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Efficient Preparation and Characterization of Carbohydrate Based Monomers. D-mannose Derivatives

Authors: L. M. Stefan, A. M. Pana, M. Silion, M. Balan, G. Bandur, L. M. Rusnac

Abstract:

The field of polymeric biomaterials is very important from the socio-economical viewpoint. Synthetic carbohydrate polymers are being increasingly investigated as biodegradable, biocompatible and biorenewable materials. The aim of this study was to synthesize and characterize some derivatives based on D-mannose. D-mannose was chemically modified to obtain 1-O-allyl-2,3:5,6-di- O-isopropylidene-D-mannofuranose and 1-O-(2-,3--epoxy-propyl)- 2,3:5,6-di-O-isopropylidene-D-mannofuranose. The chemical structure of the resulting compounds was characterized by FT-IR and NMR spectroscopy, and by HPLC-MS.

Keywords: Synthesis, Spectroscopy, Biopolymers, D-mannose

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1076638

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References:


[1] G. Swift, "Opportunities for Environmentally Degradable Polymers", Journal of Macromolecular Science, Part A, 32:4, 1995, pp. 641-651.
[2] J. P. Jain, M. Sokolsky, N. Kumar and A.J. Domb, "Fatty Acid Based Biodegradable Polymer", Polymer Reviews, 48:1, 2008, pp. 156-191.
[3] A. Steinb├╝chel, "Use of Biosynthetic, Biodegradable Thermoplastics and Elastomers from Renewable Resources: The Pros and Cons", Journal of Macromolecular Science, Part A, 32:4, 1995, pp. 653-660.
[4] M. Khalid, C. T. Ratnam, C.A Luqman, A. Salmiaton, T.S.Y. Choong, and H. Jalaludin, "Thermal and Dynamic Mechanical Behavior of Cellulose- and Oil Palm Empty Fruit Bunch (OPEFB)-Filled Polypropylene Biocomposites", Polymer-Plastics Technology and Engineering, 48:12, 2009 pp. 1244-1251.
[5] S. G. Tan, W. S. Chow, "Biobased Epoxidized Vegetable Oils and Its Greener Epoxy Blends: A Review", Polymer-Plastics Technology and Engineering, 49:15, 2010, pp. 1581-1590.
[6] X. L. Wang, K. K. Yang, and Y. Z. Wang, "Properties of Starch Blends with Biodegradable Polymers", Polymer Reviews, 43:3, 2003, 385-409.
[7] M. Okada, "Molecular design and synthesis of glycopolymers", Progress In Polymer Science, 26, 2001, pp. 67-104.
[8] V. Ladmiral, E. Melia, D. M. Haddleton, "Synthetic glycopolymers: An overview", European Polymer Journal, 40, 2004, pp. 431-449.
[9] A. M. Pana, L. Rusnac, G. Bandur, E. ┼×i┼ƒu, V. Badea, M. Silion, "Synthesis and Characterization of New Glycopolymers Based on Monosachharides and Maleic Anhydride I. Glucose derivatives", Materiale Plastice, Bucure┼ƒti, 47(1),.2010.
[10] S. Hanessian, Preparative Carbohydrate Chemistry, CRC Press, 1997, pp. 8-19.
[11] V. K. Rajput, B. Mukhopadhyay, Tetrahedron Letters, 47, 2006, pp. 5939.
[12] H. M .I. Osborn, Academic Press, 2002, pp. 50.
[13] A. M. Pana, L. Rusnac, G. Bandur, C. Deleanu, M. Balan, M. Silion, "Synthesis and Characterization of New Glycopolymers Based on Monosachharides and Maleic Anhydride II. Mannose derivatives", Materiale Plastice, Bucureşti, 47(3),.2010.