Effect of Different Conditions on the Sorption Behavior of Co2+ Using Celatom- ZeoliteY Composite
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33093
Effect of Different Conditions on the Sorption Behavior of Co2+ Using Celatom- ZeoliteY Composite

Authors: Salam K. Al-Nasri, SM Holmes

Abstract:

Composite of Celatom-ZeoliteY (Cel-ZY) was used to remove cobalt ion from an aqueous solution using batch mode. ZeoliteY has successfully superimposed on Celatom FW-14 surface using hydrothermal treatment .The product was synthesized as a novel of hierarchical porous material. It was observed from the results that Cel-ZY has higher ability to remove cobalt ions than the pure ZeoliteY powder (PZY) synthesized under the same conditions. Several parameters were studied in this project to investigate the effect of removal cobalt ion such as pH and initial cobalt concentration. It was clearly observed that the uptake of cobalt ions was affected with increase these parameters. The results proved that the product can be used effectively to remove Co2+ ions from wastewater as an environmentally friendly alternative.

Keywords: Adsorption, Celatom-Zeolite, Cobalt ions, Isotherm models.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1087624

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2381

References:


[1] ND M.Dulama, M.Pavelesscu, L.Pasare, “ Combined radioactivity liquid waste treatment process involving inorganic sorbents and micro/ altrafiltration”, journal physics 2009;Vol: 54 (Bucharest).
[2] I EnDyna, ” Potential nano-enabled environmental application of radionuclides”, Environmental Protection Agency,EPA/402/R-09/002 January 2009(Washington, DC 20460).
[3] M Streat, J Patrick, M Perez ,“Sorption of phenol and parachlorophenol from water using conventional and novel activated carbons”, Water Research 1995;29(2):467-472.
[4] A Chmielewski, M Harasimowicz, G Zakrzewska-Trznadel,” Membrane technologies for liquid radioactive waste treatment”, Czechoslovak Journal of Physics 1999;49(0):979-985.
[5] HEGMM Bakr, ” Diatomite : its characterization, modifications and applications” , Asian Journal of Materials Science 2010;2(3):121-136.
[6] H Arik, ”Synthesis of Si3N4 by the carbo-thermal reduction and nitridation of diatomite”, Journal of the European Ceramic Society 2003;23((12)): pp. 2005-2014.
[7] MS Hassan, I.A. Ibrahim, I.S. Ismael, “Diatomaceous deposits of Fayium, Egypt: Characterization and evaluation for industrial application”, Chinese J .Geochemis.1999;18:233-241.
[8] DL Durham”Diatomite” Us Geological Mineral Resource,Us Geological Survey Professional Paper 1973;820:pp.191–5.
[9] B Gao, P Jiang, F An, S Zhao, Z Ge ” Studies on the surface modification of diatomite with polyethyleneimine and trapping effect of the modified diatomite for phenol” Applied surface science 2005;250(1):273-279.
[10] RP Xu, W.; J.Yu; Q Huo; J Chen and Z Gao “Chemistry of Zeolite and related porous materials”. Wiley: Singapore 2007:pp 145-146. 0 50 100 150 200 0 100 200 300 400 Adsorption capacity qe (mg/g) Equlibrium concentration Ce (mg/L) Exp. Data Langmuir model Frenudlich model 0 5E-09 1E-08 1.5E-08 2E-08 2.5E-08 3E-08 0 2 4 6 Separation Factor (RL) Initial Concentration C0 (mg/L)
[11] ER Allen, and D.W. Ming. “Recent progress in the use of natural zeolites in agronomy and horticulture”, International Committee on Natural Zeolites,1995(Brockport, N.Y):477-490.
[12] N Gao, S Kume, K Watari “Zeolite–carbon composites prepared from industrial wastes:(I) Effects of processing parameters” Materials Science and Engineering: A 2005;399(1):216-221.
[13] A Dyer,” An introduction to zeolite molecular sieves”, 1988.
[14] O Hernandez-Ramirez,” Hierarchical bio-structures incorporating zeolite Y for wastewater treatment applications”, A thesis submitted to the University of Manchester for the degree of Doctor of Philosophy in the Faculty of Engineering and Physical Sciences 2009.
[15] O Hernández-Ramírez, PI Hill, DJ Doocey, SM Holmes, ” Removal and immobilisation of cobalt ions by a novel, hierarchically structured, diatomite/zeolite Y composite”, Journal of Materials Chemistry 2007;17(18):1804-1808.
[16] I Kula, M Ugurlu, H Karaoglu, A Çelik, “Adsorption of Cd (II) ions from aqueous solutions using activated carbon prepared from olive stone by ZnCl2 activation”,Bioresource Technology 2008;99(3):492-501.
[17] S Wang, H Li, L Xu ,”Application of zeolite MCM-22 for basic dye removal from wastewater”, Journal of colloid and interface science 2006;295(1):71-78.
[18] A El-Kamash, ”Evaluation of zeolite A for the sorptive removal of Cs< sup>+</sup> and Sr< sup> 2+</sup> ions from aqueous solutions using batch and fixed bed column operations”, Journal of Hazardous Materials 2008;151(2):432-445.
[19] G Memon, M Bhanger, M Akhtar,”Peach-nut shells-an effective and low cost adsorbent for the removal of endosulfan from aqueous solutions”, Pak. J. Anal. Environ. Chem 2009;10:14-18.
[20] MMJ Treacy, JB Higgins, R von Ballmoos,Commission IZAS,” Collection of simulated XRD powder patterns for zeolites”, Elsevier New York; 1996.
[21] VJ Inglezakis, C.D Papadeus, M.D Loizidou, H.P Grigoropoulou,” Effects of pretreatment on physical and ion exchange properties of natural clinoptilolite” Environ.Technol. 2001;22:75– 82.
[22] M Doula, A.Ioannou, A.Dimirkou, “Copper adsorption and Si, Al, Ca, Mg, and Na release from clinoptilolite”. J.Colloid Interface 2002;Sci. 245:237– 250.
[23] MI Panayotova,” Kinetics and thermodynamics of copper ions removal from wastewater by use of zeolite”, Waste Manag. 2001;21:671– 676.
[24] O Hernandez-Ramirez, SK Al-Nasri, SM Holmes, ”Hierarchical structures based on natural carbons and zeolites”, Journal of Materials Chemistry 2011;21(41):16529-16534.
[25] YB Onundi, A Mamun, M Al Khatib, Y Ahmed ,”Adsorption of copper, nickel and lead ions from Synthetic semiconductor industrial wastewater by palm shell activated carbon”, Int. J. Environ. Sci. Tech 2010;7(4):751-758.
[26] AM Ei-Kamash “Evaluation of zeolite A for the sportive removal of Cs+ and Sr2+ions from aqueous solutions using batch and fixed bed column operation”, Hazardous Materials 2007;151(2008):432-445.
[27] YS Ho ,” Isotherms for the sorption of lead onto peat:comparison of linear and non-linear methods”, Polish Journal of Environmental Studies 2006;15(1):81-86.