] F. Baldi, F.Bignotti, G. Tieghi, T.Ricco, " rubber toughening of polyamide 6/organoclay nanocomposites obtained by melt blending",Applied polym sci,Vol.99, P.3406-3416,2006.
[6] I. Gonzalez, JI. Eguiazabal,J.Nazabal, "Nanocomposites based on a polyamide 6/maleated stryrene-butylene-co-ethylene-styrene blend:effects of clay loading on morphology and mechanical properties", European polymVol.42, P.2905-2913,2006.
[7] I. Gonzalez,JI. Eguiazabal,J.Nazabal, "Compatibilization level effects on the structure and mechanical properties of rubber-modified polyamide 6/clay nanocomposites "polym sci,Vol.43,P.3611-3620,2005.
[8] S.C.Tjong, S.P.Bao,"Impact fracture toughness of polyamide0/montmorillonite nanocomposites toughened with a maleated styrene/ethylene buthylenr/styrene elastomer", polym sci : part B :Polym Phys, Vol.43,P.585-595,2005.
[9] I.Kelnar, J.Kotek, L.Kapralkova, J.Hromadkova, J. Kratochvil,"effect of elastomer type and functionality on the behavior of toughened polyamide nanocomposites"Applied polym sci,Vol.100,P.1571- 1576,2006.