Synthesis of Mg/B Containing Compound in a Modified Microwave Oven
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Synthesis of Mg/B Containing Compound in a Modified Microwave Oven

Authors: Gülşah Çelik Gül, Figen Kurtuluş


Magnesium containing boron compounds with hexagonal structure have been drawn much attention due to their superconductive nature. The main target of this work is new modified microwave oven by on our own has an ability about passing through a gas in the oven medium for attainment of oxygen-free compounds such as c-BN.  Mg containing boride was synthesized by modified-microwave method under nitrogen atmosphere using amorphous boron and magnesium source in appropriate molar ratio. Microwave oven with oxygen free environment has been modified to aimed to obtain magnesium boride without oxygen. Characterizations were done by powder X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. Mg containing boride, generally named magnesium boride, with amorphous character without oxygen is obtained via designed microwave oven system.

Keywords: Magnesium containing boron compounds, modified microwave synthesis, powder X-ray diffraction, FTIR.

Digital Object Identifier (DOI):

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[1] Jones, M. E. and Marsh R. E. (1954). "The Preparation and Structure of Magnesium Boride, MgB2". Journal of the American Chemical Society 76: 1434–1436.
[2] Nagamatsu, J., Nakagawa N., Muranaka T., Zenitani Y., Akimitsu J., 2001, "Superconductivity at 39 K in MgB2”, Nature 410, 63.
[3] Buzea, C; Yamashita, T; 2001, Review of Superconductor Proerties of MgB2, CondMat/0108265 to Appear Superconductors, Science and Technology, Topical Review.
[4] King, R.B., 2002. The Similarities Between Magnesium Diboride and Cuprate Superconductors and the Role of Subvalent Magnesium, Polyhedron, 21, 2347– 2350.
[5] Hua, H. L., et all. , 2001, Chin. Phys. Soc. and IOP Publishing Ltd., 104.
[6] Larbalestier, D C, Rogado N, Regan K A, Hayward M A, He T, Slusky J S, Inumaru K, Haas M K and Cava R J, 2001, Thin Film Magnesium Boride Superconductor with Very High Critical Current Density and Enhanced Đrreversibility Field, Nature 411 558.
[7] Mustafa Zafer Balbağ, Production of Magnesıum, Boron and Magnesıum Diboride Thin Films Using Thermionic Vacuum Arc (TVA) Technique and Investigation of Some Physical Properties, PhD thesis, Eskişehir Osmangazi Üniversitesi Fen Bilimleri Enstitüsü, 2009.
[8] Savaşkan, B., 2007, Production of MgB2 and investigation of some properties, PhD thesis, Karadeniz Teknik Üniversitesi Fen Bilimleri Enstitüsü, 93 s.
[9] Buzea, C; Yamashita, T; 2001, Review of Superconductor Properties of MgB2, Cond Mat/0108265 to Appear Superconductors, Science and Technology, Topical Review.
[10] Fenler, I., 2001, Absence of Superconductivity in BeB2, Physica C, 353, 11.
[11] Young, D, P; Adams P, W; Chan C, Y; and Fronzek F, R; 2001, Preprint, Structure and Superconducting Properties of BeB2, cond-mat/0104063.
[12] Gasparov, V. A., Sidorov N, S., Zver’kova I, I., and Kulakov M, P., 2001, Electron Transport in Diborides: Observation of Superconductivity in ZrB2, JETP Lett. 73, 532.
[13] Kaczorowski, D., Zaleski A, J., Zogal O, J., and Klamut J., 2001, Preprint, Incipient Superconductivity in TaB, Cond-mat/0103571.
[14] Strukova, G, K., Degtyareva V, F., Shovkun D, V., Zverev V, N., Kiiko V, M., Ionov A, M., and Chaika A, N., 2001, Preprint, Superconductivity in the Re-B System, Cond-mat/0105293.
[15] Kortus, J., MazinI, I., Belashcenko K., D; Antropov V, P., and Boyer L, L., 2001, “Superconductivity of metalic boron in MgB2” Phys. Rev. Lett. 86, 4656.
[16] Sen, S., Aswal D., Sıng A., 2002. Preparation and Characterization of MgB2 Superconductor, Journal of Physics, 867-870.
[17] Çelik Gül, G., Kurtuluş, F., 2015, “Pioneer synthesis and characterization of boron containing hard materials” International Journal of Chemical, Molecular, Nuclear, Materials and Metallurgical Engineering 9, 9.
[18] Azmi Seyhun KIPCAK, Synthetic production of magnesium borates from different magnesium and boron sources by various methods and the investigation of their production parameters, PhD thesis, Yıldız Technical University Graduate School of Natural and Applied Sciences, 2013.