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Refractive Index, Excess Molar Volume and Viscometric Study of Binary Liquid Mixture of Morpholine with Cumene at 298.15 K, 303.15 K, and 308.15 K
Abstract:Experimental data of refractive index, excess molar volume and viscosity of binary mixture of morpholine with cumene over the whole composition range at 298.15 K, 303.15 K, 308.15 K and normal atmospheric pressure have been measured. The experimental data were used to compute the density, deviation in molar refraction, deviation in viscosity and excess Gibbs free energy of activation as a function of composition. The experimental viscosity data have been correlated with empirical equations like Grunberg- Nissan, Herric correlation and three body McAllister’s equation. The excess thermodynamic properties were fitted to Redlich-Kister polynomial equation. The variation of these properties with composition and temperature of the binary mixtures are discussed in terms of intermolecular interactions.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1112218Procedia APA BibTeX Chicago EndNote Harvard JSON MLA RIS XML ISO 690 PDF Downloads 927
 T. Yang, S. Xia, S. Song, X. Fu and P. Ma, “Densites and viscosities of N-formylmorpholine + o-Xylene, m-Xylene, p-Xylene at different temperatures and atmospheric pressure, J. Chem. Eng. Data, 2007, vol. 52, pp. 2062–2066.
 A. M. Awwad, E. I. Alios, and S. R. Salman, “Excess Molar Volumes of Mixtures Containing Morpholine at 298.15 K,” J. Chem. Eng. Data, 1988, vol. 33(3), pp. 265–267.
 S. Sharma, M. Makavana, “Density and viscometric study of binary liquid mixtures of morpholine with aromatic hydrocarbons at temperatures 303.15K, 308.15K & 313.15 K,” Fluid Phase Equilibria, 2014, vol. 375, pp. 219–227.
 B. Marrufo, M. Sanchotella and S. Loras, “Isobaric vapor–liquid equilibria for binary and ternary mixtures with cyclohexane, cyclohexene, and morpholine at 100kPa,” Fluid Phase Equilibria, 2010, vol. 296, pp. 178–183.
 B. K. Gill, V. K. Rattan And S. Kapoor, “Vapor-Liquid Equilibrium of binary mixtures of Vinyl Acetate and Ethyl Formate with Cumene at 97.3 kPa,” J. Chem. Eng. Data, 2008, vol. 53, pp. 145–148.
 J. A. Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents: Physical Properties and Methods of Purification, 4th ed. Wiley-interscience: New York, 1986.
 B. K. Gill, V. K. Rattan And S. Kapoor, “Vapor-Liquid Equilibrium Data for N-Methylacetamide and N,N-Dimethylacetamide with Cumene at 97.3 kPa,” J. Chem. Eng. Data, 2009, vol. 54, pp. 1175–1178.
 V. K. Rattan, S. Singh and B. P. S. Sethi, “Viscosities, Densities, and Ultrasonic Velocities of Binary Mixtures of Ethylbenzene with Ethanol, 1-Propanol, and 1-Butanol at (298.15 and 308.15) K,” J. Chem. Eng. Data, 2004, vol. 49, pp. 1074-1077.
 S. Singh, B. P. S. Sethi, R. C. Katyal and V. K. RATTAN, “Viscosities, Densities, and Speeds of Sound of Binary Mixtures of o-Xylene, m-Xylene, p-Xylene, and Isopropylbenzene with 2-Butanone at 298.15 K,” J. Chem. Eng. Data, 2005, vol. 50, pp. 125-127.
 D. S. Viswanath, T. K. Ghosh, and D. H. L. Prasad, Viscosity of Liquids. Theory, Estimation, Experiment and Data, ISBN-13 978-1-4020-5482-2 (e-book).
 L. Grunberg., A. H. Nissan, “Mixture Law for viscosity,” Nature, 1949, vol.164, pp. 799-800.
 R A. McAllister, “The Viscosity of Liquid Mixtures,” AIChE J. 1960, vol. 6, pp. 427-431.