Experimental Study of Adsorption Properties of Acid and Thermal Treated Bentonite from Tehran (Iran)
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33090
Experimental Study of Adsorption Properties of Acid and Thermal Treated Bentonite from Tehran (Iran)

Authors: H. R. Moghadamzadeh, M. Naimi, H. Rahimzadeh, M. Ardjmand, V. M. Nansa, A. M. Ghanadi

Abstract:

The Iranian bentonite was first characterized by Scanning Electron Microscopy (SEM), Inductively Coupled Plasma mass spectrometry (ICP-MS), X-ray fluorescence (XRF), X-ray Diffraction (XRD) and BET. The bentonite was then treated thermally between 150°C-250°C at 15min, 45min and 90min and also was activated chemically with different concentration of sulphuric acid (3N, 5N and 10N). Although the results of thermal activated-bentonite didn-t show any considerable changes in specific surface area and Cation Exchange Capacity (CEC), but the results of chemical treated bentonite demonstrated that such properties have been improved by acid activation process.

Keywords: Acid activation, Bentonite, CEC, Thermal activation.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1081145

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 2843

References:


[1] L. Fusova, "modification of the structure of Ca-Montmorillonite" GeoScience Engineering, vol. LV, 2009, pp. 27-32.
[2] M. Önal, Y. Sarıkaya, "Preparation and characterization of acidactivated bentonite powders" Powder Technology. Vol. 172, 2007, pp.14-18.
[3] Y.H. Shen, "Preparation of organobentonite using nonionic surfactants" Chemosphere, vol. 44, 2001, pp. 989-995.
[4] M. onal, "physicochemical properties of bentonites: an overview" Commun. Fac. Sci. univ. Ank, 2006,, pp.7-14.
[5] T. Voronchak, I. Nykulyshyn, Z. Pikh, A. Rypka, "Application of clays to treatment of tannery sewages" Desalination, Vol.185, 2005, pp.419- 426.
[6] B. Lombardi, M. Baschini, R.M. Torres Sanchez, "Characterization of Montmorillonites from bentonite deposits of north PATAGONIA, ARGEBTINA: physicochemical and structural parameter correlation" Jornal of Argentine Chemical Society, Vol. 90, 2002, pp.87-99.
[7] R.J. Trauger, "the structure, properties, and analysis of bentonite in geosynthetic clay liners," Colloid Environmental Technologies, 1994.
[8] W. Zhansheng, L. Chun, S. Xifang, U. Xiaolin, D.L. Jin, Z. Hongsheng, "Characterization, Acid Activation and Bleaching Performance of Bentonite from Xinjiang" Chinese J. Chem. Eng., vol. 14, 2006, pp. 253- 258.
[9] H. Noyan , M. Onal, Y. Sar─▒kaya, "The effect of sulphuric acid activation on the crystallinity, surface area, porosity, surface acidity, and bleaching power of a bentonite" Food Chemistry, vol. 105, 2007, pp. 156-163.
[10] H. Murray, "Traditional and new applications for kaolin, smectite and palygorskite: A general overview" Applied Clay Science, Vol. 17, 2000, pp. 207-221.
[11] T. Voronchak, I. Nykulyshyn, Z. Pikh, A. Rypka, "Activated palygordkite and activated bentonite clay as the catalysts of the process of cooligomers obtaining from ethylene productions byproducts" Chemistry and Chemical Technology, Vol.6, 2012, pp.189-198.
[12] N. Stanković, M. Logar, J. Luković, J. Pantić, M. Miljević, B. Babić, A. Radosavljević-Mihajlović, "Characterization of bentonite clay from GREDA deposit" Processing and Application of Ceramics, Vol. 5, 2011, pp.97-101.
[13] J.J. Camberato, "Cation Exchange Capacity-everything you want to know more" Clemson University, Crop and Soil Environmental Science, 2001, pp. 1-4.
[14] M. onal, "changes in crystal structure, thermal behavior and surface area of a bentonite by acid activation" Commun. Fac. Sci. Univ. Ank. Series B, Vol. 53, 2007, pp.1-14.
[15] R. Francisco, V. Díaz, P, Souza Santos, "studies on the acid Activation of Brazilian smectites clays" Quim. Nova., Vol. 24, 2001, pp. 345-353.
[16] J. Temuujin, Ts. Jadambaa, G. Burmaa, Sh. Erdenechimeg , J. Amarsanaa, K. J. D. MacKenzie, "Characterisation of acid activated montmorillonite clay from Tuulant (Mongolia)" Ceramics International, Vol. 30, 2004, pp.251-255.
[17] U. Flessner, D.J. Jones, J. Rozière, J. Zajac, L. Storaro, M. Lenarda, M. Pavan, A. Jiménez-L├│pez, E. Rodr─▒╠üguez-Castell├│n, M. Trombetta, G. Busca, "A study of the surface acidity of acid-treated Montmorillonite clay catalysts" Molecular Catalysis A:Chemical, Vol. 168, 2001, pp. 247-256