Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33123
Study of Sugarcane Bagasse Pretreatment with Sulfuric Acid as a Step of Cellulose Obtaining
Authors: Candido. R.G., Godoy, G.G., Gonçalves, A.R
Abstract:
To produce sugar and ethanol, sugarcane processing generates several agricultural residues, being straw and bagasse is considered as the main among them. And what to do with this residues has been subject of many studies and experiences in an industry that, in recent years, highlighted by the ability to transform waste into valuable products such as electric power. Cellulose is the main component of these materials. It is the most common organic polymer and represents about 1.5 x 1012 tons of total production of biomass per year and is considered an almost inexhaustible source of raw material. Pretreatment with mineral acids is one of the most widely used as stage of cellulose extraction from lignocellulosic materials for solubilizing most of the hemicellulose content. This study had as goal to find the best reaction time of sugarcane bagasse pretreatment with sulfuric acid in order to minimize the losses of cellulose concomitantly with the highest possible removal of hemicellulose and lignin. It was found that the best time for this reaction was 40 minutes, in which it was reached a loss of hemicelluloses around 70% and lignin and cellulose, around 15%. Over this time, it was verified that the cellulose loss increased and there was no loss of lignin and hemicellulose.Keywords: cellulose, acid pretreatment, hemicellulose removal, sugarcane bagasse
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1082045
Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 4930References:
[1] Cardona, C. A., Quintero, J. A., & Paz, I. C. Production of bioethanol from sugarcane bagasse: Status and perspectives. Bioresource Technology, v.101, 2010, p.4754-4766.
[2] CONAB (Companhia Nacional de Abastecimento). Producão de cana no Brasil terá novo recorde. Available at: http//www. conab.gov.br.
[Accessed Oct 23, 2011].
[3] Edwards B. Energy use in cane and beet factories. Proceedings of the Australian Society of Sugar Cane Technologists,1991. p. 227-9.
[4] Dawson M,Dixon T,Inkerman P. Moisture loss from baled bagasse during storage. Proceedings of the Australian Society of Sugar Cane Technologists,1990. p. 199-206.
[5] Pandey, A., Soccol, C.R., Nigam, P., Soccol, V.T. Biotechnological potential of agro-industrial residues. I: sugarcane bagasse. Bioresource Technology, v. 74, n. 1, 2000, p. 69-80.
[6] Ojeda, K., Ávila, O, Suárez, J., Kafarov, V. Evaluation of technological alternatives for process integration of sugarcane bagasse for sustainable biofuels production -part 1. Chemical Engineering Research and Design, v. 89, n. 3, 2011, p. 270-279.
[7] Zhao, X., Wu, R., Liu, D. Production of pulp, ethanol and lignin from sugarcane bagasse by alkali-peracetic acid delignification. Biomass and Bioenergy, v.35, n.7, 2011, p. 2874-2882.
[8] Fengel, D.; Wegener, G. Wood Chemistry, Ultrastructure, Reactions, Berlin: Walter de Gruyter, 1989.
[9] Klemm, D., Heublein, B., Fink, H.P., Bonh, A. Cellulose: fascinating biopolymer and sustainable raw material. Angewandte Chemie International Edition, v. 44, n.22, 2005, p. 3358-3393.
[10] Canetieri, E., Rocha, G. J. M., de Carvalho, J. R., Silva, J. B. A. Optimization of acid hydrolysis from the hemicellulosic fraction of Eucalyptus grandis residue using response surface methodology. Bioresource Technology, 2007, p.422-8.
[11] Fernandez, N. Pulp and paper development from sugarcane bagasse. In: Third Internacional Non-wood Fiber Pulping and Papermaking Conference, Proceedings, Pequim, v. 1, 1996, p. 231-240.
[12] Marton, G., Dencs, J., Szokonya, L. Principles of biomass refining. In: Handbook of heat and mass transfer. Houston: Gulf Publishing,1989. p. 609-52.
[13] Tsao, G. Ethanol and chemicals from cellulosics. Proceedings of the International Symposium: Alternative Sources of Energy for Agriculture,1984. p. 177-85.
[14] Trickett, R., Neytzell-de Wilde, F. Dilute acid hydrolysis of bagasse hemicellulose. Chemsa, 1982; March: p.11-5.
[15] Youssef, K., Ghareib, M., Nour El Dein, M. Improvement of the biodegredation of some cellulosic wastes by acid pretreatment. Acta Microbiologica Polonica, 1991,p.187-95.
[16] Torget, R., Werdene, P., Himmel, M., Grohmann, K. Dilute acid pretreatment of short rotation woody and herbaceous crops. Applied Biochemistry and Biotechnology, 1990, p.115-26.
[17] El-Taaboulsi, M. ,Nassar, M., Abd El-Rehim, E. A modified method of nitric acid pulping of bagasse. Journal of Chemical Technology and Biotechnology, 1983, p.87-96.
[18] Fontana, J., Corea, J., Duarte, J., Barbosa, A., Blumel, M. Aqueous phosphoric acid hydrolysis of hemicelluloses from sugarcane and sorghum bagasses. Biotechnology and Bioengineering Symposium No. 14, 1984. p. 175-85.
[19] Springer. Hydrolysis of aspenwood xylan with aqueous solutions of hydrochloric acid. TAPPI Journal, 1966, p.102-6.
[20] Rocha, G. J. M., Silva, F. T., Ara├║jo, G. T., Curvelo, A. A. S. A fast and accurate method for determination of cellulose and polyoses by HPLC. In: Brazilian Symposium on the chemistry of Lignin and Other Wood Components, Curitiba. Proceedings, v.5, 1997.
[21] G ouveia, E. R.; Nascimento, R. T.; Souto-maior, A. M.; Rocha, G. J. M. Validação de metodologia para a caracterização química de bagaço de cana-de-açúcar. Química Nova, 2009, p.1-4.
[22] Koga, M, E. T. Cellulose and paper. Technology of celullosic pulp production. São Paulo: IPT, Senai, v.1, Ed. 2, 1998.
[23] B. P. Lavarack,G. J. Griffin, D. Rodman. The acid hydrolysis of sugarcane bagasse hemicellulose to produce xylose, arabinose, glucose and other products. Biomass and Bioenergy. v. 23, 2002, p.367-380.
[24] Trickett, R. Utilisation of bagasse for the production of C5-and C6- sugar,Masters thesis,University of Natal,Durban, 1984.
[25] Koukios, E., Sidiras, D. The role of pre-hydrolysis in refining lignocellulosic biomass. Cellulose Chemistry and Technology. 1995, p. 435-50.
[26] Szokonya, L., Marton, G., Havas-Dencs, J., Kovacs, M. Chemical processing of biomass I- Production of D-xylose by acidic hydrolysis of plant materials. Hungarian Journal of Industrial Chemistry. 1988, p.11- 20.