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Modeling of Bisphenol A (BPA) Removal from Aqueous Solutions by Adsorption Using Response Surface Methodology (RSM)

Authors: Mohammad Ali Zazouli, Farzaneh Veisi, Amir Veisi


Bisphenol A (BPA) is an organic synthetic compound that has many applications in various industries and is known as persistent pollutant. The aim of this research was to evaluate the efficiency of bone ash and banana peel as adsorbents for BPA adsorption from aqueous solution by using Response Surface Methodology. The effects of some variables such as sorbent dose, detention time, solution pH, and BPA concentration on the sorption efficiency was examined. All analyses were carried out according to Standard Methods. The sample size was performed using Box-Benken design and also optimization of BPA removal was done using response surface methodology (RSM). The results showed that the BPA adsorption increases with increasing of contact time and BPA concentration. However, it decreases with higher pH. More adsorption efficiency of a banana peel is very smaller than a bone ash so that BPA removal for bone ash and banana peel is 62 and 28 percent, respectively. It is concluded that a bone ash has a good ability for the BPA adsorption.

Keywords: wastewater treatment, adsorbent, banana peel, Bisphenol A (BPA), bone ash

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[1] Asgari, G. and A.R. Rahmani, Preparation of an Adsorbent from Pumice Stone and Its Adsorption Potential for Removal of Toxic Recalcitrant Contaminants. 2013. Vol. 13. 2013.
[2] Asgari, G., et al., Catalytic Ozonation of Phenol Using Copper Coated Pumice and Zeolite as Catalysts. 2012. Vol. 12. 2012.
[3] Rahmani, A., M. Samadi, and A. Enayati Moafagh, Investigation of Photocatalytic Degradation of Phenol by UV/TiO2 Process in Aquatic Solutions. Vol. 8. 2008.
[4] Zhou, Y., P. Lu, and J. Lu, Application of natural biosorbent and modified peat for bisphenol a removal from aqueous solutions. Carbohydrate Polymers, 2012. 88(2): p. 502-508.
[5] Zazouli., M.A. and MTaghavi, Phenol Removal from Aqueous Solutions by Electrocoagulation Technology Using Iron Electrodes: Effect of Some Variables. Journal of Water Resource and Protectio, 2012. 4: p. 980-983.
[6] Zazouli, M.A., M. Taghavi, and E. Bazrafshan, Influences of Solution Chemistry on Phenol Removal from Aqueous Environments by Electrocoagulation Process Using Aluminum Electrodes. J Health Scope, 2012. 1(2): p. 66-70.
[7] Zhou, D., et al., Photooxidation of bisphenol A (BPA) in water in the presence of ferric and carboxylate salts. Water Research, 2004. 38(19): p. 4107-4116.
[8] Liu, G., et al., Adsorption of bisphenol A from aqueous solution onto activated carbons with different modification treatments. Journal of Hazardous Materials, 2009. 164(2-3): p. 1275-1280.
[9] Chen, J., X. Huang, and D. Lee, Bisphenol A removal by a membrane bioreactor. Process Biochemistry, 2008. 43(4): p. 451-456.
[10] Deborde, M., et al., Oxidation of bisphenol A by ozone in aqueous solution. Water Research, 2008. 42(16): p. 4299-4308.
[11] Yamanaka, H., et al., Efficient Microbial Degradation of Bisphenol A in the Presence of Activated Carbon. Journal of Bioscience and Bioengineering, 2008. 105(2): p. 157-160.
[12] Li, Q., et al., Electrochemical detection of bisphenol A mediated by (Ru(bpy)3)2+ on an ITO electrode. Journal of Hazardous Materials, 2010. 180(1-3): p. 703-709.
[13] Basile, T., et al., Review of Endocrine-Disrupting-Compound Removal Technologies in Water and Wastewater Treatment Plants: An EU Perspective. Industrial & Engineering Chemistry Research, 2011. 50(14): p. 8389-8401.
[14] Nakanishi, A., et al., Adsorption characteristics of bisphenol A onto carbonaceous materials produced from wood chips as organic waste. J Colloid Interface Sci, 2002. 252(2): p. 393-6.
[15] Li, Y.-H., et al., Adsorption thermodynamic, kinetic and desorption studies of Pb2+ on carbon nanotubes. Water Research, 2005. 39(4): p. 605-609.
[16] Bilici Baskan, M. and A. Pala, Removal of arsenic from drinking water using modified natural zeolite. Desalination. 281(0): p. 396-403.
[17] Li, Z., et al., Partitioning behaviour of trace elements in a stoker-fired combustion unit: An example using bituminous coals from the Greymouth coalfield (Cretaceous), New Zealand. International Journal of Coal Geology, 2005. 63(1-2): p. 98-116.
[18] Kabengi, N.J., S.H. Daroub, and R.D. Rhue, Energetics of arsenate sorption on amorphous aluminum hydroxides studied using flow adsorption calorimetry. Journal of Colloid and Interface Science, 2006. 297(1): p. 86-94.
[19] Pan, J., et al., Synthesis of chitosan/γ-Fe2O3/fly-ash-cenospheres composites for the fast removal of bisphenol A and 2,4,6-trichlorophenol from aqueous solutions. Journal of Hazardous Materials. 190(1-3): p. 276-284.
[20] Brugnera, M.F., et al., Bisphenol A removal from wastewater using self-organized TIO2 nanotubular array electrodes. Chemosphere. 78(5): p. 569-575.
[21] Elkady, M.F., A.M. Ibrahim, and M.M.A. El-Latif, Assessment of the adsorption kinetics, equilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads. Desalination. 278(1-3): p. 412-423.
[22] Achak, M., et al., Low cost biosorbent banana peel for the removal of phenolic compounds from olive mill wastewater: Kinetic and equilibrium studies. Journal of Hazardous Materials, 2009. 166(1): p. 117-125.
[23] Zazouli, M.A., F. Veisi, and A. Veisi, Modeling Bisphenol A Removal from Aqueous Solution by Activated Carbon and Eggshell. Journal of Mazandaran University of Medical Sciences, 2013. 22(2): p. 129-138.
[24] Soner AltundoÄŸan, H., et al., Arsenic removal from aqueous solutions by adsorption on red mud. Waste Management, 2000. 20(8): p. 761-767.
[25] Liu, C., et al., Optimal conditions for preparation of banana peels, sugarcane bagasse and watermelon rind in removing copper from water. Bioresource Technology, 2012. 119(0): p. 349-354.
[26] Cornejo, L., et al., In field arsenic removal from natural water by zero-valent iron assisted by solar radiation. Environmental Pollution, 2008. 156(3): p. 827-831.
[27] Bilici Baskan, M. and A. Pala, Removal of arsenic from drinking water using modified natural zeolite. Desalination, 2011. 281(0): p. 396-403.
[28] Zazouli, M.A., P. Ebrahimi, and M. Bagheri Ardebilian, Study of Cd (II) and Cr (VI) biosorption by mesocarps of orange and sour orange from aqueous solutions. Environmental Engineering and Management Journal 2014. 13(2): p. 231-492.
[29] Pan, J., et al., Synthesis of chitosan/γ-Fe2O3/fly-ash-cenospheres composites for the fast removal of bisphenol A and 2,4,6-trichlorophenol from aqueous solutions. Journal of Hazardous Materials, 2011. 190(1-3): p. 276-284.