Commenced in January 2007
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Influence of Synthetic Antioxidant in the Iodine Value and Acid Number of Jatropha Curcas Biodiesel
Authors: Supriyono, Sumardiyono
Abstract:
Biodiesel is one of the alternative fuels that promising for substituting petro diesel as energy source which is advantage on sustainability and ecofriendly. Due to the raw material that tend to decompose during storage, biodiesel also have the same characteristic that tend to decompose and formed higher acid value which is the result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could prevent by introduce a small amount of antioxidant. The origin of raw materials and the process for producing biodiesel will determine the effectiveness of antioxidant. The quality degradation on biodiesel could evaluate by measuring iodine value and acid number of biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using esterification and transesterification process will stand on the quality by introduce 90 ppm pyrogallol powder on the biodiesel, which could increase Induction period time from 2 hours to more than 6 hours in rancimat test evaluation.Keywords: Acid value, antioxidant, biodiesel, iodine value.
Digital Object Identifier (DOI): doi.org/10.5281/zenodo.1108128
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[1] IEA. U.S. Energy Information Administration. International Energy Statistics - Biodiesel production.
[2] Renner A., Zelt T., Gerteiser S., From Aid to Market, the Global Exchange for Social Investment, Global Market Study on Jatropha (Final report-Abstract), Gexsi LLP, 2008.
[3] Barnwal S.K., Sharma M.P., Prospects of biodiesel production from vegetable oils in India, Renewable and Sustainable Energy Reviews 9 (2004) 363–378.
[4] Gui M.M., Lee K.T., Bhatia S., Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock, Energy 33 (2008) 1646 – 1653.
[5] Kiss A. A., Omota F., Dimian A.C., Rothenberg G., The heterogeneous advantage: biodiesel by catalytic reactive distillation, Topics in Catalysis 40 (2006) 141–150.
[6] Tamunaidu P., Bhatia S., Catalytic cracking of palm oil for the production of biofuels: Optimization studies, Bioresource Technology 98 (2007) 3593–3601.
[7] Prado C.M.R., Filho N.R.A., Production and characterization of the biofuels obtained by thermal cracking and thermal catalytic cracking of vegetable oils, Journal of Analytical and Applied Pyrolysis 86 (2009) 338–347.
[8] Motasemi F., Ani F.N., A review on microwave-assisted production of biodiesel, Renewable and Sustainable Energy Reviews 16 (2012) 4719– 4733.
[9] Shahidi F., Bailey’s Industrial Oil and Fat Products, John Wiley & Sons, 2005, Sixth Edition.
[10] Dias, J.M., Araújo, J.M., Costa, J.F., Alvim-Ferraz, M.C.M., Almeida, M.F. Biodiesel production from raw castor oil, Energy 53 (2013) 58 – 66.
[11] Akintayo E.T., Characteristics and composition of Parkia biglobbossa and Jatropha curcas oils and cakes, Bioresource Technology 92 (2004) 307–310.
[12] Pimentel D., Patzek T.W., Ethanol Production Using Corn, Switch grass, and Wood; Biodiesel Production Using Soybean and Sunflower, Natural Resources Research 14 (2005) 65-76.
[13] Dias J.M., Alvim-Ferraz M.C.M., Almeida M.F., Production of biodiesel from acid waste lard, Bioresource Technology 100 (2009) 6355 – 6361
[14] Salimon J., Abdullah R., Physicochemical Properties of Malaysian Jatropha Curcas Seed Oil, Sain Malaysia 37 (2008) 379–382
[15] Encinar J.M., Gonzalez J.F., and Rodríguez-Reinares A., Biodiesel from Used Frying Oil. Variables Affecting the Yields and Characteristics of the Biodiesel, Industrial Engineering Chemical Resources 44 (2005) 5491–5499.
[16] Sarin A., Arora R., Singh N.P., Sharma M., Malhotra R.K., Influence of metal contaminants on oxidation stability of Jatropha biodiesel, Energy 34 (2009) 1271–1275.
[17] Tang H., Wang A., Salley S.O., Simon Ng K.Y., The Effect of Natural and Synthetic Antioxidants on the Oxidative Stability of Biodiesel, Journal of the American Oil Chemists Society 85 (2008)373–382
[18] Dinkov R., Hristov G., Stratiev D., Aldayri V.B., Effect of commercially available antioxidants over biodiesel/diesel blends stability, Fuel 88 (2009) 732–737.
[19] Knothe G., Some aspects of biodiesel oxidative stability, Fuel Processing Technology 88 (2007) 669–677.
[20] Jain S., Sharma M.P., Stability of biodiesel and its blends: A review, Renewable and Sustainable Energy Reviews 14 (2010) 667–678.