An Investigation of a Three-Dimensional Constitutive Model of Gas Diffusion Layers in Polymer Electrolyte Membrane Fuel Cells
This research presents the three-dimensional mechanical characteristics of a commercial gas diffusion layer by experiment and simulation results. Although the mechanical performance of gas diffusion layers has attracted much attention, its reliability and accuracy are still a major challenge. With the help of simulation analysis methods, it is beneficial to the gas diffusion layer’s extensive commercial development and the overall stress analysis of proton electrolyte membrane fuel cells during its pre-production design period. Therefore, in this paper, a three-dimensional constitutive model of a commercial gas diffusion layer, including its material stiffness matrix parameters, is developed and coded, in the user-defined material model of a commercial finite element method software for simulation. Then, the model is validated by comparing experimental results as well as simulation outcomes. As a result, both the experimental data and simulation results show a good agreement with each other, with high accuracy.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.2363308Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 829
 J-H. Wee, “Applications of proton exchange membrane fuel cell systems,” Renewable and sustainable energy reviews, vol. 11, pp. 1720-1738, October 2007.
 X. Lü, Y. Qu, Y. Wang, C. Qin, and G. Liu, “A comprehensive review on hybrid power system for PEMFC-HEV: Issues and strategies,” Energ Convers Manage, vol. 171, pp. 1273-1291, September 2018.
 R. K. A. Rasheed, Q. Liao, Z. Caizhi, and S. H. Chan, “A review on modelling of high temperature proton exchange membrane fuel cells (HT-PEMFCs),” Int J Hydrogen Energ, vol. 42, pp. 3142-3165, February 2017.
 V. Mehta and J. S. Cooper, “Review and analysis of PEM fuel cell design and manufacturing,” J Power Sources, vol. 114, pp. 32-53, February 2003.
 D. Liu, L. Peng, and X. Lai, “Effect of dimensional error of metallic bipolar plate on the GDL pressure distribution in the PEM fuel cell,” Int J Hydrogen Energ, vol. 34, pp. 990-997, January 2009.
 D. Qiu, P. Yi, L. Peng, and X. Lai, “Study on shape error effect of metallic bipolar plate on the GDL contact pressure distribution in proton exchange membrane fuel cell,” Int J Hydrogen Energ, vol. 38, pp. 6762-6772, May 2013.
 P. Chippar, K. O, K. Kang, and H. Ju, “A numerical investigation of the effects of GDL compression and intrusion in polymer electrolyte fuel cells (PEFCs),” Int J Hydrogen Energ, vol. 37, pp. 6326-6338, April 2012.
 A. El-kharouf, T. J. Mason, D. J. L Brett, and B. G. Pollet, “Ex-situ characterisation of gas diffusion layers for proton exchange membrane fuel cells”. J Power Sources, vol. 218, pp. 393-404, November 2012.
 J. A. Pelaez and S. G. Kandlikar, “Effects of Freezing and Thawing on the Structures of Porous Gas Diffusion Media”, in ASME 2007 5th International Conference on Nanochannels, Microchannels, and Minichannels, Puela, 2007, pp. 401-408.
 D. Jones, “International Conference on Progress in MEA Materials for Medium and High Temperature Polymer Electrolyte Fuel Cells,” Fuel Cells, vol. 11, pp. 714-714, December, 2011.
 A. Arvay, E. Yli-Rantala, C. H. Liu, et al, “Characterization techniques for gas diffusion layers for proton exchange membrane fuel cells – A review,” J Power Sources, vol. 213, pp. 317-337, September 2012.
 L. Cindrella, A. M. Kannan, J. F. Lin, et al, “Gas diffusion layer for proton exchange membrane fuel cells—A review,” J Power Sources, vol. 194, pp. 146-160, October 2009.
 D. M. Fadzillah, M. I. Rosli, M. Z. M. Talib, S. K. Kamarudin, and W. R. W. Daud, “Review on microstructure modelling of a gas diffusion layer for proton exchange membrane fuel cells,” Renewable and sustainable energy reviews, vol. 77, pp. 1001-1009, September 2017.
 F. Lapicque, M. Belhadj, C. Bonnet, J. Pauchet, and Y. Thomas, “A critical review on gas diffusion micro and macroporous layers degradations for improved membrane fuel cell durability,” J Power Sources, vol. 336, pp. 40-53, December 2016.
 R. Omrani and B. Shabani, “Gas diffusion layer modifications and treatments for improving the performance of proton exchange membrane fuel cells and electrolysers: A review,” Int J Hydrogen Energ, vol. 42, pp. 28515-28536, November 2017.
 J. Park, H. Oh, T. Ha, Y. I. Lee, and K. Min, “A review of the gas diffusion layer in proton exchange membrane fuel cells: Durability and degradation,” Appl Energ, vol. 155, pp. 866-880, October 2015.
 S. Park, J-W Lee, and B. N. Popov, “A review of gas diffusion layer in PEM fuel cells: Materials and designs,” Int J Hydrogen Energ, vol. 37, pp. 5850-5865, April 2012.
 S. R. Dhanushkodi, F. Capitanio, T. Biggs, and W. Mérida, “Understanding flexural, mechanical and physico-chemical properties of gas diffusion layers for polymer membrane fuel cell and electrolyzer systems,” Int J Hydrogen Energ, vol. 40, pp. 16846-16859, December 2015.
 P. A. Gigos, Y. Faydi, and Y. Meyer, “Mechanical characterization and analytical modeling of gas diffusion layers under cyclic compression,” Int J Hydrogen Energ, vol. 40, pp. 5958-5965, May 2015.
 T. J. Mason, J. Millichamp, T. P. Neville, A. El-kharouf, B. G. Pollet, and D. J. L. Brett, “Effect of clamping pressure on ohmic resistance and compression of gas diffusion layers for polymer electrolyte fuel cells,” J Power Sources, vol. 219, pp. 52-59, December 2012.
 V. Radhakrishnan and P. Haridoss, “Effect of cyclic compression on structure and properties of a Gas Diffusion Layer used in PEM fuel cells,” Int J Hydrogen Energ, vol. 35, pp. 11107-11118, October 2010.
 V. Radhakrishnan and P. Haridoss, “Effect of GDL compression on pressure drop and pressure distribution in PEMFC flow field,” Int J Hydrogen Energ, vol. 36, pp. 14823-14828, November 2011.
 Z. Y. Su, C. T. Liu, H. P. Chang, C. H. Li, K. J. Huang, and P. C. Sui, “A numerical investigation of the effects of compression force on PEM fuel cell performance,” J Power Sources, vol. 183, pp. 182-192, August 2008.
 P. Zhou and C. W. Wu, “Numerical study on the compression effect of gas diffusion layer on PEMFC performance,” J Power Sources, vol. 170, pp. 93-100, June 2007.
 V. Mishra, F. Yang, and R. Pitchumani, “Measurement and Prediction of Electrical Contact Resistance Between Gas Diffusion Layers and Bipolar Plate for Applications to PEM Fuel Cells,” J Fuel Cell Sci Tech, vol. 1, pp. 2-9, March 2004.
 M. F. Serincan and U. Pasaogullari, “Effect of gas diffusion layer anisotropy on mechanical stresses in a polymer electrolyte membrane,” J Power Sources, vol. 196, pp. 1314-1320, February 2011.
 P. A. García-Salaberri, M. Vera, and R. Zaera, “Nonlinear orthotropic model of the inhomogeneous assembly compression of PEM fuel cell gas diffusion layers,” Int J Hydrogen Energ, vol. 36, pp. 11856-11870, September 2011.
 S. Li, J. Yuan, M. Andersson, G. Xie, and B. Sundén, “Influence of anisotropic gas diffusion layers on transport phenomena in a proton exchange membrane fuel cell,” International Journal of Energy Research, vol. 41, pp. 2034-2050, May 2017.
 A. H. Mahmoudi, A. Ramiar, and Q. Esmaili, “Effect of inhomogeneous compression of gas diffusion layer on the performance of PEMFC with interdigitated flow field,” Energ Convers Manage, vol. 110, pp. 78-89, February 2016.
 V. Norouzifard and M. Bahrami, “Deformation of PEM fuel cell gas diffusion layers under compressive loading: An analytical approach,” J Power Sources, vol. 264, pp. 92-99, October 2014.
 D. Roylance, “Laminated composite plates”, Massachusetts Institute of Technology CAMBRIDGE, Cambridge Mass, 2000.
 N. Khajeh-Hosseini-Dalasm, T. Sasabe, T. Tokumasu, and U. Pasaogullari, “Effects of polytetrafluoroethylene treatment and compression on gas diffusion layer microstructure using high-resolution X-ray computed tomography,” J Power Sources, vol. 266, pp. 213-221, November 2014.
 J. Kleemann, F. Finsterwalder, and W. Tillmetz,” Characterisation of mechanical behaviour and coupled electrical properties of polymer electrolyte membrane fuel cell gas diffusion layers,” J Power Sources, vol. 190, pp. 92-102, May 2009.
 K. K. Poornesh, Y-J Sohn, G-G Park, and Yang T-H, “Gas-diffusion layer's structural anisotropy induced localized instability of nafion membrane in polymer electrolyte fuel cell,” Int J Hydrogen Energ, vol. 37, pp. 15339-15349, October 2012.
 X. Peng and J. Cao, “A dual homogenization and finite element approach for material characterization of textile composites,” Composites Part B: Engineering, vol. 33, pp. 45-56, January 2002.
 J. Zhang, N. Kikuchi, V. Li, A. Yee, and G. Nusholtz, “Constitutive modeling of polymeric foam material subjected to dynamic crash loading,” International Journal of Impact Engineering, vol. 21, pp. 369-86, May 1998.
 K. K. Poornesh, C. Cho, and A. M. Rego, “Anisotropic Distribution of Elastic Constants in Fuel Cell Gas Diffusion Layers: Experimental Validation,” Energy and Power, vol. 5, pp. 40-45, 2015.