Fracture Toughness Properties and FTIR Analysis of Corn Fiber Green Composites
Authors: Ahmed Mudhafar Hashim, Aseel Mahmood Abdullah
Abstract:
The present work introduced a green composite consisting of corn natural fiber of constant concentration of 10% by weight incorporation with poly methyl methacrylate matrix biomaterial prepared by hand lay-up technique. Corn natural fibers were treated with two concentrations of sodium hydroxide solution (3% and 5%) with different immersed time (1.5 and 3 hours) at room temperature. The fracture toughness test of untreated and alkali treated corn fiber composites were performed. The effect of chemically treated on fracture properties of composites has been analyzed using Fourier transform infrared (FTIR) spectroscopy. The experimental results showed that the alkali treatment improved the fracture properties in terms of plane strain fracture toughness KIC. It was found that the plane strain fracture toughness KIC increased by up to 62% compared to untreated fiber composites. On the other hand, increases in both concentrations of alkali solution and time of soaking to 5% NaOH and 3 hours, respectively reduced the values of KIC lower than the value of the unfilled material.
Keywords: green composites, fracture toughness, corn natural fiber, Bio-PMMA
Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 544References:
[1] C. V. Srinivasa, and K. N. Bharath, “Impact and hardness properties of areca fiber-epoxy composites”, J. Mater. Sci. 2(4), 2011, pp. 351–356.
[2] Rokbi M., Osmani H., Imad A., and Benseddiq N., “Effect of chemical treatment on flexural properties of natural fiber-reinforced polyester composite”, Procedia Engineering, 2011, 10, pp. 2092–2097.
[3] Cao Y., Shibata S., and Fukumoto I., “Mechanical properties of biodegradable composites reinforced with bagasse fibre before and after alkali treatments”, Composites: Part A, 2006, 37, pp. 423–429.
[4] Priscila Ferreira de Oliiveira, and Maria de Fatima Vieira Marques, “Chmeical treatment of natural malva fibers and preparation of green composites with poly(3-hydroxybutyrate)”, Chemical technology, Vol. 9, No. 2, 2015.
[5] Samir Kumar Acharya, Punyapriya Mishraand, and Suraj Kumar Mehar, “Effect of surface treatment on the mechanical properties of bagasse fiber reinforced polymer composite”, BioResources, 6(3), 2011, pp. 3155–3165.
[6] David Arencon, and Jose Ignacio Velasco, “Fracture toughness of polypropylene-based particulate composites”, Materials, 2, 2009, pp. 2046–2094.
[7] M. Hughes, C. A. S. Hill, and J. R. B. Hague, “The fracture toughness of bast fibre reinforced polyester composites”, Part 1: Evaluation and analysis, Journal of materials science, 37, 2002, pp. 4669–4676.
[8] Zhao D., and Bostis J., “Experimental and numerical studies in model composites”, Part I: Experimental results, Int. J. Fract., 82, 1996, pp. 153–174.
[9] Choi N. S., and Takahashi K., “Toughness and microscopic fracture mechanisms of unfilled and short-glass-fiber-filled poly(cyano acrylate)”, J. Mater. Sci., 31, 1996, 31(3), pp. 731–740.
[10] R. V. Silva, D. Spinelli, W. W. Bose Filho, S. Claro Neto, G. O. Chierice, and J. R. Tarpani, “Fracture toughness of natural fibers/castor oil polyurethane composites”, Composites science and technology, 66, 2006, pp. 1328–1335.
[11] Maximilien E. Launey, and Robert O. Ritchie, “On the fracture toughness of advanced materials”, Adv. Mater., 21, 2009, pp. 2103–2110.
[12] Paulo Henrique Fernandes Pereira, Morsyliede de Freitas Rosa, Maria Odila Hilario Cioffi, Kelly Cristina Coelho de Carvalho Benini, Andressa Cecilia Milanese, Herman Jacobus Cornelis Voorwald, and Daniela Regina Mulinari, “Vegetable fibers in polymeric composites: a review” Polimeros, 25(1), 2015, pp. 9-22.
[13] Karnani R., Krishnan M., and Narayan R., “Biofibre-reinforced polypropylene composites”, Polymer Engineering and Science, Vol. 2, 1997, pp. 476-483.
[14] Xue Li, Lope G. Tabil, and Satyanarayan Panigrahi, “Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review”, Journal of Polymer Environment, Vol. 15, 2007, pp. 25–33.
[15] Y. A. El-Shekeil, S. M. Sapuan1, A. Khalina, E. S. Zainudin, and O. M. Al-Shuja’a, “Influence of chemical treatment on the tensile properties of kenaf fiber reinforced thermoplastic polyurethane composite”, Express polymer letters, Vol.6, No.12, 2012, pp.1032–1040.
[16] Emanuel M. Fernandes, João F. Mano, and Rui L. Reis, “Hybrid cork–polymer composites containing sisal fibre: morphology, effect of the fibre treatment on the mechanical properties and tensile failure prediction”, Composite structures, Vol. 105, 2013, pp. 153–162.
[17] Saiful Izwan Abd Razak, Noor Fadzliana Ahmad Sharif and Wan Aizan Wan Abdul Rahman, “Biodegradable Polymers and their Bone Applications: A Review”, International Journal of Basic and Applied Sciences (IJBAS-IJENS), Vol. 12, No. 1, 2012, pp. 31-49.
[18] ASTM International, E 647–2013a, “Standard test method for measurement of fatigue crack growth rates”.