Study the Effect of Rubbery Phase on Morphology and Rheology Development of PP/PA6/(EPDM: EPDM-g-MA) Ternary Blends

Authors: B. Afsari, M. Hassanpour, M. Shabani

Abstract:

This study aimed to investigate the phase morphology of ternary blends comprising polypropylene (PP), polyamide 6 (PA6), and a blend of ethylene propylene diene monomer (EPDM) and maleic anhydride-grafted EPDM (EPDM-g-MA) in a 70/15/15 ratio. Varying ratios of EPDM to EPDM-g-MA were examined. As the proportion of EPDM-g-MA increased, an interlayer phase formed between the dispersed PA6 domains and the PP matrix. This resulted in the development of a core-shell encapsulation morphology within the blends. The concentration of the EPDM-g-MA component is inversely correlated with the average size of PA6 particles. Additionally, blends containing higher proportions of the EPDM-g-MA rubbery phase exhibited an aggregated structure of the modifier particles. Notably, as the concentration of EPDM-g-MA increased from 0% to 15% in the blend, there was a consistent monotonic reduction in the size of PA6 particles.

Keywords: Phase morphology, rheology, rubbery phase, rubber functionality, ternary blends.

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