Use of Zeolite and Surfactant Modified Zeolite as Ion Exchangers to Control Nitrate Leaching

Authors: R. Malekian, J. Abedi-Koupai, S. S. Eslamian

Abstract:

Nitrogen loss from irrigated cropland, particularly sandy soils, significantly contributes to nitrate (NO3 -) levels in surface and groundwaters. Thus, it is of great interest to use inexpensive natural products that can increase the fertilizer efficiency and decrease nitrate leaching. In this study, the ability of natural Iranian zeolite clinoptilolite (Cp) and surfactant modified zeolite clinoptilolite (SMZ) to remove NH4 + and NO3 -, respectively, from aqueous solutions was determined. The feasibility of using Cp and SMZ as soil amendment to reduce nitrate leaching from soil using lysimeters was also investigated. Zeolite showed 10.23% to 88.42% NH4 + removal efficiency over a wide range of initial NH4 + concentrations. Nitrate removal efficiency by SMZ was 32.26% to 82.26%. Field study results showed that Cp and SMZ significantly (p < 0.05) reduced leachate NO3-N concentration compared to control. There was no significant difference between maximum and mean leachate NO3-N concentration of SMZ lysimeters and those of Cp lysimeters.

Keywords: Ammonium removal, Leaching, Nitrate removal, Surfactant modified zeolite

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1079354

References:

[1] Z. Li. "Use of surfactant-modified zeolite as fertilizer carriers to control nitrate release," Microporous Mesoporous Mater., vol. 61, no. 1-3, pp. 181-188, 2003.
[2] L. Fewtrell. "Drinking-water nitrate, methemoglobinemia, and global burden of disease: A discussion," Environ. Health Perspect., vol. 112, no. 14, pp. 1371-1374, 2004.
[3] H. Kirchmann, A. E. J. Johnston, and L. F. Bergstrom. "Possibilities for reducing nitrate leaching from agricultural land," Ambio, vol. 31, no. 5, pp. 404-408, 2002.
[4] B. A. Kilfoy, M. H. Ward, T. Z. Zheng, T. R. Holford, P. Boyle, P. Zhao, M. Dai, B. Leaderer, and Y. W. Zhang. "Risk of non-Hodgkin lymphoma and nitrate and nitrite from the diet in Connecticut women," Cancer Cause Control, vol. 21, no. 6, pp. 889-896, 2010.
[5] F. A. Mumpton. "La roca magica: Uses of natural zeolites in agriculture and industry," in Proc. of the National Academy of Sciences of the United States of America, 1999, pp. 3463-3470.
[6] G. M. Haggerty, and R. S. Bowman. "Sorption of chromate and other inorganic anions by organo-zeolite," Environ. Sci. Technol., vol. 28, no. 3, pp. 452-458, 1994.
[7] Z. H. Li, and R. S. Bowman. "Counterion effects on the sorption of cationic surfactant and chromate on natural clinoptilolite," Environ. Sci. Technol., vol. 31, no. 8, pp. 2407-2412, 1997.
[8] P. F. Zhang, D. M. Avudzega, and R. S. Bowman. "Removal of perchlorate from contaminated waters using surfactant-modified zeolite," J. Environ. Qual., vol. 36, no. 4, pp. 1069-1075, 2007.
[9] R. S. Bowman, G. M. Haggerty, R. G. Huddleston, D. Neel, and M. Flynn. "Sorption of nonpolar organics, inorganic cations, and inorganic anions by surfactant-modified zeolites," in: Surfactant-enhanced remediation of subsurface contamination, ACS Symposium Series 594, D. A. Sabatini, R. C. Knox, and J. H. Harwell, Eds. Washington, DC: American Chemical Society, 1995, pp. 54-64.
[10] P. Chutia, S. Kato, T. Kojima, and S. Satokawa. "Adsorption of As(V) on surfactant-modified natural zeolites," J. Hazard. Mater., vol. 162, no. 1, pp. 204-211, 2009.
[11] H. D. Chapman. "Cation exchange capacity," in: Method of Soil Analysis, C.A. Black Ed. Madison, Wisc: SSSA, 1965, pp. 891-901.
[12] D. W. Ming, and J. B. Dixon. "Quantitative determination of clinoptilolite in soils by a cation-exchange capacity method " Clays Clay Miner., vol. 35, no. 6, pp. 463-468, 1987.
[13] Z. Li, R. Beachner, Z. Mcmanama, and H. Hanlic. "Sorption of arsenic by surfactant-modified zeolite and kaolinite," Microporous Mesoporous Mater., vol. 105, no. 3, pp. 291-297, 2007.
[14] D. R. Keeney, and D. W. Nelson. "Nitrogen inorganic forms," in: Methods of Soil Analysis, 2nd ed. part 2, vol. 9, A. L. Page, Ed. Madison, Wisc: American Society of Agronomy, 1982, pp. 643-698.
[15] L. C. Lei, X. J. Li, and X. W. Zhang. "Ammonium removal from aqueous solutions using microwave-treated natural Chinese zeolite," Sep. Purif. Technol., vol. 58, no. 3, pp. 359-366, 2008.
[16] R. G. Allen, L. S. Pereira, D. Raes, and M. Smith, Crop evapotranspiration - Guidelines for computing crop water requirements. Rome: FAO Irrigation and drainage, paper 56, 1998.
[17] H. Huang, X. Xiao, B. Yan, and L. Yang. "Ammonium removal from aqueous solutions by using natural Chinese (Chende) zeolite as adsorbent," J. Hazard. Mater., vol. 175, no. 1-3, pp. 247-252, 2010.
[18] M. L. Nguyen, and C. C. Tanner. "Ammonium removal from wastewaters using natural New Zealand zeolites," New Zeal. J. Agr. Res., vol. 41, no. 3, pp. 427-446, 1998.
[19] D. Karadag, Y. Koc, M. Turan, and B. Armagan. "Removal of ammonium ion from aqueous solution using natural Turkish clinoptilolite," J. Hazard. Mater., vol. 136, no. 3, pp. 604-609, 2006.
[20] D. Steffens, and D. L. Sparks. "Kinetics of nonexchangeable ammonium release from soils," Soil Sci. Soc. Am. J., vol. 61, no. 2, pp. 455-462, 1997.
[21] H. W. Martin, and D. L. Sparks. "Kinetics of Nonexchangeable Potassium Release from Two Coastal Plain Soils," Soil Sci. Soc. Am. J., vol. 47, no. 5, pp. 883-887, 1983.
[22] Z. H. Li, I. Anghel, and R. S. Bowman. "Sorption of oxyanions by surfactant-modified zeolite," J. Dispers. Sci. Technol., vol. 19, no. 6-7, pp. 843-857, 1998.
[23] M. J. Semmens. "Cation-exchange properties of natural zeolite. pp. 45- 54. In: W.G. Pond and F.A. Mumpton (eds.), Zeo-Agriculture: Use of Natural Zeolites in Agriculture and Aquaculture " Westview Press, Boulder, CO, vol., 1984.
[24] C. T. Mackown, Role of mineral zeolites as soil amendments 1978, University of Arizona: Tuscon.
[25] EPA. Quality criteria for water, Rep. EPA 440/5-86-001. USEPA. Washington, DC., 1986.