Modelling the Sublimation-Desublimation Processes for Production of Ultrafine Powders
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Modelling the Sublimation-Desublimation Processes for Production of Ultrafine Powders

Authors: V. Golubev, A. Dosmakanbetova, A. Brener

Abstract:

The purpose of this work is to establish the theoretical foundations for calculating and designing the sublimationcondensation processes in chemical apparatuses which are intended for production of ultrafine powders of crystalline and amorphous materials with controlled fractional composition. Theoretic analysis of the primary processes of nucleation and growth kinetics of the clusters according to the degree of super-saturation and the homogeneous or heterogeneous nature of nucleation has been carried out. The engineering design procedures of desublimation processes have been offered and tested for modification of the Claus process.

Keywords: Desublimation, controlled fraction composition, nucleation, ultrafine powders.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1087061

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References:


[1] Lamminen E., Isherwood H., Effect of process parameters on ultrafine and fine particles emissions.Chemical Engineering Transactions, Vol.17, 2009, pp. 729-735.
[2] Kashchiev D., Nucleation: Basic Theory with Applications, Butterworth Heinemann, Oxford, UK, 2000.
[3] Farjoun Y., Neu J.C., Exhaustion of nucleation in a closed system, Phys. Rev.,E78, 2008, pp.1-7.
[4] Schmelzer J.W. Eds., Nucleation Theory and Applications, Willey- VCH Verlag GmbH & Co.KGaA, Weinheim, 2005.
[5] Pack D.J., Elemental Sulphur Formation in Natural Gas Transmission Pipelines, PhD Thesis, University of Western Australia, 2005.
[6] Wattis J. A. D., An introduction to mathematical models of coagulation-fragmentation processes: a discrete deterministic meanfield approach, Physica D, 222, 2006, pp. 1-20.
[7] Dosmakanbetova A., Methodology of Calculating and Designing the Sublimation-Condensation Apparatuses for Ultrafine Powders Production, PhD Thesis, State University of South Kazakhstan, 2010.