Sensing Characteristics to Acid Vapors of a TPPS Coated Fiber Optic: A Preliminary Analysis
Authors: A. Bahrampour, A. Iadicicco, G. De Luca, M. Giordano, A. Cutolo, L. Monsù Scolaro, A. Cusano
Abstract:
In this work we report on preliminary analysis of a novel optoelectronic gas sensor based on an optical fiber integrated with a tetrakis(4-sulfonatophenyl)porphyrin (TPPS) thin film. The sensitive materials are selectively deposited on the core region of a fiber tip by UV light induced deposition technique. A simple and cheap process which can be easily extended to different porphyrin derivatives. When the TPPS film on the fiber tip is exposed to acid and/or base vapors, dramatic changes occur in the aggregation structure of the dye molecules in the film, from J- to H-type, resulting in a profound modification of their corresponding reflectance spectra. From the achieved experimental results it is evident that the presence of intense and narrow band peaks in the reflected spectra could be monitored to detect hazardous vapors.
Keywords: Optical fiber sensor, Porphyrins, Thin films UV induced deposition, TPPS.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1075784
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[1] Kim R. Rogers, and Llewellyn R. Williams, "Biosensors for environmental monitoring: a regulatory perspective," TrAC Trends in Analytical Chemistry, vol. 14, n. 7, pp. 289-294, 1995
[2] J. W. Grate and M. H. Abraham, "Solubility interaction and design of chemically selective sorbent coatings for chemical sensor and arrays," Sens. Actuators B, Chem., vol. 3, no. 2, pp. 85-111, Feb 1991.
[3] M. Penza, G. Cassano, P. Aversa, F. Antolini, A. Cusano, M. Consales, M. Giordano, and L. Nicolais, "Carbon nanotubes coated multitransducing sensors for VOCs detection," Sens. Actuators B, Chem., vol. 111/112, pp. 171-180, Nov. 11, 2005.
[4] M. Giordano, M. Russo, A. Cusano, G. Mensitieri, and G. Guerra, "Syndiotactic polystyrene thin film as sensitive layer for an optoelectronic chemical sensing device," Sens. Actuators B, Chem., vol. 109, no. 2, pp. 177-184, Sep. 2005.
[5] M. Giordano, M. Russo, A. Cusano, A. Cutolo, G. Mensitieri, and L. Nicolais, "Optical sensor based on ultrathin films of ╬┤-form syndiotactic polystyrene for fast and high resolution detection of chloroform," Appl. Phys. Lett., vol. 85, no. 22, pp. 5349-5351, Nov 2004.
[6] A. Cusano, P. Pilla, L. Contessa, A. Iadicicco, S. Campopiano, A. Cutolo, M. Giordano, "High Sensitivity Optical Chemo-Sensor Based on Coated Long Period Gratings for Sub ppm Chemical Detection in Water", Applied Physic Letters, vol. 87, 234105, December 2005.
[7] S. H. Lim, ,L. Feng, J. W. Kemling,, C. J. Musto,and K. S. Suslick, "An Optoelectronic Nose for Detection of Toxic Gases," Nature Chemistry, vol. 1, pp. 562-567, 2009
[8] Giovanna De Luca, Gianmichele Pollicino, Andrea Romeo, and Luigi Mons├╣ Scolaro, "Sensing Behavior of Tetrakis(4- sulfonatophenyl)porphyrin Thin Films," Chem. Mater., vol. 18 no. 8, pp. 2005-2007, 2006.
[9] MO. Senge, M. Fazekas, EGA. Notaras, WJ. Blau, M. Zawadzka, and OB. Locos, and EM. Ni Mhuircheartaigh, "Nonlinear Optical Properties of Porphyrins", Advanced Materials, vol. 19, pp. 2737-2774, Oct 2007
[10] K. M. Kadish, K. M. Smith, R. Eds, Guilard, The Porphyrin Handbook. New York: Academic Press, 2000, vol. 6
[11] Koiti Araki, Michael J. Wagner, and Mark S. Wrighton, "Layer-by- Layer Growth of Electrostatically Assembled Multilayer Porphyrin Films," Langmuir, vol. 12, pp. 5393-5398, 1996.
[12] Zhijun Zhang, Ruisheng Hu, and Zhongfan Liu, "Formation of a Porphyrin Monolayer Film by Axial Ligation of Protoporphyrin IX Zinc to an Amino-Terminated Silanized Glass surface", Langmuir, vol. 16, pp. 537, 2000.
[13] Luigi Mons├╣ Scolaro,Andrea Romeo, Maria Angela Castriciano,Giovanna De Luca, Salvatore Patanè, and Norberto Micali, "Porphyrin Deposition Induced by UV Irradiation," J. Am. Chem. Soc., vol. 125 (8), pp. 2040-2041, 2003
[14] Xiao-Bing Zhanga, Zhi-Zhang Lib, Can-Cheng Guoa, Si-Hai Chena, Guo-Li Shena, and Ru-Qin Yua, "Porphyrin-metalloporphyrin composite based optical fiber sensor for the determination of berberine,", Analytica Chimica Acta, vol. 439, pp. 65-71, July 2001.
[15] Rong Ni, Rong-Biao Tong, Can-Cheng Guo, Guo-Li Shen, Ru-Qin Yu, "An anthracene/porphyrin dimer fluorescence energy transfer sensing system for picric acid," Talanta, vol. 63, pp. 251-257, May 2004.
[16] George Huyang, John Canning, Mattias L. Åslund, Danial Stocks, Tony Khoury, and Maxwell J. Crossley , "Evaluation of optical fiber microcell reactor for use in remote acid sensing," Optics Letters, vol. 35, pp. 817- 819, 2010
[17] Selyanchyn, Roman, Korposh Sergiy, Yasukochi Wataru, and Lee Seung-Woo, "A preliminary test for skin gas assessment using a porphyrin based evanescent wave optical fiber Sensor," Sensors & Transducers, vol. 125, no. 2, pp.54-67, Feb 2011.
[18] A. P. H. J. Schenning, F. B. G. Benneker, H. P. M. Geurts, X. Y. Liu, and R. J. M. Nolte, "Porphyrin Wheels," J. Am. Chem. Soc., vol. 118, no. 36, pp. 8549, 1996.
[19] Giovanna De Luca,Giamichele Pollincino,Andrea Romeo,Salvatore Patane, and Luigi Monsu Scolaro, "Control over the Optical and Morphological Properties of UV-Deposited Porphyrin Structures," Chem. Mater, vol. 18, pp. 5429, 2006.
[20] RF. Pasternack, and PJ. Collings, "Resonance light scattering: a new technique for studying chromophore aggregation," Science, vol. 269, no. 5226, pp. 935-935, 1995