Controlling Water Temperature during the Electrocoagulation Process Using an Innovative Flow Column-Electrocoagulation Reactor
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Controlling Water Temperature during the Electrocoagulation Process Using an Innovative Flow Column-Electrocoagulation Reactor

Authors: Khalid S. Hashim, Andy Shaw, Rafid Alkhaddar, Montserrat Ortoneda Pedrola

Abstract:

A flow column has been innovatively used in the design of a new electrocoagulation reactor (ECR1) that will reduce the temperature of water being treated; where the flow columns work as a radiator for the water being treated. In order to investigate the performance of ECR1 and compare it to that of traditional reactors; 600 mL water samples with an initial temperature of 350C were pumped continuously through these reactors for 30 min at current density of 1 mA/cm2. The temperature of water being treated was measured at 5 minutes intervals over a 30 minutes period using a thermometer. Additional experiments were commenced to investigate the effects of initial temperature (15-350C), water conductivity (0.15 – 1.2 S) and current density (0.5 -3 mA/cm2) on the performance of ECR1. The results obtained demonstrated that the ECR1, at a current density of 1 mA/cm2 and continuous flow model, reduced water temperature from 350C to the vicinity of 280C during the first 15 minutes and kept the same level till the end of the treatment time. While, the temperature increased from 28.1 to 29.80C and from 29.8 to 31.90C in the batch and the traditional continuous flow models respectively. In term of initial temperature, ECR1 maintained the temperature of water being treated within the range of 22 to 280C without the need for external cooling system even when the initial temperatures varied over a wide range (15 to 350C). The influent water conductivity was found to be a significant variable that affect the temperature. The desirable value of water conductivity is 0.6 S. However, it was found that the water temperature increased rapidly with a higher current density.

Keywords: Water temperature, flow column, electrocoagulation.

Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1108306

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References:


[1] Z. Zaroual, H. Chaair, A.H. Essadki, K. El Ass, M. Azzi. (2009). Optimizing the removal of trivalent chromium by electrocoagulation using experimental design. Chemical Engineering Journal. 148, 488– 495.
[2] Nazih K. Shammas Marie-Florence Pouet, and Alain Grasmick. (2010). Wastewater Treatment by Electrocoagulation–Flotation. Flotation Technology in Handbook of Environmental Engineering. 12, 199-220.
[3] Erick Butler, Yung-Tse Hung, Ruth Yu-Li Yeh and Mohammed Suleiman Al Ahmad. (2011). Electrocoagulation in Wastewater Treatment. Water. 3, 495-525.
[4] Donald Mills. (2000). A new process for electrocoagulation. American Water Works Association. 92 (6), 34- 43.
[5] D. Ghosh, D., H. Solanki, M.K. Purkait, (2008). Removal of Fe (II) from tap water by electrocoagulation technique. Journal of Hazardous Materials 155, 135–143.
[6] Charles Peguy Nanseu- Njiki, Serge Raoul Tchamango, Philippe Claude Ngom, Andre Darchen, Emmanuel Ngameni, (2009). Mercury (II) removal from water by electrocoagulation using aluminium and iron electrodes. Hazardous Materials. 168, 1430-1436.
[7] Reza Katal, Hassan Pahlavanzadeh. (2011). Influence of different combinations of aluminum and iron electrode on. Desalination. 265, 199–205.
[8] Mikko Vepsäläinena, Mohammad Ghiasvand, Jukka Selin, Jorma Pienimaa,Eveliina Repo, Martti Pulliainen, Mika Sillanpää. (2009). Investigations of the effects of temperature and initial sample pH on natural organic matter (NOM) removal with electrocoagulation using response surface method (RSM). Separation and Purification Technology. 69, 255–261.
[9] Wei-Lung Chou, Yen-Hsiang Huang. (2009). Electrochemical removal of indium ions from aqueous solution using iron electrodes. Journal of Hazardous Materials. 172, 46–53.
[10] N. Mameri, A.R. Yeddou, H. Lounici, D. Belhocine, H. Grib, B. Bariou. (1998). Defluoridation of septentrional Sahara water of North Africa by electrocoagulation process using bipolar aluminum electrodes. Water Research. 3 (5), 1604 - 1612.
[11] N. Daneshvar, H. Ashassi Sorkhabi, M.B. Kasiri. (2004). Decolorization of dye solution containing Acid Red 14 by electrocoagulation with a comparative investigation of different electrode connections. Journal of Hazardous Materials. B112, 55–62.
[12] Guohua Chen. (2011). Electrochemical technologies in wastewater treatment. Separation and Purification Technology. 38, 11–41.
[13] Tezcan Umran, A. Savas Koparal, Ulker Bakir Ogutveren. (2013). Fluoride removal from water and wastewater with a bach cylindrical electrode using electrocoagulation. Chemical Engineering. 223, 110– 115.
[14] Subramanyan Vasudevan, Jothinathan Lakshmi, Ganapathy Sozhan. (2009). Studies on the Removal of Iron from Drinking Water by Electrocoagulation – A Clean Process. Clean Soil Air Water. 37 (1), 45 – 51.
[15] Subramanyan Vasudevan, Jothinathan Lakshmi, Ganapathy Sozhan. (2011). Studies on the Al–Zn–In-alloy as anode material for the removal of chromium from drinking water in electrocoagulation process. Desalination. 275, 260–268.
[16] Alwis, A.A.P., Fryer, P.J., (1990). A finite-element analysis of heat generation and transfer during OH of food. Chemical Engineering Science. 45(6), 1547-1559.
[17] Castro, I. (2007). Ohmic heating as an alternative to conventional thermal treatment. PhD. Dissertation, Portugal: Universidade do Minho.
[18] Chih-Ta Wang and Wei-Lung Chou. (2009). Performance of COD removal from oxide chemical mechanical polishing wastewater using iron electrocoagulation. Journal of Environmental Science and Health. 44 (12), 1289-1297.
[19] Muftah H. El-Naas, Sulaiman Al-Zuhair, Amal Al-Lobaney, Souzan Makhlouf. (2009). Assessment of electrocoagulation for the treatment of petroleum refinery wastewater. Journal of Environmental Management. 91, 180–185.
[20] Wei-Lung Chou, Chih-Ta Wang, Kai-Yu Huang. (2010). Investigation of process parameters for the removal of polyvinyl alcohol from aqueous solution by iron electrocoagulation. Desalination. 251, 12–19.
[21] Saeb Ahmadi, Ebrahim Sardari, Hamed Reza Javadian, Reza Katal, and Mohsen Vafaie Sefti. (2013). Removal of oil from biodiesel wastewater by electrocoagulation method. Korean Journal of Chemical Engineering. 30 (3), 634-641.