Development of Environment Friendly Mimosa Tannin-Cornstarch Based Wood Adhesive
Commenced in January 2007
Frequency: Monthly
Edition: International
Paper Count: 33093
Development of Environment Friendly Mimosa Tannin-Cornstarch Based Wood Adhesive

Authors: Salise Oktay, Nilgün Kızılcan, Başak Bengü

Abstract:

At present, formaldehyde-based adhesives such as urea formaldehyde (UF), melamine formaldehyde (MF), melamine-urea formaldehyde (MUF) etc. are mostly used in wood-based panel industry because of their high reactivity, chemical versatility and economic competitiveness. However, formaldehyde-based wood adhesives are produced from non-renewable resources. Hence, there has been a growing interest in the development of environment friendly, economically competitive, bio-based wood adhesives in order to meet wood-based panel industry requirements. In this study, as formaldehyde free adhesive, tannin and starch-based wood adhesive was synthesized. Citric acid and tartaric acid were used as hardener for the resin system. Solid content, viscosity and gel time analyzes of the prepared adhesive were performed in order to evaluate the adhesive processability. FTIR characterization technique was used to elucidate chemical structures of the cured adhesive samples. In order to evaluate the performance of the prepared bio-based resin formulation, particleboards were produced in laboratory scale and mechanical, physical properties of the boards were investigated. Besides, formaldehyde contents of the boards were determined by using perforator method. The obtained results revealed that the developed bio-based wood adhesive formulation can be a good potential candidate to use in wood-based panel industry with some developments.

Keywords: Wood adhesive, cornstarch, mimosa tannin, particleboard.

Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 413

References:


[1] S. Oktay, N. Kızılcan, B. Bengü, “Development of bio-based cornstarch - Mimosa tannin - sugar adhesive for interior particleboard production,” Ind. Crops Prod., vol. 170, June, 2021.
[2] S. Boran, M. Usta, E. Gümükaya, “Decreasing formaldehyde emission from medium density fiberboard panels produced by adding different amine compounds to urea formaldehyde resin,” Int. J. Adhes. Adhes., vol. 31, pp. 674–678, October, 2011.
[3] A. Moubarik, H.R. Mansouri, A. Pizzi, F. Charrier, A. Allal, B. Charrier, “Corn flour-mimosa tannin-based adhesives without formaldehyde for interior particleboard production,” Wood Sci. Technol., vol. 47, pp. 675–683, July, 2013.
[4] D.A. Perminova, V.S. Malkov, V. Gusсhin, N. Eisenreich, “Influence of glyoxal on curing of urea-formaldehyde resins,” Int. J. Adhes. Adhes., vol. 92, pp. 1–6, July, 2019.
[5] J. Kuusisto, T.C. Maloney, “Preparation and characterization of corn starch–calcium carbonate hybrid pigments, “Ind. Crops Prod., vol. 83, pp. 294–300, May, 2016.
[6] A. Pizzi, “Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues Recent developments in eco-efficient bio-based adhesives for wood bonding: opportunities and issues,” J. Adhes. Sci. Technol vol., 20, pp. 829–846, April, 2012.
[7] G. Tondi, G., “Tannin-Based copolymer resins: Synthesis and characterization by solid state 13C NMR and FT-IR spectroscopy,” Polymers (Basel), vol. 9, June, 2017.
[8] G. Tondi, S. Wieland, T. Wimmer, T. Schnabel, A. Petutschnigg, “Starch-sugar synergy in wood adhesion science: Basic studies and particleboard production,” Eur. J. Wood Wood Prod., vol. 70, pp. 271–278, January, 2012.
[9] Z. Zhao, K. Umemura, K. Kanayama, “Effects of the addition of citric acid on tannin-sucrose adhesive and physical properties of the particleboard,” BioResources, vol. 11, pp. 1319–1333, February, 2016.
[10] X. F. Zhao, L.Q. Peng, H.L. Wang, Y.B. Wang, H. Zhang, “Environment-friendly urea-oxidized starch adhesive with zero formaldehyde-emission,” Carbohydr. Polym., vol, 181, pp. 1112–1118, February, 2018.
[11] F. Han, C. Gao, M. Liu, “Fabrication and characterization of size-controlled starch-based nanoparticles as hydrophobic drug carriers,” J. Nanosci. Nanotechnol. Vol. 13, pp. 6996–7007, October, 2013.
[12] H. Dong, T. Vasanthan, “Amylase resistance of corn, faba bean, and field pea starches as influenced by three different phosphorylation (cross-linking) techniques,” Food Hydrocoll, vol. 101, April 2020.
[13] P.S. Garcia, M.V.E. Grossmann, M.A. Shirai, M.M. Lazaretti, F. Yamashita, C.M.O. Muller, S. Mali, “Improving action of citric acid as compatibiliser in starch/polyester blown films,” Ind. Crops Prod., vol. 52, pp. 305–312, January, 2014.
[14] C. Peña, C., K. De La Caba, A. Retegi, C. Ocando, J. Labidi, J.M. Echeverria, I. Mondragon, “Mimosa and chestnut tannin extracts reacted with hexamine in solution,” J. Therm. Anal. Calorim., vol. 96, pp. 515–521, May, 2009.
[15] H. Gerengi, K. Schaefer, H.I. Sahin, “Corrosion-inhibiting effect of Mimosa extract on brass-MM55 corrosion in 0.5 M H2SO4 acidic media, “J. Ind. Eng. Chem., vol. 18, pp. 2204–2210, October, 2012.
[16] Z. Zhao, Y. Miao, Z. Yang, H. Wang, R. Sang, Y. Fu, C. Huang, Z. Wu, M. Zhang, S. Sun, K. Umemura, Q. Yong, “Effects of sulfuric acid on the curing behavior and bonding performance of tannin-sucrose adhesive,” Polymers (Basel), vol. 10, pp. 1–13, June, 2018.
[17] M. Böhm, M.Z.M. Salem, J. Srba, “Formaldehyde emission monitoring from a variety of solid wood, plywood, blockboard and flooring products manufactured for building and furnishing materials,” J. Hazard. Mater. vol. 221–222, pp. 68–79, June, 2012.
[18] C. Liu, J. Luo, X. Li, Q Gao, J. Li, “Effects of Compounded Curing Agents on Properties and Performance of Urea Formaldehyde Resin,” J. Polym. Environ., vol. 26, pp. 158–165, January, 2017.