Adjusting the Furnace and Converter Temperature of the Sulfur Recovery Units
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Adjusting the Furnace and Converter Temperature of the Sulfur Recovery Units

Authors: Hamid Reza Mahdipoor, Hamid Ganji, Hamed Naderi, Hajar Yousefian, Hooman Javaherizadeh

Abstract:

The modified Claus process is commonly used in oil refining and gas processing to recover sulfur and destroy contaminants formed in upstream processing. A Claus furnace feed containing a relatively low concentration of H2S may be incapable of producing a stable flame. Also, incomplete combustion of hydrocarbons in the feed can lead to deterioration of the catalyst in the reactors due to soot or carbon deposition. Therefore, special consideration is necessary to achieve the appropriate overall sulfur recovery. In this paper, some configurations available to treat lean acid gas streams are described and the most appropriate ones are studied to overcome low H2S concentration problems. As a result, overall sulfur recovery is investigated for feed preheating and hot gas configurations.

Keywords: Sulfur recovery unit, Low H2S content

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1054960

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References:


[1] Elsner, M. P., Menge, M., M├╝ller, C., Agar, D. W., The Claus process: teaching an old dog new tricks, Catalysis Today 79-80 (2003) 487-494.
[2] H. Fisher, Burner/Fire box design improves sulphur recovery, Hydrocarbon processing (1974 OCT.) 27-30.
[3] ZareNezhad, B., An investigation on the most important influencing parameters regarding the selection of the proper catalysts for Claus SRU converters, J. Ind. Eng. Chem. 15 (2009) 143-147.
[4] Hawboldt, K. A.; Monnery, W. D.; Svrcek, W. Y. A Study on the Effect of Quench Design on the Quality of Experimental Data. Ind. Eng. Chem. Res. 1999, 38 (6), 2260-2263.
[5] Hawboldt, K. A.; Monnery, W. D.; Svrcek, W. Y. New Experimental Data and Kinetic Rate Expression for H2S Cracking and Re-Association. Chem. Eng. Sci. 1999, 55 (5), 957-966.
[6] Monnery, W. D., Hawboldt, K. A., Pollock, A. E. and Svrcek, W. Y., Ammonia Pyrolysis and Oxidation in the Claus Furnace, Ind. Eng. Chem. Res. 2001, 40, 144-151.
[7] Paskall, H. G. Capabilityof theModified-C1ausProcess; Department of Energy and Natural Resources: Edmonton, Alberta, Canada, 1979; Chapter IV.
[8] Dowling, N. I., Hyne, J. B., and Brown, D. M., Kinetics of the Reaction between Hydrogen and Sulfur under High-Temperature Claus Furnace Conditions, Ind. Eng. Chem. Res. 1990, 29, 2327-2332.
[9] Mahdipoor, H. R., Khorsand, K., Hayati, R., Javaherizadeh, H., Effect of Reaction Furnace and Converter Temperatures on Performance of Sulfur Recovery Units (SRUs), Journal of Petroleum Science Research, accepted to published, 2012.
[10] McIntyre, G., Lyddon, L., Claus Sulphur Recovery Options, Bryan Research and Engineering, Inc. Technical Papers, Bryan, Texas.
[11] Baehr, H. Gas Purification by the I.G. Alkacid Process and Sulfur Recovery by the I.G. Claus Process. Refin. Nut. Gasoline Manuf. 1938, 17, 237-244.
[12] Gas Processors Suppliers Association (GPSA). Engineering Data Book; GPSA Tulsa, 1987; Chapter 22.
[13] Sames, J., Sulfur recovery process fundamental, Technical paper, Sulfur experts Inc.
[14] Huisman H.M., P. van der Berg, R. Mos, A.J. van Dillen, and J.W. Geus, Hydrolysis of Carbon Sulfides on Titania and Alumina Catalysts: The Influence of Water, Applied Catalysis A, 115 (1994) 157-172.
[15] Laperdrix, E., I. Justin, G. Costentin, 0. Saur, J.C. Lavalley, A. Aboulayt, J.L. Ray, and C. Nedez, Comparative Study of CS2 Hydrolysis Catalyzed by Alumina and Titania, Applied Catalysis B: Environment, 17 (1998) 167-173.
[16] Gens, T.A., Decrease in Carbonyl Sulfide in the Feed to Claus Converters by Shift Catalysts, Ind. Eng. Chem. Res. 33 (1994) 1654- 1656.
[17] Paskall, H.G.: ┬ÀReaction Furnace Chemistry and Operational Modes┬À Proceedings of Gas SWeetening and Sulphur Recovery Seminar, Comprimo/Western Research, Amsterdam (November, 1982).
[18] Sames, J.A., Dale, P.R., Wong, B.: ┬ÀEvaluation of Reaction Furnace Variables in Modified-Claus Plants┬À Proceedings of Lawrence Reid Gas Conditioning Conference, Norman, Oklahoma, (March, 1987).
[19] Puchyr, D.M J., A.K Mehrotra, LA Behie, and N. Kalogerakis, Hydrodynamic and Kinetic Modeling of Circulating Fluidized Bed Reactors Applied to a Modified Claus Plant, Chem. Eng. Sci. 51 (1996) 5251-5262.
[20] Maadah, A.G. and R.N. Maddox, Predict Claus Product, Hydrocarbon Processing 57 (1978) 143-146.
[21] Burns, R.A., R.B Lippert, and R.K. Kerr, Choose Catalyst Objectively, Hydrocarbon Processing, 53 (1974) 181-186.
[22] George, Z.M., Effect of Catalyst Basicity for COS, SO2 and COS Hydrolysis Reactions, J. catalysis, 35 (1974) 218-224.
[23] Terorde, R.J.A.M., PJ. van den Brink, L.M. Visser, A.J. van Dillen, and G.W. Geuss, Selective Oxidation of Hydrogen Sulfide to Elemental Sulfur Using Iron Oxide Catalysts on Various Supports, Catalysis Today 17 (1993) 217-224.
[24] Berben, P.H., Ph.D. Thesis, University of Utrecht, The Netherlands, 1992.